Enantioselective Diels–Alder Reaction Promoted by Achiral Functionalization of a SiO2-supported Cu–BOX [Bis(oxazoline)] Catalyst

  • Mizuki Tada
    Department of Chemistry, Graduate School of Science, The University of Tokyo
  • Satoka Tanaka
    Department of Chemistry, Graduate School of Science, The University of Tokyo
  • Yasuhiro Iwasawa
    Department of Chemistry, Graduate School of Science, The University of Tokyo

Abstract

<jats:title>Abstract</jats:title> <jats:p>We have found that surface chemical functionalization of a SiO2-supported Cu–BOX [bis(oxazoline)] catalyst with achiral 3-methacryloxypropyltrimethoxysilane remarkably increases enantioselectivity in asymmetric Diels–Alder reaction of cyclopentadiene and 3-acryloyl-2-oxazolidinone.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 34 (10), 1362-1363, 2005-09-10

    Oxford University Press (OUP)

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