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AKIBA Kin-ya  秋葉 欣哉

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… Alternative Names

AKIBA Kinya  秋葉 欣哉

秋葉 欣也  アキバ キンヤ

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Researcher Number 20011538
Other IDs
External Links
Affiliation (based on the past Project Information) *help 2005 – 2006: 早稲田大学, 理工学術院, 教授
2003: 早稲田大学, 大学院・工学研究科, 教授
2001 – 2003: Waseda Univ., Advanced Research Center for Science and Engineering, Professor, 理工学総合研究センター, 教授
2000: Toho University, Faculty of Science, Visiting Professor, 理学部, 客員教授
1999: 広島大学, 大学院・理学研究科, 教授
1986 – 1999: 広島大学, 理学部, 教授
1986: Hiroshima University, Faculty of Science (Professor), 理学部, 教授
Review Section/Research Field
Principal Investigator
有機化学一般 / Science and Engineering / Organic chemistry / Organic chemistry
Except Principal Investigator
Organic chemistry / 有機化学一般 / 物質変換
Keywords
Principal Investigator
超原子価 / 超原子価化合物 / 有機リン化合物 / アート錯体 / 高配位化合物 / Hypervalency / hypervalency / 5配位炭素化合物 / 渡環相互作用 / ア-ト錯体 … More / hypervalent / 異常原子価 / 公開シンポジウム / 有機典型元素化合物 / ス-パ-オキシド / ビスシリカ-ト / 高歪化合物 / 有機異常原子価 / Reductive Elimination Reaction / Transannular Interaction / Ate Complex / Bismuth / Antimony / Highly Coordinated Compound / Metalloidal Main-group Element / 位置異性化反応 / 三座配位子 / 二座配位子 / シリケ-ト / 還元的脱離反応 / ビスマス / アンチモン / 典型金属 / Oxidation Number / Asymmetric Reaction / Organo-Transitionmetals / <sigma> - <pi> Interaction / Hetero Atom / 酸化数 / 高スピン分子 / 遷移金属 / 不斉反応 / 触媒反応 / 低配位リン化合物 / ヘテロ原子 / 5 coordinate phosphorane / 6 coordinate carbon species / 5 coordinate carbon species / 4 coordinate phosphoranide / 6 coordinate perphosphoranide / hypervalent compound / ホスホラニドアニオン / 6配位リン化学種 / チオキサンテンアレン / 6配位炭素種 / 5配位リン化合物 / 6配位炭素化合物 / 4配位リンアニオン / 6配位リンアニオン / Z-olefin / Wittig reaction / oxidative ring closure / positional isomer / pseudorotation / high coordination / organo-phosphorus compounds / Z-オレフィン合成 / 酸化的閉環 / Z-オレフィン / Wittig反応 / 酸化的関環 / 位置異性体 / 擬似回転 / 高配位 / 1,2-転位反応 / 臭素化 / 環状ケテンシリルアセタール / 位置選択性 / 4H-ピラン / 有機銅試薬 / シロキシピリリウム塩 / 高配位有機ヘテロ原子 / 低配位有機典型元素 / 高配位有機典型金属 / ヘテロ原子化学 / 還元的脱離の選択性 / ハロゲノリシス / プロトノリシス / 位置異性化 / 有機典型金属 / アンチモン-炭素結合 / 加プロトン分解 / 位置異性比 / 6配位アート錯体 / ニトロン / 合成化学 / 環状付加 / 高配位有機リン化合物 / 反結合性軌道 / 6配位 / ウィティッヒ反応 / スピロホスホラン / アピコフィリシティー / 典型金属元素 / 活性1,3-双極子 / スーパーオキシド / ヘテロ元素 / 配位と結合生成 / 典型元素 / リガンドカップリング / リガンドトランスファー / 八面体構造 / 三方両錐構造 / 1,3ー双極子 / 有機と有機金属の接具 / 原子価拡張能 / 電極上電子移動反応 / アンチモンア-ト錯体 / スルフラン / アリルシリカ-ト / 典型元素と遷移金属の接点 / 低配位化合物 … More
Except Principal Investigator
hypervalent / 超原子価 / carbon / boron / tridentate ligand / 炭素 / ホウ素 / 3座配位子 / ハイパーバレント / ヘテロアロマチック / ペルフルオロアルキル / セルロース / 生理活性 / オリゴ糖 / 糖 / ジホスフェン / オクタシラキュバン / synthesis / 合成 / DFT calculation / pentacoordinate / anthracene / SN2反応 / 精密電子密度解析 / 密度汎関数計算 / 炭素密度汎関数計算 / 5配位 / アントラセン / porphyrin / antimony / arsenic / phosphorus / phophorane / pentacoordinate boron species / pentacoordinate carbon species / S_N2反応 / メスバウアー分光 / 反結合性P-O軌道 / アンチアピコフィリシティー / ポルフィリン / アンチモン / ヒ素 / リン / ホスホラン / 5配位ホウ素 / 5配位炭素 / Molecular Orbital Calculations / Organic Stereochemistry / Carbenes / Carbocations / Reaction Intermediate / Selectivity and Reactivity / Transition State Structure / Ground State Structure / 分子軌道法計算 / 有機立体化学 / カルベン / カルボカチオン / 反応中間体 / 選択性と反応性 / 遷移状態構造 / 基底状態構造 / Active species / Pseudo rotation / Higher periodic compound / High coodinate bond / Bulky substituent / Low coodinate bond / Central Dogma / Heteroatom compound / ジカチオン / カチオンラジカル / 多種結合化合物 / 配位子カップリング反応 / 擬回転 / 高配位化合物 / ヘテロ原子間結合 / 活性種 / 凝回転 / 高周期化合物 / 高配位結合 / 嵩高い置換基 / 低配位結合 / セントラルドグマ / ヘテロ原子化合物 / ヘテロ原子 / 電子授受 / 不安定分子種 / 分子認識場 / 動的性質 / 分子設計理論 / 分子設計 / 機能開発 / 反応 / 有機ヘテロ原子化合物 / ポリフィリン / ポリカルコゲニド / ポリシラン / 高周期元素多重結合 / 複素環化合物 / 典型元素カチオン種 / 低配位典型元素化合物 / 高配位典型元素化合物 / 有機電導体 / 機能性物質 / 生理活性物質 / 医薬 / 硫黄 / ポルフィリン錯体 / チトクロームP-450 / 複合酸化物触媒 / メタノール / アンチモン-炭素σ結合 / ルテニウムオキソ中間体 / プロパン部分酸化 / リン酸鉄触媒 / プロパンの脱水素反応 / Sb-ポルフィリン錯体 / アルカンからのケトン合成 / 触媒的酢酸合成 / 酢酸パラジウム / メタノール直接合成 / メタン / 有機活性種 / 反応性有機金属分子 / 有機金属活性分子 / 有機典型金属分子 / 有機遷移金属分子 / 有機金属分子の創製 / シラシクロペンタジエン / 高電導性有機錯体 / ジホスホラン / アリルエ-テル / オクタキュバン / ペリプラノンB / スルフラン / 環状ポリシラン / ホススファアレン / 10ーSー3スルフラン / 分子力学パラメ-タ- / 束縛回転 / ジゲルミラン / ゲルモ-ル / ジホスファアレン / シリラン / ジゲルメン / オクタシルセスキオキサン / スピントラップ / トリチアペンタレン / カルボニルアニオン / カルボニル化 / 触媒反応 / 環変換 / 立体選択的合成 / ヘテロ環合成 / 分子変換 / 増炭素反応 Less
  • Research Projects

    (34 results)
  • Research Products

    (8 results)
  • Co-Researchers

    (66 People)
  •  Innovation of 6 Coordinate Hypervalent Compounds Bearing Carbon and Phosphorus as Central AtomsPrincipal Investigator

    • Principal Investigator
      AKIBA Kin-ya
    • Project Period (FY)
      2005 – 2006
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Organic chemistry
    • Research Institution
      Waseda University
  •  15族元素を中心原子とするヘテロ環状有機超原子価化合物の合成と反応Principal Investigator

    • Principal Investigator
      多田 愈, 秋葉 欣哉
    • Project Period (FY)
      2002 – 2003
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Review Section
      Science and Engineering
    • Research Institution
      Waseda University
  •  Creation of Hypervalent Carbon Species : Study on Bond Formation and Interaction

    • Principal Investigator
      YAMAMOTO Yohsuke
    • Project Period (FY)
      2002 – 2003
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Organic chemistry
    • Research Institution
      HIROSHIMA UNIVERSITY
  •  15族元素を中心原子とするヘテロ環状有機超原子価化合物の合成と反応Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      2001
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas (A)
    • Review Section
      Science and Engineering
    • Research Institution
      Waseda University
  •  Design and Synthesis of Novel Multidentate Ligands-Application to Main Group Elements and Transition Metal Chemistry-

    • Principal Investigator
      YAMAMOTO Yohsuke
    • Project Period (FY)
      2000 – 2001
    • Research Category
      Grant-in-Aid for Scientific Research (A)
    • Research Field
      物質変換
    • Research Institution
      Hiroshima University
  •  新規典型元素化合物の創出と元素特性発現の探究

    • Principal Investigator
      川島 隆幸
    • Project Period (FY)
      1999
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Organic chemistry
    • Research Institution
      The University of Tokyo
  •  Design for Novel Organo Hypervalent CompoundsPrincipal Investigator

    • Principal Investigator
      TAKAHASHI Masashi, 秋葉 欣哉
    • Project Period (FY)
      1999 – 2000
    • Research Category
      Grant-in-Aid for Scientific Research (A).
    • Research Field
      Organic chemistry
    • Research Institution
      TOHO UNIVERSITY
      Hiroshima University
  •  Elucidation of Novel Character of HIgh Coordinate Organo-phosphorus Compounds and Their Use to Wittig ReactionPrincipal Investigator

    • Principal Investigator
      AKIBA Kin-ya
    • Project Period (FY)
      1997 – 1998
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Organic chemistry
    • Research Institution
      Hiroshima University
  •  SELECTIVITY AND REACTIVITY OF ORGANIC REACTIONS CONTROLLED BY THE COMBINED EFFECTS OF GROUND AND TRANSITION STATES

    • Principal Investigator
      TAKEUCHI Ken'ichi
    • Project Period (FY)
      1995 – 1996
    • Research Category
      Grant-in-Aid for Scientific Research (A)
    • Research Field
      Organic chemistry
    • Research Institution
      KYOTO UNIVERSITY
  •  メタンの活性化とそれを用いた有機合成反応

    • Principal Investigator
      藤元 薫
    • Project Period (FY)
      1994
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      The University of Tokyo
  •  有機硫黄化学の基礎および応用的研究

    • Principal Investigator
      岡崎 廉治
    • Project Period (FY)
      1994
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Field
      Organic chemistry
    • Research Institution
      The University of Tokyo
  •  Studies on the Establishment of the Central Dogma for Heteroatom Chemistry

    • Principal Investigator
      FURUKAWA Naomichi
    • Project Period (FY)
      1994 – 1995
    • Research Category
      Grant-in-Aid for Co-operative Research (A)
    • Research Field
      Organic chemistry
    • Research Institution
      University of Tsukuba
  •  有機典型元素化合物の異常原子価Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1992 – 1993
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  高配位典型金属化合物の異常原子価Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1992
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  ヘテロ原子の特性を利用する分子設計

    • Principal Investigator
      安藤 亘
    • Project Period (FY)
      1991
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      University of Tsukuba
  •  有機典型元素化合物の異常原子価Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1991
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  高配位典型金属化合物の異常原子価Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1991
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  有機活性種の創製と機能制御

    • Principal Investigator
      村橋 俊一
    • Project Period (FY)
      1991
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Field
      有機化学一般
    • Research Institution
      Osaka University
  •  ヘテロ原子の特性を利用する分子設計

    • Principal Investigator
      安藤 亘
    • Project Period (FY)
      1990
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      University of Tsukuba
  •  高配位典型金属化合物の異常原子価Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1990
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  有機典型元素化合物の異常原子価Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1990
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  有機典型元素化合物の異常原子価に関する総合研究Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1989
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Institution
      Hiroshima University
  •  新増炭素手法による分子変換

    • Principal Investigator
      大城 芳樹
    • Project Period (FY)
      1989
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Osaka University
  •  ヘテロ原子の特性を利用する分子設計

    • Principal Investigator
      ANDO Wataru
    • Project Period (FY)
      1989
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      University of Tsukuba
  •  分子設計の基礎と展開に関する総合研究

    • Principal Investigator
      村田 一郎
    • Project Period (FY)
      1988
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Institution
      Osaka University
  •  シロキシピリリウム塩とソフトな求核試剤による新規な増炭反応Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1988
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  Construction of Hypervalent Organometalloidal Systems in Main-group Elements and Exploration of their New ReactionsPrincipal Investigator

    • Principal Investigator
      AKIBA Kin-ya
    • Project Period (FY)
      1988 – 1989
    • Research Category
      Grant-in-Aid for General Scientific Research (B)
    • Research Field
      有機化学一般
    • Research Institution
      HIROSHIMA UNIVERSITY
  •  Hypervalentな有機典型金属系の開発とその還元的脱離の選択性に関する研究Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1987
    • Research Category
      Grant-in-Aid for Special Project Research
    • Research Institution
      Hiroshima University
  •  有機ヘテロ原子化合物の反応と機能開発に関する研究

    • Principal Investigator
      松本 英之, 永井 洋一郎
    • Project Period (FY)
      1987 – 1988
    • Research Category
      Grant-in-Aid for Co-operative Research (A)
    • Research Field
      有機化学一般
    • Research Institution
      Gunma University
  •  有機ヘテロ原子化学の基礎と応用Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1987
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Field
      有機化学一般
    • Research Institution
      Hiroshima University
  •  典型有機金属化合物における特異な高配位系の開発とその機能Principal Investigator

    • Principal Investigator
      秋葉 欣哉
    • Project Period (FY)
      1986
    • Research Category
      Grant-in-Aid for Special Project Research
    • Research Institution
      Hiroshima University
  •  植物系有機炭素資源の化学修飾による機能開発

    • Principal Investigator
      石川 延男
    • Project Period (FY)
      1985 – 1987
    • Research Category
      Grant-in-Aid for Special Project Research
    • Research Institution
      Tokyo Institute of Technology
  •  植物系有機資源の化学修飾による機能開発

    • Principal Investigator
      石川 延男
    • Project Period (FY)
      1985 – 1987
    • Research Category
      Grant-in-Aid for Special Project Research
    • Research Institution
      Tokyo Institute of Technology
  •  Investigation of Common Character in Reactions of Hetero Atoms and OrganometallicsPrincipal Investigator

    • Principal Investigator
      AKIBA Kin-ya
    • Project Period (FY)
      1985 – 1986
    • Research Category
      Grant-in-Aid for Co-operative Research (A)
    • Research Field
      有機化学一般
    • Research Institution
      HIROSHIMA UNIVERSITY

All 2007 2006 2005

All Journal Article

  • [Journal Article] Syntheses, Crystal and Solution Structures, Ligand Exchange and Ligand Coupling Reactions of Mixed Pentaarylantimony Compounds2007

    • Author(s)
      G.Schroeder, T.Okinaka, Y.Mimura, M.Watanabe, T.Matsuzaki, A.Hisaoka, Y.Yamamoto, S.Matsukawa, K-y.Akiba
    • Journal Title

      Chem. Eur. J. 13

      Pages: 2517-2529

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17550048
  • [Journal Article] A New Method for the Formation of Anti-Apicopholic (0-cis) Spirophosphoranes-Kinetic Studies on the Stereomutation of 0-cis Arylspirophosphoranes to Their O-trans Isomers2006

    • Author(s)
      K Kajiyama, M.Yoshimune, S.Kojima, K-y.Akiba
    • Journal Title

      Eur. J. Org. Chem.

      Pages: 2739-2746

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17550048
  • [Journal Article] The Ligand-Exchange Process of P-Hapical Phosphoranes and the Thermal Formation and Pseudorotation of Anti-Apicophilic Spirophosphoranes2006

    • Author(s)
      S.Kojima, K Kajiyama, M.Nakamoto, S.Matsukawa, K.-y.Akiba
    • Journal Title

      Eur. J. Org. Chem.

      Pages: 218-234

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17550048
  • [Journal Article] Synthesis and Characterization of Stable Hypervalent Carbon Compounds (10-C-5) Bearing a 2,6-Bis(p-substituted phenyloxymethyl)benzene Ligand2005

    • Author(s)
      X-ray Analysis, DFT Calculation K-y..Akiba, Y.Yoriyama, M.Mizozoe, H.Inohara, T.Nishii, Y.Yamamoto, M.Minoura, D.Hashizume, F.Iwasaki, N.Takagi, K Ishimura, S.Nagase
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 5893-5901

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17550048
  • [Journal Article] Synthesis and Characterization of Stable Hypervalent Carbon Compounds (10-C-5)2005

    • Author(s)
      Akiba, K.-y., Yamamoto, Y., Iwasaki, F., Nagase, S.
    • Journal Title

      Journal of American Chemical Society 127

      Pages: 5893-5901

    • Data Source
      KAKENHI-PROJECT-17550048
  • [Journal Article] Synthesis and Characterization of Stable Hypervalent Carbon Compounds (10-C-5) Beraring a 2,6-Bis(p-substituted phenyloxymethyl)benzene Ligand2005

    • Author(s)
      秋葉 欣哉
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 5893-5901

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-17550048
  • [Journal Article] Syntheses and Structures of Hypervalent Pentacoordinate Carbon and Boron Compounds Bearing an Anthracene Skeleton-Elucidation of Hypervalent Interaction Based on2005

    • Author(s)
      M.Yamashita, Y.Yamamoto, K-y.Akiba, D.Hashizume, F.Iwasaki, N.Takagi, S.Nagase
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 4354-4371

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-17550048
  • [Journal Article] Syntheses and Strucrues of Hypervalent Pentacoordinate Carbon and boron compounds2005

    • Author(s)
      Yamashita, M., Yamamoto, Y., Akiba, K.-y.
    • Journal Title

      Journal of American Chemical Society 127

      Pages: 4354-4371

    • Data Source
      KAKENHI-PROJECT-17550048
  • 1.  FURUKAWA Naomichi (80015966)
    # of Collaborated Projects: 7 results
    # of Collaborated Products: 0 results
  • 2.  ANDO Wataru (30008429)
    # of Collaborated Projects: 7 results
    # of Collaborated Products: 0 results
  • 3.  TAMAO Kohei (60026218)
    # of Collaborated Projects: 7 results
    # of Collaborated Products: 0 results
  • 4.  YOSHIFUJI Masaaki (90011676)
    # of Collaborated Projects: 6 results
    # of Collaborated Products: 0 results
  • 5.  中村 晃 (80029404)
    # of Collaborated Projects: 4 results
    # of Collaborated Products: 0 results
  • 6.  松本 英之 (90008467)
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  • 11.  OKAZAKI Renji (70011567)
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  • 23.  SUZUKI Hitomi (50025342)
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  • 59.  佐藤 瀏 (00003872)
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  • 60.  TAKEUCHI Ken'ichi (50026358)
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  • 66.  KIKUTI Yasuaki (00434283)
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