Surface-Mediated Catalyst Design for Selective Oxidation Catalysis
Project/Area Number |
18065003
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Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
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Research Institution | Institute for Molecular Science (2008-2009) The University of Tokyo (2006-2007) |
Principal Investigator |
TADA Mizuki Institute for Molecular Science, 物質分子科学研究領域, 准教授 (70396810)
|
Co-Investigator(Kenkyū-buntansha) |
SASAKI Takehiko 東京大学, 大学院・新領域創成科学研究科, 准教授 (90242099)
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Project Period (FY) |
2006 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
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Budget Amount *help |
¥32,000,000 (Direct Cost: ¥32,000,000)
Fiscal Year 2009: ¥8,000,000 (Direct Cost: ¥8,000,000)
Fiscal Year 2008: ¥8,000,000 (Direct Cost: ¥8,000,000)
Fiscal Year 2007: ¥8,000,000 (Direct Cost: ¥8,000,000)
Fiscal Year 2006: ¥8,000,000 (Direct Cost: ¥8,000,000)
|
Keywords | 固定化金属錯体 / 固体触媒 / 触媒構造解析 / 選択酸化 / 触媒反応機構 / 協奏機能触媒 / 反応機構 / 触媒表面 / 時間分解XAFS / ルテニウム / モレキュラーインプリンティング / 触媒 / 表面 / XAFS / in-situ解析 / 協奏機能 / 活性構造 / レニウム / ゼオライト |
Research Abstract |
Novel unique metal catalysts were designed and prepared on oxide surfaces by metal-complex attaching and selective structural transformation at the surfaces and we have found concerto catalysis for selective oxidation on these surface-mediated metal-complex catalysts. Dynamic structural changes of catalytically active species in the concerto catalysis were investigated by in-situ time-resolved XAFS technique and the reaction mechanism and structural kinetics of the concerto catalysis were demonstrated.
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Report
(6 results)
Research Products
(116 results)
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[Journal Article] In-situ Time-Resolved Dynamic Surface Events on the Pt/C Cathode in a Fuel Cell under Operando Conditions2007
Author(s)
M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, Y. Iwasawa
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Journal Title
Angew. Chem. Int. Ed 46
Pages: 4310-4315
Related Report
Peer Reviewed
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[Journal Article] In-Situ Time-Resolved Dynamic Surface Events on the Pt/C Cathode in a Fuel Cell under Operando Conditions2007
Author(s)
M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, Y. Iwasawa
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Journal Title
Angew. Chem. Int. Ed 46
Pages: 4310-4315
Related Report
Peer Reviewed
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[Journal Article] In-situ Time-resolved Dynamic Surface Events on the Pt/C Cathode ina Fuel Cell under Operando Conditions2007
Author(s)
M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, Y. Iwasawa
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Journal Title
Angew. Chem. Int. Ed. 46
Pages: 4310-4315
Related Report
Peer Reviewed
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