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Yanai Hikaru  矢内 光

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YANAI Hikaru  矢内 光

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Researcher Number 10408685
Other IDs
Affiliation (Current) 2025: 東京薬科大学, 薬学部, 准教授
Affiliation (based on the past Project Information) *help 2016 – 2023: 東京薬科大学, 薬学部, 准教授
2014 – 2015: 東京薬科大学, 薬学部, 講師
2008 – 2013: Tokyo University of Pharmacy and Life Science, 薬学部, 助教
2005 – 2007: 東京薬科大学, 薬学部, 助手
Review Section/Research Field
Principal Investigator
Chemical pharmacy / Basic Section 47010:Pharmaceutical chemistry and drug development sciences-related / Science and Engineering
Except Principal Investigator
Chemical pharmacy
Keywords
Principal Investigator
炭素酸 / ブレンステッド酸 / 有機化学 / 有機合成化学 / 触媒開発 / 有機フッ素化学 / カルボアニオン / 連続反応 / 多環式芳香族炭化水素 / カスケード反応 … More / 双性イオン / 多成分反応 / インジウム / ルイス酸 / 分配係数 / 溶解度 / 光反応 / 複素環式芳香族化合物 / 蛍光分子 / 構造化学 / push-pullアルケン / 薬学 / ナフタレン / 多環式芳香族化合物 / シリルアセタール / 有機分子触媒 / トリアゾール / 付加環化反応 / アルミニウム / ブレンステット酸 / 糖ミメティクス / 合成化学 / 有機反応学 … More
Except Principal Investigator
塩化クロム / フルオロオレフィン / トリフルオロアセトアルデヒド / トリフルオロメタンスルホニル / ペプチドミメチックス / トリフルオロメチル / Atoropisomeric amide / Fluoroacrylate / Diels-Alder reaction / Trifluoroacetaldehyde / Glutamate receptor / Chromium chloride / Peptidemimetics / Fluorinated olefin / 軸不斉アミド / イミデート転位反応 / フルオロビニルエーテル / 軸負不斉ラクタム / ルイス酸 / ジペプチドイソスター / フルオロアリルアルコール / アトロプ異性 / ペプチドミメティックス / アトロプ異性アミド / フルオロアクリル酸エステル / Diels-Alder反応 / グルタミン酸受容体 / シリルオキシフラン / アミド配座異性 / 向山-マイケル反応 / ジフルオロメチレン / ジフルオロケトン / ブレンステッド酸 / メイケル付加反応 / アルドール反応 / アルキルアルミニウム / 炭素酸 / トリフリル基 / ペプチドイソスター / フルオロアルケン / 有機フッ素化学 Less
  • Research Projects

    (10 results)
  • Research Products

    (243 results)
  • Co-Researchers

    (8 People)
  •  Development of functional molecules bearing stable carbanion moietiesPrincipal Investigator

    • Principal Investigator
      矢内 光
    • Project Period (FY)
      2023 – 2025
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Review Section
      Basic Section 47010:Pharmaceutical chemistry and drug development sciences-related
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  Development of novel cascade reactions for polysubstituted polycyclic aromaticsPrincipal Investigator

    • Principal Investigator
      YANAI Hikaru
    • Project Period (FY)
      2020 – 2022
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Review Section
      Basic Section 47010:Pharmaceutical chemistry and drug development sciences-related
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  Structural chemistry on highly stabilized carbanionsPrincipal Investigator

    • Principal Investigator
      Yanai Hikaru
    • Project Period (FY)
      2017 – 2019
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Chemical pharmacy
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  強酸性炭素酸を鍵構造とする新しい有機分子触媒の設計と利用Principal Investigator

    • Principal Investigator
      矢内 光
    • Project Period (FY)
      2014 – 2015
    • Research Category
      Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
    • Review Section
      Science and Engineering
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  Novel cascade reactions triggered by silyl acetal activationPrincipal Investigator

    • Principal Investigator
      Yanai Hikaru
    • Project Period (FY)
      2014 – 2016
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Chemical pharmacy
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  有機分子触媒の設計を先導する新しい酸性官能基の開発Principal Investigator

    • Principal Investigator
      矢内 光
    • Project Period (FY)
      2012 – 2013
    • Research Category
      Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
    • Review Section
      Science and Engineering
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  Development of new synthetic reactions based on novel acid catalystsPrincipal Investigator

    • Principal Investigator
      YANAI Hikaru
    • Project Period (FY)
      2010 – 2012
    • Research Category
      Grant-in-Aid for Young Scientists (B)
    • Research Field
      Chemical pharmacy
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  Preparation of functionalized organofluorine compounds toward drug discovery

    • Principal Investigator
      TAGUCHI Takeo
    • Project Period (FY)
      2008 – 2010
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Chemical pharmacy
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  Development of functional molecules on the basis of design of novel Lewis acid catalystsPrincipal Investigator

    • Principal Investigator
      YANAI Hikaru
    • Project Period (FY)
      2007 – 2009
    • Research Category
      Grant-in-Aid for Young Scientists (B)
    • Research Field
      Chemical pharmacy
    • Research Institution
      Tokyo University of Pharmacy and Life Science
  •  Development of synthetic methodogies for organofluorine compounds in medicinal chemistry

    • Principal Investigator
      TAGUCHI Takeo
    • Project Period (FY)
      2005 – 2007
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Chemical pharmacy
    • Research Institution
      Tokyo University of Pharmacy and Life Science

All 2024 2023 2022 2021 2020 2019 2018 2017 2016 2015 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 Other

All Journal Article Presentation Book Patent

  • [Book] 有機分子触媒の開発と工業利用2018

    • Author(s)
      矢内 光
    • Total Pages
      333
    • Publisher
      シーエムシー出版
    • ISBN
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Book] フッ素化学入門20152015

    • Author(s)
      矢内 光
    • Publisher
      三共出版
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Book] Green Synthetic Approaches for Biologically Relevant Heterocycles2014

    • Author(s)
      Hikaru Yanai
    • Publisher
      Elsevier
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Book] Fluorine in Medicinal Chemistry and Chemical Biology2009

    • Author(s)
      矢内光, 他
    • Publisher
      Wiley-Blackwell
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Book] Fluorine in Medicinal Chemistry and Chemical Biology2009

    • Author(s)
      Hikaru Yanai
    • Publisher
      Wiley-Blackwell
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Book] Acid Catalysis in Modern Organic Synthesis2008

    • Author(s)
      矢内光, 他
    • Publisher
      Wiley-VCH
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Development of Stable Carbanionic Substituents2023

    • Author(s)
      Hikaru Yanai
    • Journal Title

      The Chemical Record

      Volume: 23 Issue: 9

    • DOI

      10.1002/tcr.202300076

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Journal Article] Reversing the Bond Length Alternation Order in Conjugated Polyenes by Substituent Effects2023

    • Author(s)
      H. Yanai et al.
    • Journal Title

      Chemistry - A European Journal

      Volume: 29 Issue: 15

    • DOI

      10.1002/chem.202203538

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-20K06947, KAKENHI-PROJECT-23K06031
  • [Journal Article] Diverse Synthesis of 2H‐Isoindole‐Based Polycyclic Aromatic Compounds2023

    • Author(s)
      Teru Kawazoe, Hikaru Yanai et al.
    • Journal Title

      Chemistry - A European Journal

      Volume: 29 Issue: 50

    • DOI

      10.1002/chem.202301703

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Journal Article] Indium-promoted butenolide synthesis through consecutive C-C and C-O bond formations in aqueous tetrahydrofuran enabled by radicals2023

    • Author(s)
      H. Yanai et al.
    • Journal Title

      Organic Chemistry Frontiers

      Volume: 10 Issue: 7 Pages: 1773-1779

    • DOI

      10.1039/d3qo00133d

    • Peer Reviewed / Open Access / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-20K06947, KAKENHI-PROJECT-23K06031
  • [Journal Article] Au(I) as a π-Lewis Base Catalyst: Controlled Synthesis of Sterically Congested Bis(triflyl)enals from α-Allenols2022

    • Author(s)
      H. Yanai et al.
    • Journal Title

      ACS Catalysis

      Volume: 12 Issue: 19 Pages: 11675-11681

    • DOI

      10.1021/acscatal.2c03858

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Journal Article] A Fluorinated Carbanionic Substituent for Improving Water Solubility and Lipophilicity of Fluorescent Dyes2021

    • Author(s)
      Yanai, H.; Hoshikawa, S. Moriiwa, Y.; Shoji, A.; Yanagida, A.; Matsumoto, T.
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Issue: 10 Pages: 5168-5172

    • DOI

      10.1002/anie.202012764

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Journal Article] Regioselective Synthesis of 4‐Aryl‐1,3‐dihydroxy‐2‐naphthoates through 1,2‐Aryl‐Migrative Ring Rearrangement Reaction and their Photoluminescence Properties2021

    • Author(s)
      H. Yanai et al.
    • Journal Title

      Chemistry - A European Journal

      Volume: 27 Issue: 44 Pages: 11442-11449

    • DOI

      10.1002/chem.202101459

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Journal Article] Metal-Free C-C/C-N/C-C Bond Formation Cascade for the Synthesis of (Trifluoromethyl)sulfonylated Cyclopenta[b]indolines2021

    • Author(s)
      Lazaro-Milla, C.; Yanai, H.; Almendros, P.
    • Journal Title

      Organic Letters

      Volume: 23 Issue: 8 Pages: 2921-2926

    • DOI

      10.1021/acs.orglett.1c00557

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Journal Article] Synthesis of Polycyclic Aromatic Hydrocarbons Decorated by Fluorinated Carbon Acids/Carbanions2021

    • Author(s)
      H. Yanai et al.
    • Journal Title

      Chemistry - A European Journal

      Volume: 27 Issue: 65 Pages: 16112-16116

    • DOI

      10.1002/chem.202103188

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Journal Article] Catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols2020

    • Author(s)
      Martin-Mejias, I.; Aragoncillo, C.; Yanai, H.; Hoshikawa, S.; Fujimoto, Y.; Matsumoto, T.; Almendros, P.
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 12 Pages: 1795-1798

    • DOI

      10.1039/c9cc08930f

    • Peer Reviewed / Open Access / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Journal Article] Trifluorosulfonylation cascade in allenols: stereocontrolled synthesis of bis(triflyl)enones2020

    • Author(s)
      Lazaro-Milla, C.; Macicior, J.; Yanai, H.; Almendros, P.
    • Journal Title

      Chemistry A European Journal

      Volume: 26 Issue: 41 Pages: 8983-8989

    • DOI

      10.1002/chem.202001236

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Journal Article] Chemical bonding in polarised push-pull ethylenes2019

    • Author(s)
      Yanai, H.; Suzuki, T.; Kleemiss, F.; Fukaya, H.; Dobashi, Y.; Malaspina, L. A.; Grabowsky, S.; Matsumoto, T.
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 26 Pages: 8839-8844

    • DOI

      10.1002/anie.201904176

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Journal Article] Synthesis and Characterization of Stable Phosphorus Carbabetaines2018

    • Author(s)
      Yanai, H.; Almendros , P.; Takahashi , S.; Lazaro-Milla, C.; Alcaide, B.; Matsumoto, T.
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 13 Issue: 15 Pages: 1956-1961

    • DOI

      10.1002/asia.201800769

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Journal Article] Transition metal-free controlled synthesis of bis[(trifluoromethyl)sulfonyl]ethyl-decorated heterocycles2018

    • Author(s)
      Almendros, P.; Yanai, H.; Hoshikawa, S.; Aragoncillo, C.; Lazaro-Milla, C.; Toledano-Pinedo, M.; Matsumoto, T.; Alcaide, B.
    • Journal Title

      Organic Chemistry Frontiers

      Volume: 5 Issue: 21 Pages: 3163-3169

    • DOI

      10.1039/c8qo00955d

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Journal Article] Design of Novel Hydrogen-bonding Donor Organocatalysts and Their Application to Asymmetric Direct Aldol Reaction2017

    • Author(s)
      H. Akutsu, K. Nakashima, H. Yanai, A. Kotani, S. Hirashima, T. Yamamoto, R. Takahashi, A. Yoshida, Y. Koseki, H. Hakamata, T. Matsumoto, T. Miura
    • Journal Title

      Synlett

      Volume: 28 Issue: 11 Pages: 1363-1367

    • DOI

      10.1055/s-0036-1558971

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-16K08178, KAKENHI-PROJECT-17K08224
  • [Journal Article] カルボアニオン含有塩の合成と有機触媒としての利用2017

    • Author(s)
      矢内 光
    • Journal Title

      化学工業

      Volume: 68 Pages: 73-78

    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Journal Article] 2-(Pyridinium-1-yl)-1,1-bis((perfluoroalkyl)sulfonyl)ethan-1-ide: a practical reagent for synthesis of strongly acidic 1,1-bis((perfluoroalkyl)sulfonyl)alkanes2017

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chem. Eur. J.

      Volume: 23 Issue: 34 Pages: 8203-8211

    • DOI

      10.1002/chem.201700515

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Journal Article] Sequential Mukaiyama-Michael reaction induced by carbon acids2016

    • Author(s)
      Yanai, H., Kobayashi, O., Takada, K., Isono, T., Satoh, T.,Matsumoto, T.
    • Journal Title

      Chemical Communications

      Volume: 52 Issue: 16 Pages: 3280-3283

    • DOI

      10.1039/c5cc10115h

    • Peer Reviewed / Acknowledgement Compliant
    • Data Source
      KAKENHI-PUBLICLY-26105703, KAKENHI-PUBLICLY-26105755, KAKENHI-PROJECT-13J03764, KAKENHI-PROJECT-26460015
  • [Journal Article] Synthesis of 1,2,3,4-tetrasubstituted naphthalenes through a cascade reaction triggered by silyl acetal activation2016

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chem. Commun.

      Volume: 52 Issue: 51 Pages: 7974-7977

    • DOI

      10.1039/c6cc03510h

    • Peer Reviewed / Acknowledgement Compliant
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Journal Article] An efficient isoprenylation of xanthones at the C1 position by utilizing anion-accelerated aromatic oxy-Cope rearrangement2016

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Synlett

      Volume: 27 Issue: 06 Pages: 848-853

    • DOI

      10.1055/s-0035-1561326

    • Peer Reviewed
    • Data Source
      KAKENHI-PUBLICLY-26105755, KAKENHI-PROJECT-25460024, KAKENHI-PROJECT-23000006
  • [Journal Article] A rapid entry to diverse γ-ylidenetetronate derivatives through regioselective bromination of tetronic acid derived γ-lactones and metal-catalyzed postfunctionalization2015

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Eur. J. Org. Chem.

      Volume: - Issue: 28 Pages: 6259-6269

    • DOI

      10.1002/ejoc.201500663

    • Peer Reviewed / Int'l Joint Research
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Journal Article] Synthesis of (Z)-fluoroallyl azides through aluminium-mediated defluorinative functionalization reactions2015

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Tetrahedron Letters

      Volume: 56 Issue: 7 Pages: 925-929

    • DOI

      10.1016/j.tetlet.2014.12.128

    • Peer Reviewed / Acknowledgement Compliant
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Journal Article] Chemistry of Fluorinated Carbon Acids: Synthesis, Physicochemical Properties, and Catalysis2015

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chemical and Pharmaceutical Bulletin

      Volume: 63 Issue: 9 Pages: 649-662

    • DOI

      10.1248/cpb.c15-00487

    • NAID

      130005096032

    • ISSN
      0009-2363, 1347-5223
    • Language
      English
    • Peer Reviewed / Acknowledgement Compliant
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Journal Article] Chemoselective Two-directional Reaction of Bi-functionalized Substrates: Formal Ketal-selective Mukaiyama Aldol Type Reaction2015

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Synlett

      Volume: 26 Issue: 17 Pages: 2457-2461

    • DOI

      10.1055/s-0035-1560478

    • Peer Reviewed / Acknowledgement Compliant
    • Data Source
      KAKENHI-PROJECT-26460015, KAKENHI-PUBLICLY-26105755
  • [Journal Article] Synthesis of superacidic carbon acid and its derivatives2015

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Journal of Fluorine Chemistry

      Volume: 127 Pages: 108-119

    • DOI

      10.1016/j.jfluchem.2014.11.006

    • Peer Reviewed / Acknowledgement Compliant
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Journal Article] ビス(トリフリル)メチル基をもつ強酸性炭素酸の合成と触媒としての応用2014

    • Author(s)
      矢内 光
    • Journal Title

      有機合成化学協会誌

      Volume: 72 Pages: 158-170

    • NAID

      130003395382

    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Journal Article] Gas-phase acidity of 1,1-bis(trifluoromethanesulfonyl)propane derivatives and related compounds. Experimental and theoretical studies2014

    • Author(s)
      Hikaru Yanai
    • Journal Title

      J. Phys. Org. Chem.

      Volume: 27

    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Journal Article] 1,1-Bis(triflyl)alkadienes: easy-to-handle building blocks for strongly acidic carbon acids2014

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Asian J. Org. Chem.

      Volume: 3

    • Peer Reviewed
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Journal Article] 2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: Structural Behaviour And Availability as Bis(triflyl)ethylating Reagents2013

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 86 Pages: 10091-10093

    • DOI

      10.1039/c3cc46171h

    • Peer Reviewed
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Journal Article] Reductive alkylation of bis(triflyl)methane through self-promoting formation of easily isolable 1,1-bis(triflyl)alkenes2013

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Tetrahedron Letters

      Volume: 54 Issue: 17 Pages: 2160-2163

    • DOI

      10.1016/j.tetlet.2013.02.039

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019, KAKENHI-PUBLICLY-24105533
  • [Journal Article] Novel One-Pot Synthesis of Xanthones via Sequential Fluoride Ion-Promoted Fries-Type Rearrangement and Nucleophilic Aromatic Substitution2013

    • Author(s)
      Yuuki Fujimoto, Ryohei Itakura, Hiroki Hoshi, Hikaru Yanai, Yoshio Ando, Keisuke Suzuki, and Takashi Matsumoto
    • Journal Title

      Synlett

      Volume: 24 Issue: 19 Pages: 2575-2580

    • DOI

      10.1055/s-0033-1339881

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-23000006, KAKENHI-PUBLICLY-24105533
  • [Journal Article] Synthesis, Characterization, and Applications of Zwitterions Containing Carbanion Moiety2013

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 52 Issue: 5 Pages: 1560-1563

    • DOI

      10.1002/anie.201208809

    • Peer Reviewed
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Journal Article] Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities2013

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Molecules

      Volume: 18 Issue: 12 Pages: 15531-15540

    • DOI

      10.3390/molecules181215531

    • Peer Reviewed
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Journal Article] Organic Acid-Catalysis in Reactions of Lactones with Silicon Enolates2013

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Asian J. Org. Chem.

      Volume: 2 Issue: 11 Pages: 989-996

    • DOI

      10.1002/ajoc.201300157

    • Peer Reviewed
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Journal Article] Four component reaction of aldehydes, isocyanides, Me3SiN3, and aliphatic alcohols catalyzed by indium triflate2012

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Tetrahedron Letters

      Volume: 53 Issue: 25 Pages: 3161-3164

    • DOI

      10.1016/j.tetlet.2012.04.046

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019, KAKENHI-PUBLICLY-24105533
  • [Journal Article] Preparation of (Z)-1-fluoro-1-alkenyl carboxylates, carbonates and carbamates through chromium mediated transformation of dibromofluoromethylcarbinyl esters and the reactivity as double acyl group donors2012

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Journal of Fluorine Chemistry

      Volume: 133 Pages: 38-51

    • DOI

      10.1016/j.jfluchem.2011.07.022

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Journal Article] Organic acid induced olefination reaction of lactones2012

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chemical Communications

      Volume: 48 Issue: 71 Pages: 8967-8969

    • DOI

      10.1039/c2cc33606e

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019, KAKENHI-PUBLICLY-24105533
  • [Journal Article] Copper mediated defluorinative allylic alkylation of difluorohomoallyl alcohol derivatives directed to an efficient synthetic method for (Z)-fluoroalkene dipeptide isosteres.2011

    • Author(s)
      D.Watanabe, M.Koura, A.Saito, H.Yanai, Y.Nakamura, M.Okada, A.Sato, T.Taguchi
    • Journal Title

      J.Fluorine Chem. 132

      Pages: 327-338

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] An effective method to introduce carbon acid functionality : 2,2-bis(trifluoromethanesulfonyl)ethylation reaction of arenes2011

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chemistry-A European Journal

      Volume: 17 Issue: 42 Pages: 11747-11751

    • DOI

      10.1002/chem.201102023

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Journal Article] Copper-free defluorinative alkylation of allylic difluorides through Lewis acid-mediated C-F bond activation2011

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Tetrahedron Letters

      Volume: 52 Issue: 23 Pages: 2997-3000

    • DOI

      10.1016/j.tetlet.2011.03.148

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Journal Article] Copper-free defluorinative alkylation of allylic difluorides through Lewis acid-mediated C-F bond activation.2011

    • Author(s)
      H.Yanai, H.Okada, A.Sato, M.Okada, T.Taguchi
    • Journal Title

      Tetrahedron Lett. 52

      Pages: 2997-3000

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] A regioselective synthesis of poly-substituted aryl triflones through self-promoting three component reaction2011

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chemical Communications

      Volume: 47 Issue: 25 Pages: 7245-7247

    • DOI

      10.1039/c1cc12093j

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Journal Article] 1,4-Addition of Silicon Dienoates to α, β-Unsaturated Aldehydes Catalyzed by In situ-generated Silicon Lewis Acid2010

    • Author(s)
      H.Yanai, A.Takahashi, T.Taguchi
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 8728-8730

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Development of efficient Lewis acid catalysts for intramolecular cycloaddition reactions of ester-tethered substrates2010

    • Author(s)
      高橋新, 矢内光, Min Zhang, 園田高明, 三島正章, 田口武夫
    • Journal Title

      The Journal of Organic Chemistry 75

      Pages: 1259-1265

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] 1,4-Addition of silicon dienoates to α,β-unsaturated aldehydes catalyzed by in situ-generated silicon Lewis acid2010

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chemical Communications

      Pages: 8728-8730

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Journal Article] A rapid and convergent synthesis of α,α-difluoro-β-hydroxyketones through regiospecific defluorinative alkylation reaction2010

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Tetrahedron Letters

      Volume: 51 Pages: 2625-2628

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Journal Article] Carbon Acid Induced Mukaiyama Aldol Reaction of Sterically Hindered Ketones.2010

    • Author(s)
      H.Yanai, Y.Yoshino, A.Takahashi, T.Taguchi
    • Journal Title

      J.Org.Chem. 75

      Pages: 5375-5378

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Highly Effective Vinylogous Mukaiyama-Michael Reaction Catalyzed by Silyl Methide Species Generated from 1,1,3,3-Tetrakis(trifluoro-methanesulfonyl)propane.2010

    • Author(s)
      A.Takahashi, H.Yanai, M.Zhang, T.Sonoda, M.Mishima, T.Taguchi
    • Journal Title

      J.Org.Chem. 75

      Pages: 1259-1265

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] A Rapid and Convergent Synthesis of α, α-Difluoro-β-hydroxyketones through Regiospecific Defluorinative Alkylation Reaction2010

    • Author(s)
      H.Yanai, T.Ichikawa, T.Taguchi
    • Journal Title

      Tetrahedron Lett.

      Volume: 51 Pages: 2625-2628

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Trihaloacetaldehyde N,O-acetals : useful building blocks for dihalomethylene compounds.2010

    • Author(s)
      H.Yanai, T.Taguchi
    • Journal Title

      Tetrahedron 66

      Pages: 4530-4541

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Carbon Acid Induced Mukaiyama Aldol Reaction of Sterically Hindered Ketones2010

    • Author(s)
      H.Yanai, Y.Yoshino, A.Takahashi, T.Taguchi
    • Journal Title

      J.Org.Chem.

      Volume: 75 Pages: 5375-5378

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Carbon acid induced Mukaiyama aldol type reaction of sterically hindered ketones2010

    • Author(s)
      Hikaru Yanai
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 75 Pages: 5375-5378

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Journal Article] 1,4-Addition of Silicon Dienoates to α,β-Unsaturated Aldehydes Catalyzed by In situ-generated Silicon Lewis Acid.2010

    • Author(s)
      H.Yanai, A.Takahashi, T.Taguchi
    • Journal Title

      Chem.Commun. 46

      Pages: 8728-8730

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Trihaloacetaldehyde N, O-Acetals : Useful Building Blocks for Dihalomethylene Compounds2010

    • Author(s)
      H.Yanai, T Taguchi
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 4530-4541

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Highly effective vinylogous Mukaiyama-Michael reaction catalyzed by silyl methide species generated from 1,1,3,3-tetrakis(trifluoromethanesulfonyl)propane2010

    • Author(s)
      Hikaru Yanai
    • Journal Title

      The Journal of Organic Chemistry 75

      Pages: 1259-1265

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Trihaloacetaldehyde N,O-acetals : Useful building blocks for dihalomethylene compounds2010

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 4530-4541

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Journal Article] Direct alkylative Passerini reaction of aldehydes, isocyanides, and free aliphatic alcohols catalyzed by indium(III) triflate2009

    • Author(s)
      Hikaru Yanai
    • Journal Title

      The Journal of Organic Chemistry 74

      Pages: 3927-3929

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Direct Alkylative Passerini Reaction of Aldehydes, Isocyanates, and Free Aliphatic Alcohols Catalyzed by In(III) Triflate2009

    • Author(s)
      Hikaru Yanai
    • Journal Title

      J.Org.Chem. 74

      Pages: 3927-3929

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Novel defluorinative alkylation of trifluoroacetaldehyde N, O-acetal derivatives and its application to multi-component reaction2009

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chemical Communications

      Pages: 1034-1036

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Direct alkylative Passerini reaction of aldehydes, isocyanides, and free aliphatic alcohols catalyzed by indium(III) triflate2009

    • Author(s)
      矢内光, 小口智子, 田口武夫
    • Journal Title

      The Journal of Organic Chemistry 74

      Pages: 3927-3929

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Remarkable rate acceleration of intramolecular Diels-Alder reaction in ionic liquids2009

    • Author(s)
      矢内光, 小倉弘, 田口武夫
    • Journal Title

      Organic & Biomolecular Chemistry 7

      Pages: 3657-3659

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Novel defluorinative alkylation of trifluoroacetaldehyde N,O-acetal derivatives and its application to multi-component reaction.2009

    • Author(s)
      H.Yanai, T.Taguchi
    • Journal Title

      Chem.Commun.

      Pages: 1034-1036

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Novel defluorinative alkylation of trifluoroacetaldehyde N, O-acetalDerivatives and its application to multi-component reaction2009

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chem. Commun.

      Pages: 1034-1036

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Remarkable rate acceleration of intramolecular Diels-Alder reaction in ionic liquid2009

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Org.Biomol.Chem. 7

      Pages: 3657-3659

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Remarkable ratc acceleration of intramolecular Diels-Alder reaction in ionic liquids2009

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Organic, Biomolecular Chemistry 7

      Pages: 3657-3659

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Novel defluorinative alkylation of trifluoroacetaldehyde N, O-acetal derivatives and its application to multi-component reaction2009

    • Author(s)
      矢内光, 田口武夫
    • Journal Title

      Chemical Communications

      Pages: 1034-1036

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] An efficient synthesis of triazolo-carbohydrate mimetics and theirconformational analysis2008

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Ore. Biomol. Chem. 6

      Pages: 2679-2685

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] An efficient synthesis of triazolo-carbohydrate mimetics and their conformational analysis2008

    • Author(s)
      矢内光, 小原峻, 田口武夫
    • Journal Title

      Organic & Biomolecular Chemistry 6

      Pages: 2679-2685

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] An efficient synthesis of triazolo-carbohydrate mimetics and their conformational analysis2008

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Organic & Biomolecular Chemistry 6

      Pages: 2679-2685

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Tetrakis(trifluoromethanesulfonyl)propane: highly effective Bronsted acid catalyst for vinylogous Mukaiyama-Michael reaction of ・, ・-enones with silyloxyfurans2008

    • Author(s)
      高橋新, 矢内光, 田口武夫
    • Journal Title

      Chemical Communications

      Pages: 2385-2387

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Tetrakis(trifluoromethanesulfonyl)propane : Highly effective Bronsted Acid Catalyst for Vinylogous Mukaiyama-Michael Reaction of α,β-Enones with Silyloxyfurans.2008

    • Author(s)
      A.Takahashi, H.Yanai, T.Taguchi
    • Journal Title

      Chem.Commun.

      Pages: 2385-2387

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Journal Article] Tetrakis(trifluoromethanesulfonyl)propane : Highly effective Bronsted acid catalyst for vinylogous Mukaiyama-Michael reaction of α, β-enones with silyloxyfurans2008

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Chemical Communications

      Pages: 2385-2387

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Development of efficient Lewis acid catalysts for intramolecular cycloaddition reactions of ester-tethered substrates2007

    • Author(s)
      田口武夫, 齊藤亜紀夫, 矢内光
    • Journal Title

      The Chemical Records 7

      Pages: 167-179

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Development of effective Lewis acids for the catalytic Diels-Alder reaction of α, β-unsaturated lactones with cyclopentadiene2007

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Tetrahedron Letters 48

      Pages: 2993-2997

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Convenient synthesis of fluorhlated quinohine,1,2-dihydroquinohne and 1,2,3,4-tetrahydroquinoline derivatives2007

    • Author(s)
      矢内 光、田口 武夫, ら
    • Journal Title

      Tetrahedron 63

      Pages: 2153-2160

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Development of effective Lewis acids for the catalytic Diels-Alder reaction of α,β-unsaturated lactones with cyclopentadiene2007

    • Author(s)
      Yanai, H., Takahashi, A., Taguchi, T
    • Journal Title

      Tetrahedron Lett 48

      Pages: 2993-2997

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Development of effective Lewis acids for the catalytic Diek-Alderreaction of α,β-unsaturated lactones with cyclopentadiene2007

    • Author(s)
      矢内 光、田口 武夫, ら
    • Journal Title

      Tetrahedron Lett. 48

      Pages: 2993-2997

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Dimethylaluminum methide complex Tf_2CHAlMe_2 : an effective catalyst for Diels-Alder reaction of α,β-unsaturated lactone derivatives with cyclopantadiene2007

    • Author(s)
      Yanai, H., Takahashi, A., Taguchi, T
    • Journal Title

      Tetrahedron 63

      Pages: 12149-12159

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Dimethylaluminum nlethide complex-Tf_2CHAlMe_2:an effective catalyst for Diels-Alder reaction of α,β-unsaturated lactone derivatives with cyclopantadiene2007

    • Author(s)
      矢内 光、田口 武夫, ら
    • Journal Title

      Tetrahedron 63

      Pages: 12149-12159

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Convenient synthesis of fluorinated quinoline, 1,2-dihydroquinoline and 1,2,3,4-tetrahydroquinoline Derivatives2007

    • Author(s)
      Yanai, H., Mimura, H., Kawada, K., Taguchi, T
    • Journal Title

      Tetrahedron 63

      Pages: 2153-2160

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Dimethylaminum methide complex Tf_2CHA1Me_2: an effective catalyst for Diels-Alder reaction of α, β-unsaturated lactone derivatives with cyclopentadiene2007

    • Author(s)
      Hikaru Yanai
    • Journal Title

      Tetrahedron 63

      Pages: 12149-12159

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Dimethylaluminum methide complex Tf2CHAlMe2: An effective catalyst for Diels-Alder reaction of ・, ・-unsaturated lactone derivatives with cyclopentadiene2007

    • Author(s)
      矢内光, 高橋新, 田口武夫
    • Journal Title

      Tetrahedron 63

      Pages: 12149-12159

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Development of effective Lewis acids for the catalytic Diels-Alder reaction of ・, ・-unsaturated lactones with cyclopentadiene2007

    • Author(s)
      矢内光, 高橋新, 田口武夫
    • Journal Title

      Tetrahedron Letters 48

      Pages: 2993-2997

    • Data Source
      KAKENHI-PROJECT-19790025
  • [Journal Article] Intramolecular [3+2] cycloaddition reaction of α,β-enoate derivatives having allylsilane parts : 1,1'-biphenyl-2,2'-di(triflypamide (BIPAM) + 2Me2A1C1 as a Novel Lewis acid2006

    • Author(s)
      Saito, A., Sakamoto, W., Yanai, H., Taguchi, T
    • Journal Title

      Tetrahedron Lett 47

      Pages: 4181-4185

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Intramolecular Diels-Alder reaction of 1,7,9-decatrienoates catalyzed by indium(III) trifluoromethanesulfonate in aqueous media2005

    • Author(s)
      Yanai, H., Saito, A., Taguchi, T
    • Journal Title

      Tetrahedron 61

      Pages: 7087-7093

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Intramolecular Diels-Alder reaction α-fluoroacrylate derivatives promoted by novel bidentate aluminum Lewis acid2005

    • Author(s)
      Saito, A., Yanai, H., Sakamoto, W., Takahashi, K., Taguchi, T
    • Journal Title

      J. Fluorine Chem 126

      Pages: 709-714

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Journal Article] Intramolecular Diels-Alder reaction of 1,7,9-decatrienoates catalyzed by indium(III) trifluoromethanes ulfonate in aqueous media2005

    • Author(s)
      矢内 光、田口 武夫, ら
    • Journal Title

      Tetrahedron 61

      Pages: 7087-7093

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-17590015
  • [Patent] ビス(トリフルオロメタンスルホニル)エチル基を有する化合物及び酸触媒、並びにその製造方法2010

    • Inventor(s)
      田口武夫、矢内光
    • Industrial Property Rights Holder
      セントラル硝子株式会社、東京薬科大学
    • Industrial Property Number
      2010-281174
    • Filing Date
      2010-12-17
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] 溶媒効果を活用したアルケンとビス(トリフリル)エチレンの反応による強酸性炭素酸の選択的合成2024

    • Author(s)
      干川翔貴,矢内 光
    • Organizer
      日本薬学会 第144年会
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Presentation] 光酸発生条件を用いたMukaiyamaアルドール反応とその利用2024

    • Author(s)
      相川莉央,矢内 光
    • Organizer
      日本薬学会 第144年会
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Presentation] HFIP-mediated detriflylative allylic substitution reactions on the cyclobutene platform2023

    • Author(s)
      Shoki Hoshikawa, Hikaru Yanai
    • Organizer
      23rd International Symposium on Fluorine Chemistry
    • Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Presentation] 光酸発生剤を用いたMukaiyamaアルドール反応2023

    • Author(s)
      矢内 光
    • Organizer
      第46回 フッ素化学討論会
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Presentation] 窒素原子がドープされた多環式芳香族炭化水素の合成とその物性2023

    • Author(s)
      川添 輝,矢内 光
    • Organizer
      第49回 反応と合成の進歩シンポジウム
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Presentation] gem-ビス(トリフリル)シクロブテンの脱トリフリル-アリル置換反応2023

    • Author(s)
      矢内 光
    • Organizer
      第46回 フッ素化学討論会
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Presentation] Fluorinated stable carbanions as substituents for controlling the solubility profiles of organic compounds2023

    • Author(s)
      Hikaru Yanai
    • Organizer
      23rd International Symposium on Fluorine Chemistry
    • Invited / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-23K06031
  • [Presentation] Push-pull置換ポリエンにおける異常な炭素-炭素結合長2022

    • Author(s)
      矢内光
    • Organizer
      日本薬学会第142年会
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Presentation] Ring-rearrangement Strategy for Selective Synthesis of Pseudo Aromatic Polyketides2022

    • Author(s)
      H. Yanai
    • Organizer
      International Congress on Pure & Applied Chemistry Kota Kinabaru 2022
    • Invited / Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Presentation] 求電子アルケンを用いるカルボアリーレーション反応:超強酸性炭素酸で修飾された多環式芳香族化合物の合成2021

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第141年会
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Presentation] 含フッ素置換基が共役ポリエンの炭素-炭素結合の長さに及ぼす効果2021

    • Author(s)
      矢内光
    • Organizer
      第44回フッ素化学討論会
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Presentation] 1,1-ビス(トリフリル)エチレンを用いたシクロブテン生成反応を鍵段階とするスピロ(シクロブタン―フルオレイン)骨格の効率的構築2021

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第141年会
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Presentation] ビニル型カルボカチオン中間体への分子内求核付加反応における極安定カルボアニオンの反応性2020

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第140年会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 1,1-ビス(トリフリル)エチレンを用いたアルキンの求電子付加反応:多環式骨格のダイバージェント構築2020

    • Author(s)
      矢内 光
    • Organizer
      第43回 フッ素化学討論会
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Presentation] フッ素で安定化されたカルボアニオン性置換基による有機蛍光色素の物性制御2020

    • Author(s)
      矢内 光
    • Organizer
      反応と合成の進歩 2020 特別企画シンポジウム
    • Data Source
      KAKENHI-PROJECT-20K06947
  • [Presentation] 含フッ素カルボアニオン構造による蛍光色素の物性制御2020

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第140年会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 含フッ素強酸性置換基の導入による蛍光色素の溶解性制御2019

    • Author(s)
      矢内 光
    • Organizer
      第42回 フッ素化学討論会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 1,1-Bis(triflyl)ethylation reaction of heterocyclic compounds2019

    • Author(s)
      Hikaru Yanai
    • Organizer
      9th European Symposium on Fluorine Chemistry
    • Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] トリフリル基で安定化されたカルボアニオンの反応性:ビニル型カルベニウムイオンに対する結合形成と化学選択性2019

    • Author(s)
      矢内 光
    • Organizer
      第42回 フッ素化学討論会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 2,2-ビス(トリフリル)-1,1-ジアミノエチレン:ユニークな動的構造をもつ新たな水素結合供与体2018

    • Author(s)
      矢内 光
    • Organizer
      第11回 有機触媒シンポジウム
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] Ultimately Polarised Push-Pull Ethylenes: Unusual Conformational Behaviour and its Application2018

    • Author(s)
      H. Yanai
    • Organizer
      The 22nd International Symposium on Fluorine Chemistry
    • Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 高度に分極したジアリール push-pull エチレンにおける化学変換2018

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第138年会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 強酸性炭素酸の合成を指向した複素環式芳香族化合物の2,2-ビス(トリフリル)エチル化反応2018

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第138年会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 複素環に対する強酸性炭素酸構造の導入法の開発2018

    • Author(s)
      矢内 光
    • Organizer
      第41回 フッ素化学討論会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 2,2- ビス(トリフリル)-1,1- ビス(アリールアミノ)エチレンの化学修飾2018

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第139年会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 含窒素複素環に対するビス(トリフリル)エチル化反応2018

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第139年会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 高度に分極したPush-pull エチレンの構造特性の解明と触媒応用2018

    • Author(s)
      矢内 光
    • Organizer
      第44回 反応と合成の進歩シンポジウム
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] トリフリル基で安定化されたカルボアニオン構造をもつリンベタインの合成と構造化学2018

    • Author(s)
      矢内 光
    • Organizer
      第41回 フッ素化学討論会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 炭素ジアニオン等価体の合成素子としての利用2018

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第138年会
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 日本薬学会 第137年会2017

    • Author(s)
      矢内 光
    • Organizer
      温和な酸触媒を用いた二種のケトン間における化学選択性
    • Place of Presentation
      仙台
    • Year and Date
      2017-03-24
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] 高度に分極したpush-pullエチレンの合成2017

    • Author(s)
      矢内 光
    • Organizer
      第43回 反応と合成の進歩シンポジウム
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] Highly Polarized Push-pull Ethylenes: Synthesis, Structure and Applications2017

    • Author(s)
      Hikaru Yanai
    • Organizer
      26th French-Japanese Symposium on Medicinal and Fine Chemistry
    • Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] ペルフルオロアルキルスルホニル基で置換されたpush-pullエチレンの合成とその動的立体構造2017

    • Author(s)
      矢内 光
    • Organizer
      フルオラス科学研究会 第10回シンポジウム
    • Data Source
      KAKENHI-PROJECT-17K08224
  • [Presentation] 溶媒効果に基づくMukaiyamaアルドール型反応の化学選択性のスイッチング2016

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会
    • Place of Presentation
      横浜
    • Year and Date
      2016-03-29
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] Highly Selective Synthesis of 1,2,3,4-Tetrasubstituted Naphthalenes Through Fluoride-induced Cascade Reaction2016

    • Author(s)
      Hikaru Yanai
    • Organizer
      25th French-Japanese Symposium on Medicinal and Fine Chemistry
    • Place of Presentation
      Tokyo
    • Year and Date
      2016-05-15
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] 強酸性炭素酸を鍵構造とする新しい有機分子触媒の設計と利用2016

    • Author(s)
      矢内 光
    • Organizer
      有機分子触媒による未来型分子変換 第6回 公開シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      2016-01-22
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] ビス(ペルフオロアキスホニペル)アルカン類の合成と有機溶媒中での酸性度評価2016

    • Author(s)
      矢内 光
    • Organizer
      第39回 フッ素化学討論会
    • Place of Presentation
      佐賀
    • Year and Date
      2016-09-29
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] カルボアニオン構造をもつピリジニウム型双性イオンの合成と利用法2016

    • Author(s)
      矢内 光
    • Organizer
      第109回 有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2016-06-08
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] 酸性双性イオン触媒を用いた Mukaiyama アルドール反応の化学選択性2016

    • Author(s)
      矢内 光
    • Organizer
      第60回 日本薬学会 関東支部大会
    • Place of Presentation
      東京
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] 強酸性炭素酸誘導体を用いたイソクマリン類とケテンシリルアセタールの反応2016

    • Author(s)
      矢内 光
    • Organizer
      第42回 反応と合成の進歩シンポジウム
    • Place of Presentation
      静岡
    • Year and Date
      2016-11-07
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] 新しい有機酸触媒の開発:有機フッ素化学からのアプローチ2015

    • Author(s)
      矢内 光
    • Organizer
      フルオラス科学研究会 第8回 シンポジウム
    • Place of Presentation
      静岡
    • Year and Date
      2015-10-02
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] Sequential Mukaiyama-Michael Reaction Induced by Fluorinated Carbon Acid2015

    • Author(s)
      Hikaru Yanai
    • Organizer
      21th International Symposium on Fluorine Chemistry
    • Place of Presentation
      Como, Italy
    • Year and Date
      2015-08-23
    • Int'l Joint Research
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] フッ素化学が拓く強酸性化合物の世界2015

    • Author(s)
      矢内 光
    • Organizer
      日本フッ素化学会 フッ素化学セミナー
    • Place of Presentation
      東京
    • Year and Date
      2015-09-16
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] 新しい有機酸触媒の開発:有機フッ素化学からのアプローチ2015

    • Author(s)
      矢内 光
    • Organizer
      フルオラス科学研究会 第8回 シンポジウム
    • Place of Presentation
      静岡
    • Year and Date
      2015-10-02
    • Invited
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] Chemoselective Two-directional Reaction Induced by Acidic Zwitterions Bearing Highly Stabilized Carbanion Moiety2015

    • Author(s)
      Hikaru Yanai
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-15
    • Int'l Joint Research
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] Chemoselective Two-directional Reaction Induced by Acidic Zwitterions Bearing Highly Stabilized Carbanion Moiety2015

    • Author(s)
      Hikaru Yanai
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-15
    • Int'l Joint Research
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] Chemistry of Superacidic Carbon Acids: Synthesis, Properties and Applications2015

    • Author(s)
      Hikaru Yanai
    • Organizer
      Departmental Seminar at Instituto de Quimica Organica General, CSIC
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2015-09-03
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] Catalytic Behaviour of Carbon Acid Derivatives2015

    • Author(s)
      Hikaru Yanai
    • Organizer
      The 39th Naito Conference
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2015-07-06
    • Int'l Joint Research
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] フッ素が拓く強酸性化合物の化学2015

    • Author(s)
      矢内 光
    • Organizer
      Nagoya University, ITbM/IGER Chemistry Workshop ~Symposium of Organic Chemistry by Students~
    • Place of Presentation
      名古屋
    • Year and Date
      2015-10-30
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] フルオロピリジニウム型双性イオンを用いる触媒的分子変換2015

    • Author(s)
      矢内 光
    • Organizer
      第8回 有機触媒シンポジウム
    • Place of Presentation
      沖縄
    • Year and Date
      2015-05-10
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] Development of Fluorinated Zwitterion Catalysts2015

    • Author(s)
      Hikaru Yanai
    • Organizer
      9th French-Japanese Symposium on Fluorine Chemistry
    • Place of Presentation
      Nice, France
    • Year and Date
      2015-08-30
    • Int'l Joint Research
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] フッ素で置換された炭素酸触媒を用いる逐次反応の開発2015

    • Author(s)
      矢内 光
    • Organizer
      第38回 フッ素化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2015-09-17
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] 安定なカルボアニオン構造を持つ双性イオンの合成と利用2014

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第134年会
    • Place of Presentation
      熊本
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] Synthesis and Catalysis of Fluorinated Organic Brønsted Acids2013

    • Author(s)
      Hikaru Yanai
    • Organizer
      17th European Symposium on Fluorine Chemistry
    • Place of Presentation
      Paris, France
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] 有機酸触媒を用いたラクトンのオレフィン化反応2013

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第133年会
    • Place of Presentation
      横浜
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] カルボアニオン構造をもつ双性イオンの合成と触媒性能の評価2013

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第133年会
    • Place of Presentation
      横浜
    • Year and Date
      2013-03-27
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] Stereoelectronic Effects in 2-Ammonioethan-1-ides: Experimental and Theoretical Analyses2013

    • Author(s)
      Hikaru Yanai
    • Organizer
      17th European Symposium on Fluorine Chemistry
    • Place of Presentation
      Paris, France
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] Strong Organic Acids Containig Fluorine; Synthesis, Structure, and Catalysis2013

    • Author(s)
      Hikaru Yanai
    • Organizer
      4th Japan-Korea-China Joint Seminar on Fluorine Chemistry
    • Place of Presentation
      Nagoya
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] 安定な1,1-ビス(トリフリル)アルケンの合成と利用2013

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第133年会
    • Place of Presentation
      横浜
    • Year and Date
      2013-03-27
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] 有機酸触媒を用いたラクトンのオレフィン化反応2013

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第133年会
    • Place of Presentation
      横浜
    • Year and Date
      2013-03-27
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] Highly regioselective synthesis of poly-substituted aryl trifluoromethyl sulfones2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      Kyoto
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] ビス(トリフリル)エチル化反応を用いた超強酸触媒の開発2012

    • Author(s)
      矢内光
    • Organizer
      日本薬学会第132年会
    • Place of Presentation
      札幌
    • Year and Date
      2012-03-29
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 炭素-フッ素結合活性化を基盤とするフルオロアルケンの合成:官能基化されたジペプチドイソスターの合成研究2012

    • Author(s)
      矢内 光
    • Organizer
      第38回 反応と合成の進歩シンポジウム
    • Place of Presentation
      東京
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Synthesis of multiple carbon acids and their catalyst activity in organic reactions2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2012-07-24
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 有機フッ素化合物から有機化学を学ぶ2012

    • Author(s)
      矢内 光
    • Organizer
      第2回 フッ素化学若手の会
    • Place of Presentation
      茨城
    • Year and Date
      2012-09-13
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] ビス(トリフリル)エチル化反応を用いた超強酸触媒の開発2012

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会第132 年会
    • Place of Presentation
      札幌
    • Year and Date
      2012-03-29
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Highly regioselective synthesis of poly-substituted aryl trifluoromethyl sulfones2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      Kyoto
    • Year and Date
      2012-07-22
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] Synthesis of multiple carbon acids and their catalyst activity in organic reactions2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      Kyoto
    • Year and Date
      2012-07-22
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] 超強酸性を呈する炭素酸の合成と有機分子触媒としての応用2012

    • Author(s)
      矢内 光
    • Organizer
      文部科学省科学研究費補助金「新学術領域研究(研究領域提案型)」有機分子触媒による未来型分子変換 第1回 全体会議
    • Place of Presentation
      京都
    • Year and Date
      2012-06-08
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] 炭素-フッ素結合活性化を基盤とするフルオロアルケンの合成:官能基化されたジペプチドイソスターの合成研究2012

    • Author(s)
      矢内 光
    • Organizer
      第38回 反応と合成の進歩シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2012-11-06
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Defluorinative allylic substitution reaction via Csp3-F bond activation by aluminium-fluorine interaction2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2012-07-24
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 新しい三成分反応を基盤とするトリフリルアレーン類の位置選択的合成2012

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会第132 年会
    • Place of Presentation
      札幌
    • Year and Date
      2012-03-30
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 取り扱い容易な有機強酸の開発と利用2012

    • Author(s)
      矢内 光
    • Organizer
      有機合成化学協会北海道支部 若手研究者のための有機化学札幌セミナー
    • Place of Presentation
      札幌
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] Highly regioselective synthesis of poly-substituted aryl trifluoromethyl sulfones2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2012-07-24
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 1,1-ビス(トリフリル)エチレンの系内発生を基盤とする新合成反応の開発2012

    • Author(s)
      矢内 光
    • Organizer
      第101回 有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2012-06-06
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] 1-ビス(トリフリル)エチレンの系内発生を基盤とする新合成反応の開発2012

    • Author(s)
      矢内 光
    • Organizer
      第101回 有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2012-06-06
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 新しい三成分反応を基盤とするトリフリルアレーン類の位置選択的合成2012

    • Author(s)
      矢内光
    • Organizer
      日本薬学会第132年会
    • Place of Presentation
      札幌
    • Year and Date
      2012-03-30
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] カルボアニオン構造を持つ双性イオンの合成と利用2012

    • Author(s)
      矢内 光
    • Organizer
      第38回 反応と合成の進歩シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2012-11-05
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] Defluorinative azidation reaction of difluoroallyl compounds using silylated azide2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      Kyoto
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 超強酸性化合物の効率的な合成手法の開発と有機酸触媒としての利用2012

    • Author(s)
      矢内 光
    • Organizer
      第5回 有機触媒シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2012-10-26
    • Data Source
      KAKENHI-PUBLICLY-24105533
  • [Presentation] Defluorinative azidation reaction of difluoroallyl compounds using silylated azide2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2012-07-24
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Defluorinative allylic substitution reaction via Csp3-F bond activation by aluminium-fluorine interaction2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      Kyoto
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Synthesis of multiple carbon acids and their catalyst activity in organic reactions2012

    • Author(s)
      Hikaru Yanai
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      Kyoto
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 1,1-ビス(トリフリル)エチレンの系内発生を基盤とする新合成反応の開発2012

    • Author(s)
      矢内 光
    • Organizer
      第101回 有機合成シンポジウム
    • Place of Presentation
      東京
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 有機酸触媒を用いたラクトンのオレフィン化反応2012

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第133 年会
    • Place of Presentation
      東京
    • Year and Date
      2012-11-06
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Defluorinative alkylation of allylic difluorides directed to an efficient synthesis of functionalized fluorinated alkenes2011

    • Author(s)
      Hikaru Yanai
    • Organizer
      242nd American Chemical Society National Meeting
    • Place of Presentation
      Denver, CO, USA
    • Year and Date
      2011-08-30
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 多置換アリールトリフルオロメチルスルホンの合成2011

    • Author(s)
      矢内 光
    • Organizer
      第1回フッ素化学若手の会
    • Place of Presentation
      岐阜
    • Year and Date
      2011-08-01
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Post-synthetic modification of arenes by bis(triflyl)methyl group directed to development of superacid catalysts2011

    • Author(s)
      Hikaru Yanai
    • Organizer
      242nd American Chemical Society National Meeting
    • Place of Presentation
      Denver, CO, USA
    • Year and Date
      2011-08-28
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Post-synthetic modification of arenes by bis(triflyl)methyl group directed to development of superacid catalysts2011

    • Author(s)
      Hikaru Yanai
    • Organizer
      242nd American Chemical Society National Meeting
    • Place of Presentation
      デンバー,米国
    • Year and Date
      2011-08-28
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 超強酸触媒の開発を指向したアレーン骨格へのビス(トリフリル)メチル基の導入法の開発2011

    • Author(s)
      矢内 光
    • Organizer
      第35回フッ素化学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-27
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Defluorinative alkylation of allylic difluorides directed to an efficient synthesis of functionalized fluorinated alkenes2011

    • Author(s)
      Hikaru Yanai
    • Organizer
      242nd American Chemical Society National Meeting
    • Place of Presentation
      デンバー,米国
    • Year and Date
      2011-08-30
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] ジフルオロホモアリルアルコールのC-F結合活性化を基軸とするフルオロオレフィン,クロロオレフィンの選択的合成2011

    • Author(s)
      矢内光,岡田はる奈,佐藤梓,岡田みどり,田口武夫
    • Organizer
      日本薬学会第131年会
    • Place of Presentation
      静岡
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] アレーン骨格を利用した多価炭素酸の合成と酸触媒としての利用2011

    • Author(s)
      小倉弘,藤田聖也,矢内光,田口武夫
    • Organizer
      日本薬学会第131年会
    • Place of Presentation
      静岡
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] アレーン骨格を利用した多価炭素酸の合成と酸触媒としての利用2011

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第131年会
    • Place of Presentation
      静岡
    • Year and Date
      2011-03-30
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] ビス(トリフルオロメタンスルホニル)メタンをC1ソースとするシクロヘキセンの一段階合成2011

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会 第131年会
    • Place of Presentation
      静岡
    • Year and Date
      2011-03-31
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 強酸性を呈する多価C-H酸の効率的合成法の開発2011

    • Author(s)
      矢内 光
    • Organizer
      第9回次世代を担う有機化学シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2011-05-27
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] アルデヒド,イソシアニド,遊離脂肪族アルコールおよびトリメチルシリルアジドの四成分反応2010

    • Author(s)
      矢内 光
    • Organizer
      第36回 反応と合成の進歩シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2010-11-01
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] Development of novel synthetic reactions inspired by fluorine chemistry2010

    • Author(s)
      Hikaru Yanai
    • Organizer
      第8回 日中フッ素化学工業会議
    • Place of Presentation
      東京
    • Year and Date
      2010-06-10
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 立体的に込み合ったケトンに対する効率的なMukaiyamaアルドール反応の開発2010

    • Author(s)
      矢内光
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-29
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Tetrakis(trifluoromethanesulfonyl)propane: highly effective Bronsted acid catalyst for C-C bond forming reactions of 2-silyloxyfurans with carbonyl compounds2010

    • Author(s)
      Hikaru Yanai
    • Organizer
      16th European Symposium on Fluorine Chemistry
    • Place of Presentation
      リュブリャナ,スロベニア
    • Year and Date
      2010-07-22
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 立体的に込み合ったケトンに対する効率的なMukaiyamaアルドール反応の開発2010

    • Author(s)
      吉野泰裕,高橋新,矢内光,田口武夫
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] Bronsted酸触媒を用いる分子内型alkylativc Passerini反応2010

    • Author(s)
      矢内光
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-29
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] 1,1,3,3-テトラキス(トリフルオロメタンスルホニル)プロパンを用いた炭素-炭素結合形成反応の高度効率化2010

    • Author(s)
      矢内光
    • Organizer
      第97回 有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2010-06-18
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 1,1,3,3-テトラキス(トリフルオロメタンスルホニル)プロパンを用いた炭素-炭素結合形成反応の高度効率化2010

    • Author(s)
      矢内 光
    • Organizer
      第97回有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2010-06-18
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] A rapid and convergent synthesis of a,a-difluoroketones through regio-specific defluorinative alkylation of trifluoroacetaldehyde N,O-acetals2010

    • Author(s)
      Hikaru Yanai
    • Organizer
      16th European Symposium on Fluorine Chemistry
    • Place of Presentation
      リュブリャナ,スロベニア
    • Year and Date
      2010-07-22
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] シリルビス(トリフルオロメタンスルホニル)メチドを触媒とするα,β-不飽和アルデヒドへの1,4-付加反応2010

    • Author(s)
      矢内光,高橋新,田口武夫
    • Organizer
      第34回フッ素化学討論会
    • Place of Presentation
      札幌
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] ジフルオロホモアリルアルコール類に対する多彩な脱フッ素アリル置換反応2010

    • Author(s)
      矢内光,岡田はる奈,佐藤梓,岡田みどり,田口武夫
    • Organizer
      第34回フッ素化学討論会
    • Place of Presentation
      札幌
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] 選択的C-F結合切断を機軸とするジフルオロケトン類の迅速合成2010

    • Author(s)
      矢内光
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-29
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] 3,3-ジフルオロ-1-アルケンを用いるフルオロアルケニルアジドの位置および立体選択的合成2010

    • Author(s)
      佐藤謙介,矢内光,佐藤梓,中村裕子,岡田みどり,田口武夫
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] Tetrakis(trifluoromethanesulfonyl)propane : Highly effective Bronsted acid catalyst for C-C bond forming reactions of 2-silyloxyfurans with carbonyl compounds2010

    • Author(s)
      A.Takahashi, H.Yanai, Y.Yoshino, T.Taguchi
    • Organizer
      16th European Symposium on Fluorine Chemistry
    • Place of Presentation
      ユブリアナスロベニア
    • Year and Date
      2010-07-22
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] アルコキシ化されたニトリリウム種を活用する新規四成分反応の開発2010

    • Author(s)
      矢内光
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-29
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] シリルビス(トリフルオロメタンスルホニル)メチドを触媒とするα,β-不飽和アルデヒドへの1,4-付加反応2010

    • Author(s)
      矢内 光
    • Organizer
      第34回 フッ素化学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-10-18
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] A rapid and convergent synthesis of α,α-difluoroketones through regio-specific defluorinative alkylation of trifluoroacetaldehyde N,O-acetals2010

    • Author(s)
      Hikaru Yanai
    • Organizer
      16th European Symposium on Fluorine Chemistry
    • Place of Presentation
      リュブリャナ,スロベニア
    • Year and Date
      2010-07-22
    • Data Source
      KAKENHI-PROJECT-22790019
  • [Presentation] 金属トリフラートの特性を活用したアルデヒド,イソシアニド,脂肪族アルコールの新規三成分反応2009

    • Author(s)
      矢内光
    • Organizer
      第33回フッ素化学討論会
    • Place of Presentation
      八王子,東京
    • Year and Date
      2009-10-19
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Alkylative Passerini反応:簡便かつ収束的な・-アルコキシアミドの合成2009

    • Author(s)
      矢内光
    • Organizer
      第35回反応と合成の進歩シンポジウム
    • Place of Presentation
      金沢
    • Year and Date
      2009-11-16
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Trifluoroacetaldehyde N,O-acetals : Highly effective building block for α,α-difluoroketone derivatives2009

    • Author(s)
      矢内光
    • Organizer
      19th International Symposium on Fluorine Chemistry
    • Place of Presentation
      ジャクソンホール,米国
    • Year and Date
      2009-08-24
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Trifluoroacetaldehyde N, O-acetals: Highly effective building block for ・, ・-difluoroketone derivatives2009

    • Author(s)
      矢内光
    • Organizer
      19th International Symposium on Fluorine Chemistry
    • Place of Presentation
      ジャクソンホール・米国ワイオミング州
    • Year and Date
      2009-08-24
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] ポリハロケトン類の有用な保護基:N-ベンジル-N,O-アセタール2009

    • Author(s)
      矢内光,市川辰徳,田口武夫
    • Organizer
      第33回フッ素化学討論会
    • Place of Presentation
      東京
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] Carbon acids in organic chemistry2009

    • Author(s)
      矢内光
    • Organizer
      Symposium on Fluorinc Chemistry in Kyoto Institute of Technology
    • Place of Presentation
      京都
    • Year and Date
      2009-05-20
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] ジアミンの添加による位置特異的脱フッ素アルキル化反応の顕著な加速効果2009

    • Author(s)
      矢内光
    • Organizer
      第33回フッ素化学討論会
    • Place of Presentation
      八王子,東京
    • Year and Date
      2009-10-19
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] トリクロロアセトアルデヒドN, O-アセタールを用いた交差Reformmatsky型反応2009

    • Author(s)
      矢内光
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      京都
    • Year and Date
      2009-03-26
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] テトラキス(トリフルオロメタンスルホニル)プロパンを炭素酸触媒として用いた2-シリルオキシフランのα,β-不飽和アルデヒドに対する共役付加反応2009

    • Author(s)
      高橋新,矢内光,加藤麻衣子,田口武夫
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      京都
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] ポリハロケトン類の有用な保護基:N-ベンジル-N,O-アセタール2009

    • Author(s)
      矢内光
    • Organizer
      第33回フッ素化学討論会
    • Place of Presentation
      八王子,東京
    • Year and Date
      2009-10-19
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] 炭素酸触媒を用いるジアステレオ選択的ビニロガスMukaiyama-Michael反応2009

    • Author(s)
      高橋新,矢内光,田口武夫
    • Organizer
      第33回フッ素化学討論会
    • Place of Presentation
      東京
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] アルデヒド,イソシアニドおよび遊離脂肪族アルコールの三成分反応によるα-アルコキシアミドの合成2009

    • Author(s)
      矢内光
    • Organizer
      The International Conference on Fluorine Chemistry '09
    • Place of Presentation
      京都
    • Year and Date
      2009-05-21
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] アルデヒド,イソシアニドおよび遊離脂肪族アルコールの三成分反応によるα-アルコキシアミドの合成2009

    • Author(s)
      矢内光
    • Organizer
      第57回有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2009-05-09
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] 炭素酸触媒を用いるジアステルオ選択的ビニロガスMukaiyama-Michael反応2009

    • Author(s)
      矢内光
    • Organizer
      第33回フッ素化学討論会
    • Place of Presentation
      八王子,東京
    • Year and Date
      2009-10-19
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] テトラキス(トリフルオロメタンスルホニル)プロパン:シリルオキシフランを用いた炭素-炭素結合形成反応に有効なBronsted酸触媒2009

    • Author(s)
      矢内光
    • Organizer
      第7回次世代を担う有機化学シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      2009-07-23
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Trifluoroacetaldehyde N,O-acetals : Useful building blocks fbr functionalized difluoromethylene compounds2009

    • Author(s)
      矢内光
    • Organizer
      The International Conference on Fluorine Chemistry '09
    • Place of Presentation
      京都
    • Year and Date
      2009-05-21
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Tetrakis(trifluoromethanesulfonyl)propane: highly effective Bronsted acid catalyst for vinylogous Mukaiyama-Michael and aldol reactions using 2-silyloxyfurans2009

    • Author(s)
      矢内光
    • Organizer
      19th International Symposium on Fluorine Chemistry
    • Place of Presentation
      ジャクソンホール・米国ワイオミング州
    • Year and Date
      2009-08-26
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Alkylative Passerini反応:簡便かつ収束的なα-アルコキシアミドの合成2009

    • Author(s)
      矢内光
    • Organizer
      第35回反応と合成の進歩シンポジウム
    • Place of Presentation
      金沢
    • Year and Date
      2009-11-16
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Tandem azidation/1, 3-dipolar cycloaddition reaction : An efficient synthesis of triaz olo-carbohydrate mimetics with stereochemical diversity and their conformation an alysis2008

    • Author(s)
      Hikaru Yanai
    • Organizer
      236th American Chemical Society National Meeting
    • Place of Presentation
      Philadelphia, USA
    • Year and Date
      2008-08-20
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] トリフルオロアセトアルデヒドN, O-アセタール : C-F結合切断に基づくジフルオロメチルアニオン前駆体としての利用2008

    • Author(s)
      矢内光
    • Organizer
      第32回フッ素化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2008-11-17
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] 脱フッ素アリル置換反応による官能基化されたフルオロアルケンの合成2008

    • Author(s)
      佐藤謙介,矢内光,福田寛人,中村裕子,岡田みどり,田口武夫
    • Organizer
      第32回フッ素化学討論会
    • Place of Presentation
      名古屋
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] テトラキス(トリフルオロメタンスルホニル)プロパンをBronsted酸触媒とするビニロガスMukaiyama-aldol反応の開発2008

    • Author(s)
      矢内光,吉野泰裕,高橋新,田口武夫
    • Organizer
      第32回フッ素化学討論会
    • Place of Presentation
      名古屋
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] 炭素酸触媒を用いるビニロガスMukaiyama-Michael反応の開発2008

    • Author(s)
      高橋新,矢内光,田口武夫
    • Organizer
      第32回フッ素化学討論会
    • Place of Presentation
      名古屋
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] Tandem azidation/1, 3-dipolar cycloaddition reaction: An efficient synthesis of triazolo-carbohydrate mimetics with stereochemical diversity and their conformation analysis2008

    • Author(s)
      矢内光
    • Organizer
      236th American Chemical Society National Meeting
    • Place of Presentation
      フィラデルフィア・米国
    • Year and Date
      2008-08-20
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] トリフルオロアセトアルデヒドN,O-アセタール:C-F結合切断に基づくジフルオロメチルアニオン前駆体としての利用2008

    • Author(s)
      矢内 光,三村英之,河田恒佐,田口武夫
    • Organizer
      第32回フッ素化学討論会
    • Place of Presentation
      名古屋
    • Data Source
      KAKENHI-PROJECT-20590013
  • [Presentation] Development of Lewis acid and Bronsted acid catalysts for Diels-Alder reaction of α, β-unsaturated lactone derivatives2008

    • Author(s)
      矢内光
    • Organizer
      236th American Chemical Society National Meeting
    • Place of Presentation
      フィラデルフィア・米国
    • Year and Date
      2008-08-20
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] テトラキストリフルオロメタンスルホニルプロパンを炭素酸触媒とするシリルオキシフラン誘導体のMukaiyama-Michael反応2008

    • Author(s)
      矢内光
    • Organizer
      第94回有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2008-11-18
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] Development of efficient Lewis acid catalysts for Diels-Alder reactions of dienophiles having ・, ・-unsaturated ester moiety2007

    • Author(s)
      矢内光
    • Organizer
      15th European Symposium on Fluorine Chemistry
    • Place of Presentation
      プラハ・チェコ
    • Year and Date
      2007-07-20
    • Data Source
      KAKENHI-PROJECT-19790025
  • [Presentation] シリルアセタールの活性化を引き金とする1,2,3,4-四置換ナフタレンの選択的な合成

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会第135年会
    • Place of Presentation
      神戸
    • Year and Date
      2015-03-25 – 2015-03-28
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] フッ素の特異性に着目した有機フッ素化合物の新しい合成法とその利用

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会第135年会
    • Place of Presentation
      神戸
    • Year and Date
      2015-03-25 – 2015-03-28
    • Invited
    • Data Source
      KAKENHI-PROJECT-26460015
  • [Presentation] 極安定カルボアニオン構造をもつピリジニウム型双性イオンの化学

    • Author(s)
      矢内 光
    • Organizer
      第40回反応と合成の進歩シンポジウム
    • Place of Presentation
      仙台
    • Year and Date
      2014-11-10 – 2014-11-11
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] Highly Stabilized Carbanions by Fluorinated Substituents

    • Author(s)
      Hikaru Yanai
    • Organizer
      International Conference on Fluorine Chemistry 2014
    • Place of Presentation
      Yokohama
    • Year and Date
      2014-05-28 – 2014-05-30
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] Chemoselective Mukaiyama Aldol Type Reactions Catalyzed by Fluorinated Zwitterion

    • Author(s)
      Hikaru Yanai
    • Organizer
      4th International Symposium on Organofluorine Compounds “Bordeaux Fluorine Days”
    • Place of Presentation
      Bordeaux, France
    • Year and Date
      2014-07-06 – 2014-07-10
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] フッ素置換によって安定化されたカルボアニオン構造をもつ双性イオンの触媒作用

    • Author(s)
      矢内 光
    • Organizer
      第37回フッ素化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2014-10-30 – 2014-10-31
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] フッ素の特異性に着目した有機フッ素化合物の新しい合成法とその利用

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会第135年会 奨励賞受賞講演
    • Place of Presentation
      神戸
    • Year and Date
      2015-03-25 – 2015-03-28
    • Invited
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • [Presentation] シリルアセタールの活性化を引き金とする1,2,3,4-四置換ナフタレンの選択的な合成

    • Author(s)
      矢内 光
    • Organizer
      日本薬学会第135年会
    • Place of Presentation
      神戸
    • Year and Date
      2015-03-25 – 2015-03-28
    • Data Source
      KAKENHI-PUBLICLY-26105755
  • 1.  TAGUCHI Takeo (00016180)
    # of Collaborated Projects: 2 results
    # of Collaborated Products: 36 results
  • 2.  KITAGAWA Osamu (30214787)
    # of Collaborated Projects: 1 results
    # of Collaborated Products: 0 results
  • 3.  三浦 剛
    # of Collaborated Projects: 0 results
    # of Collaborated Products: 1 results
  • 4.  平島 真一
    # of Collaborated Projects: 0 results
    # of Collaborated Products: 1 results
  • 5.  佐藤 敏文
    # of Collaborated Projects: 0 results
    # of Collaborated Products: 1 results
  • 6.  鈴木 啓介
    # of Collaborated Projects: 0 results
    # of Collaborated Products: 1 results
  • 7.  松本 隆司
    # of Collaborated Projects: 0 results
    # of Collaborated Products: 1 results
  • 8.  安藤 吉勇
    # of Collaborated Projects: 0 results
    # of Collaborated Products: 1 results

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