TOMIOKA Hideo 富岡秀雄

Researcher Number	20024599
Other IDs
External Links
Affiliation (based on the past Project Information) *help	2007 – 2008: Aichi Institute of Technology, 工学部, 教授 2006: 愛知工業大学, 工学部, 客員教授 1987 – 2004: 三重大学, 工学部, 教授 2000: 三重大, 工学部, 教授 1999: 三重大学, 工学研究科, 教授
Review Section/Research Field	Principal Investigator Organic chemistry / 有機化学一般 / Chemistry / 物質変換 / Organic chemistry Except Principal Investigator 有機化学一般 / Organic chemistry / 広領域 / Synthetic chemistry / 工業物理化学 / 物質変換
Keywords	Principal Investigator 光分解 / 寿命測定 / ジアリールカルベン / 立体保護 / 閃光光分解 / SQUID / Matrix Isolation Spectroscopy / カルベンーヘテロ原子相互作用 / Stevens転位 / 低温マトリックス分離分光法 … More / 速度論的安定化 / ジアゾ化合物 / ESR / ポリジアゾ化合物 / 磁気的測定 / Laser Flash Photolysis / Lifetime Measurement / PVM / TCGMSG / GAMESS / Gaussian / ミセル / 二分子膜 / ポリイオン錯体 / メロシアニン会合体 / 長鎖アルキル基の効果 / 水溶性スピロピラン / キャストフィルム / 分子内イリドの発生 / oーキノジメタン / 真空フラッシュ熱分解 / 閃光々分解 / イリドの分子内的発生 / 極低温マトリックス分離分光法 / ジクロロカルベンの発生 / CーH挿入 / つっかい効果 / 低温マトリクス分光法 / 長寿命三重項カルベン / 高スピンポリカルベン / 有機磁性素材 / 開殻電子構造 / 熱力学的安定化 / レーザ閃光光分解 / 電子スピン共鳴スペクトル / ジラジカル / 電子状態 / 電子構造 / 理論計算 / マトリクス分離分光法 / 光化学 / 閉環反応 / 開環反応 / マトリクス分離分光 / ホトクロミズム特性 / 置換基効果 / 溶媒効果 / ミセル効果 / ジフェニルカルベン / フルオレニリデン / カルベンの寿命測定 / カルボニルオキシド / H-引き抜き-転位-再結合 / オルト効果 / 隣接基関与 / 低温マトリックス合離 / ジデュリールカルベン / トリプチシルカルベン / カルベのフィリシティー / フォトクロミズム特性 / ミセルの効果 / ナフトピラン / 段階的発色の検討 / 不安定分子先駆体の合成 / 不安定分子の理論計算 / 不安定分子の反応解析 / 不安定分子の直接観測 / 低温マトリックス分離光法 / Theoretical Prediction / Analysis of Reaction of Unstable Molecules / Direct Observation of Unstable Molecules / Neutral Divalent Species / Strained Molecules / Peroxides / 02Synthesis of precursors Generating Unstable Molecules / レーザー閃光々分解 / マトリックス分離分解法 / 光化学反応中間体 / アリールナイトレン / デヒドロアゼピン / レーザー / フラッシュ閃光光分解 / マトリックス分離分光法 / YAGレーザー / フラッシュ閃光分解 / Transient Organic Photoproducts / Diarylcarbenes / Arylnitrenes / Dehydroazepines / トリプチシル(アリール)カルベン / ビス(エタノテトラヒドロアントリル)カルベン / ESR測定 / レーザ閃光々分解 / 生成物分析 / 低温マトリックス分光法 / 構造解析 / レーザ閃光々分析 / ビス(エタノテトラヒドロアントラセニル)カルベン / Triptycyl (aryl) carbene / Bis [(ethanotetrahydro) anthnyl] carbene / ESR Measurement / Product Analysis / Structural Analysis / MO理論計算 / ソフトウエア / インターフェイス / メニュー画面 / ユーザーフレンドリー / 開殻有機分子 / ラジカル / 三重項カルベン / Molecular Orbital Theoretical Calculations / Software / Interface / Menue / User-Friendly / Open-shell Organic Molecules / Radicals / Triplet Carbenes / 立体保護基の開発 / ポリジアゾ化合物の合成 / ポリカルベンの発生 / トリフルオロメチル基 / トリブチシル基 / ポリカルベン / ビシクロオクチル基 / Kinetic Stabilization / Steric Protectors / Poly (diazo) Compounds / Polycarbenes / Electron Spin Resonance / Photolysis / パラレル化 / 量子化学計算 / 大規模有機分子 / MPI / Parallelization / Molecular Orbital Calculations / Large Molecules … More Except Principal Investigator カルベン / 有機磁性体 / 反応中間体 / 炭化水素塩 / 電子移動 / Carbene / ラジカル / 磁場効果 / ラジカルカチオン / 有機強磁性体 / 分子場 / 反応場 / 包接結晶反応 / マトリックス / 生体反応モデル / 立体保護 / 分子軌道計算 / ナイトレン / 反応性中間体 / ラジカルイオン / シリレン / silylene / 固相反応 / 不斉合成 / 超高圧反応 / フラッシュ気相熱分解 / プラズマ / フラーレン / Plasma / 有機合成 / 高スピン有機分子 / ESRスペクトル / カルベン・ナイトレン / 有機フエリ磁性体 / 有機安定高スピン種 / 強磁性的分子間相互友用 / ヘキサキスカルベン / 基底三重項カルベン / カルバイン / カルベンラジカルイオン / 高次原子価欠損 / 光応答分子 / ホトクロミック / 結晶の光化学 / 光DNA切断 / 化学発光 / 光機能分子 / 生物発光 / 構造有機化学 / 物性有機化学 / 物性科学 / 非局在電子系 / 分子磁性 / 安定ラジカル / 安定カルベン / 磁気双安定性 / 不斉分子磁石 / スピン発生 / 開殻分子種 / 磁気的相互作用 / 反磁性 / 強磁性 / 常磁性 / イオンラジカル / スピンラダー / スピンクロスオーバー / ビラジカル / 有機強磁性 / 光補集系 / 高効率電子移動 / 人工光合成反応 / カルベン錯体 / ゲルミレン / アリ-ルカルベン / アルキルフルオロカルベノイド / アリルカルベン白金錯体 / 二原子価欠損型反応活性種 / フィッシャ-型カルベン / メタセシス / metal-carbene complex / carbene / qermylene / arylcarbene / MO calculation / alkylfluorocarbenoid / allylcarbene-Pt / 不斉反応 / シリコンクラスタ- / Molecular transformation / Reactive environment / Crystalline field reaction / Matrix / Inclusion Crystal / Transition metal complex / Silicon cluster / Steric protection / 置換基効果 / ヘテロ元素化合物 / 立体化学 / 反応速度 / 光化学反応 / Substituent effect / Heteroatom Compounds / Stereochemistry / Asymmetric Synthesis / Kinetics / Photochemical reaction / Electron transfer / Reaction intermediate / 超音波化学 / クラウンエーテル / 芳香族求核置換反応 / ヌクレオシド / カルベル / High pressure reaction / Sonochemistry / Flash vacuum pyrolysis / Crown Ethers / Hybrid film / Hydrolysis / 異常活性分子 / カルベン金属類似体 / ケイ素フラーレン / 活性異常分子 / 極低温マトリックス / 歪化合物 / 反応性ケイ素種 / 活性分子 / 異常原子価 / 高歪み化合物 / 活性種 / 反芳香族性 / π-共役 / 歪み化合物 / 活性中間体 / ヘテロ原子 / 機能性有機材料 / 反応制御 / fullerene / reactive intermediate / unusual reactions / strained compounds / perooxysulfinate / long triplet carbene / 超音波 / ラジカル反応 / 有機官能基変換 / 極限反応 / Organic Synthesis / High Pressure Reaction / Ultrasonic Reaction / Flash Vapor Pyrolysis / Radical Reaction / Functional Group Transformation / Unusual Methodology / 原子トンネル / 低温化学 / 宇宙化学 / 水素移動 / 水素付加 / 水素引抜 / 原子トンネリング / 水素原子移動 / マトリックスアイソレーション / フリーラジカル / 低温化学反応 / 同位体効果 / 水素移行反応 / 宇宙化学反応 / アルキルラジカル / 星間塵 / 錯体触媒 / Atomic tunneling / Cryogenic chemistry / Cosmic chemistry / Hydrogen transfer / Hydrogen Addition / Hydrogen abstraction / Radical / カルベノイド / ポリシラン / スピン整列 / スピン多重度 / 有機合成反応 / 二原子価欠損型反応性中間体 / Nitrene / Silylene / Carbenoid / C-H Insertion / Spectroscopy / Organic Magnetism Less

Relationship between Structure and Reactivity of Bis(diradicals) Incorporated into Aromatic Compounds. General Views on the Behaviors of Open-Shell・Electronic SystemsPrincipal Investigator
- Principal Investigator
  
  TOMIOKA Hideo
- Project Period (FY)
  2006 – 2008
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Organic chemistry
- Research Institution
  Aichi Institute of Technology
三重項有機分子の安定化とその複合化による磁性分子素材の構築Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  2000 – 2004
- Research Category
  
  Grant-in-Aid for Specially Promoted Research
- Review Section
  
  Chemistry
- Research Institution
  Mie University
炭素-炭素結合の極限に迫る。三重結合の場合Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  2000
- Research Category
  
  Grant-in-Aid for Exploratory Research
- Research Field
  
  物質変換
- Research Institution
  Mie University
位置・時間によるナノオーダー反応制御
- Principal Investigator
  
  高木克彦
- Project Period (FY)
  1999
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  工業物理化学
- Research Institution
  Nagoya University
特異なスピン共役系の関係と展開
- Principal Investigator
  
  小林啓二
- Project Period (FY)
  1998 – 2000
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas (A)
- Research Institution
  The University of Tokyo
構造・物性有機化学の新展開の探索:特異な非局在電子系の創出
- Principal Investigator
  
  中筋一弘
- Project Period (FY)
  1997
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Organic chemistry
- Research Institution
  Osaka University
Preparation of Stable Triplet Carbenes and Its Application to Stable High-Spin MoleculesPrincipal Investigator
- Principal Investigator
  
  TOMIOKA Hideo
- Project Period (FY)
  1997 – 1998
- Research Category
  
  Grant-in-Aid for Scientific Research (A)
- Research Field
  
  Organic chemistry
- Research Institution
  MIE UNIVERSITY
Development of Theoretical Calculation System for Computationally Demanding Molecules with High Cost-PerformancePrincipal Investigator
- Principal Investigator
  
  TOMIOKA Hideo
- Project Period (FY)
  1997 – 1998
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Organic chemistry
- Research Institution
  Mie University
環境場制御に基づく光応答分子系の精密設計
- Principal Investigator
  
  齋藤烈 (斎藤烈 / 斉藤烈)
- Project Period (FY)
  1996
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Kyoto University
Atomic Tunneling in Organic Reactions
- Principal Investigator
  
  ICHIKAWA Tsuneki
- Project Period (FY)
  1996 – 1998
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Hokkaido University
New Material Transformation under Unusual Reaction Conditions
- Principal Investigator
  
  KOTSUKI Hiyoshizo
- Project Period (FY)
  1995 – 1997
- Research Category
  
  Grant-in-Aid for Scientific Research (A)
- Research Field
  
  物質変換
- Research Institution
  Kochi University
Kinetic Stabilization of Triplet Carbenes by Steric ProtectorsPrincipal Investigator
- Principal Investigator
  
  TOMIOKA Hideo
- Project Period (FY)
  1995 – 1996
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Organic chemistry
- Research Institution
  MIE UNIVERSITY
Developement of User-Friendly System of Theoretical Calculations for Organic ExperimentalistsPrincipal Investigator
- Principal Investigator
  
  TOMIOKA Hideo
- Project Period (FY)
  1995 – 1996
- Research Category
  
  Grant-in-Aid for Scientific Research (A)
- Research Field
  
  Organic chemistry
- Research Institution
  MIE UNIVERSITY
安定三重項カルベンの開発とその磁性発現への展開Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  1994
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Mie University
安定三重項カルベンの開発とその磁性発現への展開Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  1993
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Mie University
カルベン型高活性分子
- Principal Investigator
  
  OKU Akira
- Project Period (FY)
  1993
- Research Category
  
  Grant-in-Aid for Co-operative Research (B)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Kyoto Institute of Technology
Reactive and Unusual Molecules
- Principal Investigator
  
  ANDO Wataru
- Project Period (FY)
  1993 – 1995
- Research Category
  
  Grant-in-Aid for Co-operative Research (A)
- Research Field
  
  Organic chemistry
- Research Institution
  University of Tsukuba
ケイ素逆イリドの分光学的キャラクタリゼーションと反応性の解析Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  1992
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Mie University
特異な分子場の設計に基づく物質変換
- Principal Investigator
  
  OKAZAKI Renji
- Project Period (FY)
  1992
- Research Category
  
  Grant-in-Aid for Co-operative Research (B)
- Research Field
  
  有機化学一般
- Research Institution
  The University of Tokyo
Multi-dimentional Analysis of Highly Specific Organic Reactions Governed by the Combinal Influence of Functional Groups
- Principal Investigator
  
  SUZUKI Hitomi
- Project Period (FY)
  1992 – 1993
- Research Category
  
  Grant-in-Aid for Co-operative Research (A)
- Research Field
  
  有機化学一般
- Research Institution
  KYOTO UNIVERSITY
Unusual Methodologies in Chemical Synthesis
- Principal Investigator
  
  MATSUMOTO Kiyoshi
- Project Period (FY)
  1992 – 1993
- Research Category
  
  Grant-in-Aid for Co-operative Research (A)
- Research Field
  
  有機化学一般
- Research Institution
  KYOTO UNIVERSITY
Instrumental Development in Time Resolved Infrared Spectroscopy with Microsecond Time ResolutionPrincipal Investigator
- Principal Investigator
  
  TOMIOKA Hideo
- Project Period (FY)
  1992 – 1993
- Research Category
  
  Grant-in-Aid for Developmental Scientific Research (B)
- Research Field
  
  有機化学一般
- Research Institution
  MIE UNIVERSITY
新規材料の素材としての不安定分子種の設計
- Principal Investigator
  
  竹内賢一
- Project Period (FY)
  1991
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Kyoto University
ケイ素逆イリドの分光学的キャラクタリゼ-ションと反応性の解析Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  1991
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Mie University
新規材料の素材としての不安定分子種の設計
- Principal Investigator
  
  岩村秀
- Project Period (FY)
  1990
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  The University of Tokyo
Molecular Transformation Based on Design of Novel Reaction Environment
- Principal Investigator
  
  OKAZAKI Renji
- Project Period (FY)
  1990 – 1991
- Research Category
  
  Grant-in-Aid for Co-operative Research (A)
- Research Field
  
  有機化学一般
- Research Institution
  The University of Tokyo
スピロピランの分子修飾による高効率機能性フォトクロミック材料の分子設計Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  1989
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Mie University
新規材料の素材としての不安定分子種の設計
- Principal Investigator
  
  IWAMURA Hiizu
- Project Period (FY)
  1989
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  The University of Tokyo
Chemical Behaviors and Synthetic Applications of Hypovalent Organic Metastable Species Under WellーControlled Conditions
- Principal Investigator
  
  TAKAYA Hidemasa
- Project Period (FY)
  1989 – 1990
- Research Category
  
  Grant-in-Aid for Co-operative Research (A)
- Research Field
  
  広領域
- Research Institution
  Kyoto University
Synthesis and Characterization of Unstable Organic Molecules Using Photochemical Process at Low TemperaturePrincipal Investigator
- Principal Investigator
  
  TOMIOKA Hideo
- Project Period (FY)
  1989 – 1990
- Research Category
  
  Grant-in-Aid for Co-operative Research (A)
- Research Field
  
  有機化学一般
- Research Institution
  Mie University
カルベン反応における非結合相互作用の効果とその超安定カルベンの分子設計への応用Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  1988 – 1989
- Research Category
  
  Grant-in-Aid for General Scientific Research (B)
- Research Field
  
  有機化学一般
- Research Institution
  Mie University
スピロピランの分子修飾による高効率機能性フォトクロミック材料の分子設計Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  1988
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Mie University
スピロピランの分子修飾による高効率機能性フォトクロミック材料の分子設計Principal Investigator
- Principal Investigator
  
  富岡秀雄
- Project Period (FY)
  1987
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Mie University
Carbene-Type Reactive Intermediates: Novel Physical Properties and Synthetic Applications
- Principal Investigator
  
  OKU Akira
- Project Period (FY)
  1987 – 1988
- Research Category
  
  Grant-in-Aid for Co-operative Research (A)
- Research Field
  
  広領域
- Research Institution
  Kyoto Institute of Technology

All 2009 2008 2004

All Journal Article Presentation Book

[Book] 最新のカルペン化学2009
- Author(s)
  富岡秀雄
- Total Pages
  356
- Publisher
  名古屋大学出版会
- Data Source
  KAKENHI-PROJECT-18550048
[Book] 最新のカルベン化学2009
- Author(s)
  富岡秀雄
- Total Pages
  356
- Publisher
  名古屋大学出版会
- Data Source
  KAKENHI-PROJECT-18550048
[Book] Tunneling Insertion Reaction of Carbenes(Series on Atomic, Optical, and Plasma Physics, Volume 36)2004
- Author(s)
  Hideo Tomioka
- Publisher
  Springer
- Data Source
  KAKENHI-PROJECT-12002007
[Book] Triplet Carbenes2004
- Author(s)
  Hideo Tomioka
- Publisher
  Wiley, New York
- Data Source
  KAKENHI-PROJECT-12002007
[Journal Article] Photolysis of Benzocyclopente-1, 2-dione Derivatives in Oxygen-Doped Argon Matrix at Low Temperature2009
- Author(s)
  T. Itoh, J. Tatsugi, H. Tomioka
- Journal Title
  
  Bull. Chem. Soc. Jpn 82
  
  Pages: 475-481
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-18550048
[Journal Article] Photolysis of 1, 2-Naphthoquinone in Oxygen-Doped Argon Matrix at Low Temperature2009
- Author(s)
  T. Itoh, J. Tatsugi, H. Tomioka
- Journal Title
  
  Bull. Chem. Soc. Jpn 82(印刷中)
- NAID
  10025118695
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-18550048
[Journal Article] 1-and 2-Nitreno-2-naphthyl-carbenes. A Combined Experimental and Computational Study2008
- Author(s)
  H. Tomioka, N. Nakane, J. Tatsugi
- Journal Title
  
  Bull. Chem. Soc. Jpn 81
  
  Pages: 1629-1637
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-18550048
[Journal Article] 1-and 2-Nitreno-2-naphthylcarbenes. A Combined Experimental and Computational Study2008
- Author(s)
  Hideo Tomioka
- Journal Title
  
  Bull. Chem. Soc. Jpn. 81
  
  Pages: 1629-1637
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-18550048
[Presentation] 1-メチルイサチンの酸素含有Arマトリクス中10Kでの光化学的挙動2008
- Author(s)
  伊藤貴賢, 立木次郎, 富岡秀雄
- Organizer
  第38複素環化学討論会
- Place of Presentation
  広島県民センターふくやま
- Year and Date
  2008-11-22
- Data Source
  KAKENHI-PROJECT-18550048
[Presentation] 1,2,3-インダントリオンの10Kマトリクス中での光化学的挙動2008
- Author(s)
  伊藤貴賢, 立木次郎, 富岡秀雄
- Organizer
  第39回中部化学関係学協会支部連合秋季大会
- Place of Presentation
  名古屋大学
- Year and Date
  2008-11-08
- Data Source
  KAKENHI-PROJECT-18550048

1. IWAMURA Hiizu (10011496)

# of Collaborated Projects: 5 results

# of Collaborated Products: 0 results
2. TAKEUCHI Kenichi (50026358)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
3. TAKAYA Hidemasa (40022644)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
4. KOBAYASHI Keiji (50012456)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
5. OKU Akira (50027885)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
6. ISHIKAWA Mitsuo (20025985)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
7. HIRAI Katsuyuki (80208793)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
8. ANDO Wataru (30008429)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
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TOMIOKA Hideo 富岡 秀雄

Research Projects

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Relationship between Structure and Reactivity of Bis(diradicals) Incorporated into Aromatic Compounds. General Views on the Behaviors of Open-Shell・Electronic SystemsPrincipal Investigator

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三重項有機分子の安定化とその複合化による磁性分子素材の構築Principal Investigator

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炭素-炭素結合の極限に迫る。三重結合の場合Principal Investigator

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Preparation of Stable Triplet Carbenes and Its Application to Stable High-Spin MoleculesPrincipal Investigator

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Development of Theoretical Calculation System for Computationally Demanding Molecules with High Cost-PerformancePrincipal Investigator

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Kinetic Stabilization of Triplet Carbenes by Steric ProtectorsPrincipal Investigator

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Developement of User-Friendly System of Theoretical Calculations for Organic ExperimentalistsPrincipal Investigator

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安定三重項カルベンの開発とその磁性発現への展開Principal Investigator

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安定三重項カルベンの開発とその磁性発現への展開Principal Investigator

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TOMIOKA Hideo 富岡秀雄