KOMURO Takashi 小室貴士

Researcher Number	20396419
Other IDs
Affiliation (Current)	2025: 東北大学, 理学研究科, 講師
Affiliation (based on the past Project Information) *help	2025: 東北大学, 理学研究科, 講師 2021 – 2023: 東北大学, 理学研究科, 講師 2016 – 2020: 東北大学, 理学研究科, 助教 2011 – 2015: 東北大学, 理学(系)研究科(研究院), 助教 2012: 東北大学, 大学院・理学研究科, 助教 2007 – 2009: Tohoku University, Graduate School of Science, Assistant Professor 2006: 東北大学, 大学院理学研究科, 助手
Review Section/Research Field	Principal Investigator Inorganic chemistry / Basic Section 34010:Inorganic/coordination chemistry-related Except Principal Investigator Inorganic chemistry
Keywords	Principal Investigator シリル配位子 / C-H結合活性化 / キレート配位子 / 触媒反応 / N-複素環式カルベン / 触媒 / 金属錯体 / ヒドロホウ素化 / ヒドロシリル化 / 多座配位子 … More / 1,8-ナフチリジン / 結合活性化 / ケイ素配位子 / 支持配位子 / 配位子設計 / 水素化 / 配位不飽和錯体 / ルテニウム錯体 / シリル錯体 / 豊富元素 / キレート錯体 / 複核錯体 / 3d金属錯体 / 可視光駆動 / 脱水素ホウ素化 / ピリジン配位子 / 鉄錯体 / 部分水素化 / C-H重水素化 / 光反応 / 金属－配位子協働作用 / 二核錯体 / 触媒・化学プロセス / 合成化学 / H/D交換 / C-D結合活性化 / ピンサー配位子 / ボリル化 / 窒素配位子 / 遷移金属錯体 / 重水素化 / 小分子活性化 / 官能基化 / ビス(シリル)配位子 / イリジウム錯体 / 金属－ケイ素錯体 / 後周期遷移金属 / キサンテン誘導体 / Si-C結合切断 / 含酸素有機分子 / タングステン錯体 / C-O結合開裂 / 不飽和有機分子 / 三員環錯体 / η3-α-シラベンジル錯体 / 金属／ケイ素錯体 / 反応機構 / ケイ素-炭素結合切断 / タングステン錯体 / モリブデン錯体 / η^3-α-シラベンジル錯体 / 金属/ケイ素錯体 / N-ヘテロ環カルベン配位子 … More Except Principal Investigator ルテニウム錯体 / シリレン錯体 / タングステン錯体 / シラベンジル錯体 / iminoacyl complex / silabenzyl complex / 1,2-migration reaction / cycloaddition reaction / tungsten complex / ruthenium complex / hydrosilylene complex / silylene complex / メタラサイクル / ハロシリレン錯体 / 結合活性化 / 水素架橋錯体 / イミノアシル錯体 / 1,2-転位反応 / 環化付加反応 / ヒドロシリレン錯体 / モリブデン錯体 / ヒドロシリル化 / ヒドロゲルミル化 / 反応機構 / 三重結合 / ジゲルマビニリデン錯体 / ゲルミリン錯体 / ゲルミレン錯体 / 不飽和結合 / 有機金属化学 Less

豊富遷移金属－ケイ素キレート錯体触媒の高機能化と強固結合切断反応への活用Principal Investigator
- Principal Investigator
  
  小室貴士
- Project Period (FY)
  2025 – 2027
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Review Section
  
  Basic Section 34010:Inorganic/coordination chemistry-related
- Research Institution
  Tohoku University
Development of highly reactive complexes of 3d transition metals by use of silicon-based multidentate ligands and exploration of catalytic functions of these complexesPrincipal Investigator
- Principal Investigator
  
  小室貴士
- Project Period (FY)
  2022 – 2024
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Review Section
  
  Basic Section 34010:Inorganic/coordination chemistry-related
- Research Institution
  Tohoku University
Development of Catalysts Bearing Metal Centers Activated by Silicon-Based Supporting Ligands and Their Use for Transformation of C-H BondsPrincipal Investigator
- Principal Investigator
  
  Komuro Takashi
- Project Period (FY)
  2019 – 2021
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Review Section
  
  Basic Section 34010:Inorganic/coordination chemistry-related
- Research Institution
  Tohoku University
Development of Transformations of Inert Bonds Catalyzed by Chelate Complexes Involving Silyl Coordinating MoietiesPrincipal Investigator
- Principal Investigator
  
  Komuro Takashi
- Project Period (FY)
  2016 – 2018
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University
Development and Catalytic Functions of Reactive Metal-Silicon Complexes Supported by Chelate Ligands Bearing a Substitution-Labile MoietyPrincipal Investigator
- Principal Investigator
  
  KOMURO Takashi
- Project Period (FY)
  2013 – 2015
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University
Elucidation of reactivity of new metal/silicon complexes having two types of labile bond and their application as catalystsPrincipal Investigator
- Principal Investigator
  
  KOMURO Takashi
- Project Period (FY)
  2011 – 2012
- Research Category
  
  Grant-in-Aid for Young Scientists (B)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University
Reaction Search and Function Development for the Unsaturated Bonding Systems between Transition Metals and Heavier Group 14 Elements
- Principal Investigator
  
  TOBITA Hiromi
- Project Period (FY)
  2010 – 2012
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University
Development of Catalytic Reactions Promoted by Ruthenium Complexes Having a Multidentate Silyl LigandPrincipal Investigator
- Principal Investigator
  
  KOMURO Takashi
- Project Period (FY)
  2008 – 2009
- Research Category
  
  Grant-in-Aid for Young Scientists (B)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University
Construction of Novel Silicon-Transition Metal Multiple Bonds, Elucidation of the Mechanisms for Their Reactions, and Their Expansion to Catalytic Reactions
- Principal Investigator
  
  TOBITA Hiromi
- Project Period (FY)
  2006 – 2007
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University

[Journal Article] Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles2024
- Author(s)
  Komuro Takashi, Hayasaka Kohei, Takahashi Kasumi, Ishiwata Nozomu, Yamauchi Kota, Tobita Hiromi, Hashimoto Hisako
- Journal Title
  
  Dalton Transactions
  
  Volume: 53 Issue: 9 Pages: 4041-4047
- DOI
  10.1039/d3dt03605g
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22K05123
[Journal Article] Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C-H borylation of arenes2022
- Author(s)
  Komuro Takashi, Mochizuki Daiki, Hashimoto Hisako, Tobita Hiromi
- Journal Title
  
  Dalton Transactions
  
  Volume: 51 Issue: 26 Pages: 9983-9987
- DOI
  10.1039/d2dt01227h
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22K05123
[Journal Article] Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms2022
- Author(s)
  Komuro Takashi、Nakajima Yumiko、Takaya Jun、Hashimoto Hisako
- Journal Title
  
  Coordination Chemistry Reviews
  
  Volume: 473 Pages: 214837-214837
- DOI
  10.1016/j.ccr.2022.214837
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22K05122, KAKENHI-PROJECT-22K05123, KAKENHI-PROJECT-23K23356
[Journal Article] Iridium Complexes with a Naphthyridine-Based Si,N-Ligand: Synthesis and Catalytic Activity toward Olefin Hydrogenation2022
- Author(s)
  Sato Keita, Komuro Takashi, Osawa Tomohiro, Hashimoto Hisako, Tobita Hiromi
- Journal Title
  
  Organometallics
  
  Volume: 41 Issue: 18 Pages: 2612-2621
- DOI
  10.1021/acs.organomet.2c00373
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22K05123, KAKENHI-PROJECT-23K23356
[Journal Article] Catalysts for Regio- and Stereoselective C(sp3)-H Deuteration of Tricyclohexylphosphine with Benzene-d6 Generated via Dehydrochlorination of Chlorido(dihydrido)iridium Complexes Containing a Xanthene-Based Bis(silyl) Chelate Ligand2021
- Author(s)
  Komuro Takashi, Asagami Junpei, Higashi Hironori, Sato Keita, Hashimoto Hisako, Tobita Hiromi
- Journal Title
  
  Organometallics
  
  Volume: 40 Issue: 18 Pages: 3113-3123
- DOI
  10.1021/acs.organomet.1c00359
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-19K05490
[Journal Article] Synthesis of ruthenium-bis(silyl) chelate complexes without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex with bis(hydrosilyl)xanthene and phosphines2020
- Author(s)
  Kitano Takeo，Komuro Takashi，Sato Keita，Tobita Hiromi
- Journal Title
  
  Journal of Organometallic Chemistry
  
  Volume: 919 Pages: 121316-121316
- DOI
  10.1016/j.jorganchem.2020.121316
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-19K05490
[Journal Article] Bifunctional Rhodium Complex Featuring a Silyl-1,8-naphthyridine Si,N-Chelate Ligand: Cooperation of Metal and Pendant Base for Capture and Bond-weakening of BH32020
- Author(s)
  Sato Keita，Komuro Takashi，Hashimoto Hisako，Tobita Hiromi
- Journal Title
  
  Chemistry Letters
  
  Volume: 49 Issue: 11 Pages: 1431-1434
- DOI
  10.1246/cl.200489
- NAID
  130007936899
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-19K05490
[Journal Article] Double and Single Hydroboration of Nitriles Catalyzed by a Ruthenium-Bis(silyl)xanthene Complex: Application to One-Pot Synthesis of Diarylamines and N-Arylimines2019
- Author(s)
  Takeo Kitano, Takashi Komuro, Hiromi Tobita
- Journal Title
  
  Organometallics
  
  Volume: 38 Issue: 7 Pages: 1417-1420
- DOI
  10.1021/acs.organomet.9b00064
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-16K05714, KAKENHI-PROJECT-15H03782
[Journal Article] Silyl-Pyridine-Amine Pincer-Ligated Iridium Complexes for Catalytic Silane Deuteration via Room Temperature C-D Bond Activation of Benzene-d62019
- Author(s)
  T. Komuro, T. Osawa, R. Suzuki, D. Mochizuki, H. Higashi, H. Tobita
- Journal Title
  
  Chemical Communications
  
  Volume: 55 Issue: 7 Pages: 957-960
- DOI
  10.1039/c8cc09178a
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15H03782, KAKENHI-PROJECT-16K05714
[Journal Article] Synthesis and Unique Catalytic Reactivity of Metal Complexes with Chelate-Type Silyl Ligands Connected by Xanthene2018
- Author(s)
  小室　貴士，飛田　博実
- Journal Title
  
  Journal of Synthetic Organic Chemistry, Japan
  
  Volume: 76 Issue: 12 Pages: 1301-1309
- DOI
  10.5059/yukigoseikyokaishi.76.1301
- NAID
  130007529558
- ISSN
  0037-9980, 1883-6526
- Year and Date
  2018-12-01
- Language
  Japanese
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-16K05714
[Journal Article] Diruthenium Complexes with a 1,8-Naphthyridine-based Bis(silyl) Supporting Ligand: Synthesis and Structures of Complexes Containing RuII2(μ-H)2 and RuI2 Cores2018
- Author(s)
  Indra Kusuma, Takashi Komuro, Hiromi Tobita
- Journal Title
  
  Chem. Lett.
  
  Volume: 47 Issue: 4 Pages: 400-403
- DOI
  10.1246/cl.171099
- NAID
  130006638904
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-16K05714, KAKENHI-PROJECT-15H03782
[Journal Article] シリルキレート配位子を持つ金属錯体触媒を用いたC-H結合および小分子の変換に関する最近の展開2017
- Author(s)
  小室　貴士
- Journal Title
  
  Bull. Jpn. Soc. Coord. Chem.
  
  Volume: 70 Pages: 36-39
- NAID
  40021484997
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-16K05714
[Journal Article] Tandem Hydrosilylation/o-C-H Silylation of Arylalkynes Catalyzed by Ruthenium Bis(silyl) Aminophosphine Complexes2017
- Author(s)
  Takeo Kitano, Takashi Komuro, Rikima Ono, Hiromi Tobita
- Journal Title
  
  Organometallics
  
  Volume: 36 Issue: 15 Pages: 2710-2713
- DOI
  10.1021/acs.organomet.7b00528
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-16K05714, KAKENHI-PROJECT-15H03782
[Journal Article] Directed ortho-C-H Silylation Coupled with trans-Selective Hydrogenation of Arylalkynes Catalyzed by Ruthenium Complexes of a Xanthene-Based Si,O,Si-Chelate Ligand, “Xantsil”2016
- Author(s)
  Takashi Komuro, Takeo Kitano, Nobukazu Yamahira, Keisuke Ohta, Satoshi Okawara, Nathalie Mager, Masaaki Okazaki, Hiromi Tobita
- Journal Title
  
  Organometallics
  
  Volume: 印刷中 Issue: 9 Pages: 1209-1217
- DOI
  10.1021/acs.organomet.5b01013
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-25410058, KAKENHI-PROJECT-15H03782, KAKENHI-PROJECT-15K05443, KAKENHI-PROJECT-16K05714
[Journal Article] Direct Conversion of a Si-C(aryl) Bond to Si-Heteroatom Bonds in the Reactions of eta3-alfa-Silabenzyl Molybdenum and Tungsten Complexes with 2-Substituted Pyridines2015
- Author(s)
  Y. Kanno, T. Komuro, H. Tobita
- Journal Title
  
  Organometallics
  
  Volume: 34 Issue: 15 Pages: 3699-3705
- DOI
  10.1021/acs.organomet.5b00335
- Peer Reviewed / Open Access
- Data Source
  KAKENHI-PROJECT-15H03782, KAKENHI-PROJECT-25410058
[Journal Article] Synthesis of Ruthenium Complexes with a Nonspectator Si,O,P-Chelate Ligand: Interconversion between a Hydrido(η2-silane) Complex and a Silyl Complex Leading to Catalytic Alkene Hydrogenation2015
- Author(s)
  Takashi Komuro, Takafumi Arai, Kei Kikuchi, Hiromi Tobita
- Journal Title
  
  Organometallics
  
  Volume: 34 Issue: 7 Pages: 1211-1217
- DOI
  10.1021/om5011885
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-25410058
[Journal Article] Insertion of carbon monoxide into an aldehyde C=O double bond induced by an (η3-α-silabenzyl)carbonylmolybdenum complex2014
- Author(s)
  Yuto Kanno, Takashi Komuro, Hiromi Tobita
- Journal Title
  
  RSC Advances
  
  Volume: 4 Issue: 37 Pages: 19068-19071
- DOI
  10.1039/c4ra02308k
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-25410058
[Journal Article] Synthesis of a 14-electron iridium(III) complex with a xanthene-based bis(silyl) chelate ligand (xantsil): A distorted seesaw-shaped four-coordinate geometry and reactions leading to 16-electron complexes2014
- Author(s)
  Takashi Komuro, Keisuke Furuyama, Takeo Kitano, Hiromi Tobita
- Journal Title
  
  Journal of Organometallic Chemistry
  
  Volume: 751 Pages: 686-694
- DOI
  10.1016/j.jorganchem.2013.09.009
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-25410058
[Journal Article] Synthesis, Structure, and Reactions of a (η^3-α-silabenzyl)molybdenum Complex: A Synthetic Equivalent of a Coordinatively Unsaturated Silyl Complex2013
- Author(s)
  小室貴士,菅野雄斗,飛田博実
- Journal Title
  
  Organometallics
  
  Volume: 32巻 Issue: 9 Pages: 2795-2803
- DOI
  10.1021/om400225j
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-23750053, KAKENHI-PROJECT-25410058
[Journal Article] (η^3-α-Silabenzyl)tungsten Complexes: An Isolable Intermediate for Interconversion between a Silylene Complex and a Silyl Complex through 1,2-Aryl Migration2013
- Author(s)
  E. Suzuki, T. Komuro, Y. Kanno, and H. Tobita
- Journal Title
  
  Organometallics
  
  Volume: 32 Issue: 3 Pages: 748-751
- DOI
  10.1021/om4000105
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22350024, KAKENHI-PROJECT-23750053
[Journal Article] Silane(silyl) and Bis(silyl)hydrido Manganese Complexes with Different Mn…H…Si Interaction: Observation of Gradual Si-H Bond Activation on the Metal Center2012
- Author(s)
  小室　貴士
- Journal Title
  
  Chemistry Letters
  
  Volume: 41 Issue: 8 Pages: 774-776
- DOI
  10.1246/cl.2012.774
- NAID
  10030947051
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22350024, KAKENHI-PROJECT-23750053
[Journal Article] Synthesis and Characterisation of HydridoMolybdenum and Tungsten ComplexesHaving a Hemilabile Tridentate Si,Si,O-Ligand: Observation of StepwiseHydrosilylation of a Nitrile to Form an N-Silylimine on the Metal2011
- Author(s)
  CentreT. Komuro, R. Begum, R. Ono, and H. Tobita
- Journal Title
  
  Dalton Trans
  
  Volume: 40 Issue: 10 Pages: 2348-2357
- DOI
  10.1039/c0dt01047b
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22350024
[Journal Article] Synthesis and Characterisation of Hydrido Molybdenum and Tungsten Complexes Having a Hemilabile Ttidentate Si, Si, OLigand : Observation of Stepwise Hydrosilylation of Nitrile to Form NSilylimine on the Metal Centre2011
- Author(s)
  小室貴士
- Journal Title
  
  Dalton Trans.
  
  Pages: 2348-2357
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22350024
[Journal Article] Thermal reaction of a ruthenium bis(silyl) complex having a lutidine-based Si, N, Si ligand: formation of aμ-silyl(μ-silylene) diruthenium complex involving a 3c-2e Ru-Si-C interaction2010
- Author(s)
  T. Komuro, H. Tobita
- Journal Title
  
  Chem. Commun. 46
  
  Pages: 1136-1137
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20750040
[Journal Article] Synthesis and Characterization ofκ2C, N-N-Silyliminoacyl Tungsten Complexes Cp*(CO)2W{κ2C, N-C(R)=NSiR´3} [R = Me, Et, i-Pr, t-Bu; R´3 = (p-Tol)2Me, (p-Tol)3, Et3; Cp* =η5-C5Me5]: Thermally Induced Carbon-Carbon Bond Cleavage of Their Iminoacyl Ligands2010
- Author(s)
  E. Suzuki, T. Komuro, Y. Kanno, M. Okazaki, H. Tobita
- Journal Title
  
  Organometallics 29
  
  Pages: 1839-1848
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20750040
[Journal Article] Thermal reaction of a ruthenium bis(silyl)complex having a lutidine-based Si,N,Si ligand : formation of a μ-silyl(μ-silylene)diruthenium complex involving a 3c-2e Ru-Si-C interaction2010
- Author(s)
  小室貴士
- Journal Title
  
  Chem.Commun. 46
  
  Pages: 1136-1137
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20750040
[Journal Article] Synthesis and Structures of Alkynylchlorocyclotriphosphazenes and Their Cluster-forming Reactions with Octacarbonyldicobalt2009
- Author(s)
  T. Komuro, K. Mori, H. Tobita
- Journal Title
  
  Heterocycles 77
  
  Pages: 1171-1183
- NAID
  40016454352
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20750040
[Journal Article] Synthesis and Characterization of DMAP-Stabilized Aryl(silylene) Complexes and (Arylsilyl)(DMAP) Complexes of Tungsten: Mechanistic Study on the Interconversion between These Complexes via 1, 2-Aryl Migration2009
- Author(s)
  E. Suzuki, T. Komuro, M. Okazaki, H. Tobita
- Journal Title
  
  Organometallics 28
  
  Pages: 1791-1799
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20750040
[Journal Article] Synthesis and Structures of Allcynylchlorocyclotriphosphazenes and Their Cluster-forming Reactions with Octacarbonyldicobalt2009
- Author(s)
  小室貴士
- Journal Title
  
  Heterocycles 77
  
  Pages: 1171-1183
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20750040
[Journal Article] New Hydrosilylation Reaction of Arylacetylene Accompanied by C-H Bond Activation Catalyzed by a Xantsil Ruthenium Complex2008
- Author(s)
  H. Tobita, N. Yamahira, K. Ohta, T. Komuro, M. Okazaki
- Journal Title
  
  Pure Appl. Chem. 80
  
  Pages: 1155-1160
- NAID
  120006653839
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20750040
[Journal Article] Recombination of an Fe-Si-P Linkage to an Fe-P-Si Linkage through an Isolable Intermediate Phosphasilaferracyclopropane2008
- Author(s)
  M. Okazaki, T. Yoshitomi, J. Naito, A. Sato, T. Komuro, H. Tobita
- Journal Title
  
  J. Am. Chem. Soc. 130
  
  Pages: 17674-17675
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20750040
[Journal Article] [Ru(xantsil)(CO)(η^6-toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand [xantsil=(9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyI)]2008
- Author(s)
  M. Okazaki, N. Yamahira, J. J. G. Minglana, T. Komuro, H. Ogino, H. Tobita
- Journal Title
  
  Organometallics 27
  
  Pages: 918-926
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Journal Article] A New Hydrosilylation Reaction of Arylacetylene Accompanied by C-H. Bond Activation Catalyzed by a Xantsil Ruthenium Complex2008
- Author(s)
  H. Tobita, N. Yamahira, K. Ohta, T. Komuro, M. Okazaki
- Journal Title
  
  Pure Appl. Chem. 80
  
  Pages: 1155-1160
- NAID
  120006653839
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Journal Article] Synthesis, Structure, and Properties of Three-and Six-Membered Metallacycles Composed of Iron, Germanium, and Sulfur Atoms2007
- Author(s)
  M. Okazaki, H. Kimura, T. Komuro, H. Okada, H. Tobita
- Journal Title
  
  Chem. Lett. 36
  
  Pages: 990-991
- NAID
  10019743987
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Journal Article] The First Resonance Hybrid of Silyl-Carbene and Pyridyl-Silylene Complexes: Formation by Aryl C-H Bond Activation of DMAP [4-(Dimethylamino)pyridine] on a Silylene Complex2007
- Author(s)
  R. Begum, T. Komuro, and H. Tobita
- Journal Title
  
  Chem. Lett. 36
  
  Pages: 650-651
- NAID
  10019936073
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Journal Article] Three-and Five-Membered W/C/N Metallacycles Formed by Incorporation of Acetonitrile Molecules into Silyltungsten Intermediates2007
- Author(s)
  E. Suzuki, T. Komuro, M. Okazaki, H. Tobita
- Journal Title
  
  Organometallics 26
  
  Pages: 4379-4382
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Journal Article] Iron, Ruthenium, and Osmium Complexes Supported by the Bis(sily) Chelate Ligand (9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl): Synthesis, Characterization, and Reactivity2007
- Author(s)
  J. J. G. Minglana, M. Okazaki, K. Hasegawa, L. -S. Luh, N. Yamahira, T. Komuro, H. Ogino, H. Tobita
- Journal Title
  
  Organometallics 26
  
  Pages: 5859-5866
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Journal Article] Group 6 Metal Complexes with a Hemilabile Tridentate Xantsil Ligand and Facile Insertion of BuCN into a W-Si Bond [Xantsil=(9, 9-Dimethylxanthene-4, 5-diy)bis(dimethylsilyl)]2006
- Author(s)
  R. Begum, T. Komuro, and H. Tobita
- Journal Title
  
  Chem. Commun.
  
  Pages: 432-433
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Presentation] シリル-NHCキレート鉄錯体の合成およびアルケンのヒドロホウ素化に対する触媒活性2024
- Author(s)
  石渡望，小室貴士，橋本久子
- Organizer
  日本化学会第104春季年会(2024)
- Data Source
  KAKENHI-PROJECT-22K05123
[Presentation] Synthesis, Structures, and Catalytic Activity of Silyl-NHC Chelate Iron Complexes2023
- Author(s)
  Nozomu Ishiwata, Takashi Komuro, Hisako Hashimoto
- Organizer
  令和5年度化学系学協会東北大会および日本化学会東北支部80周年記念国際会議
- Data Source
  KAKENHI-PROJECT-22K05123
[Presentation] Iridium complexes bearing a silyl－1,8-naphthyridine bidentate ligand: synthesis and catalytic activity for hydrogenation of alkenes2022
- Author(s)
  Sato Keita, Komuro Takashi, Osawa Tomohiro, Hashimoto Hisako, Tobita Hiromi
- Organizer
  8th Asian Silicon Symposium
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-22K05123
[Presentation] シリル－NHC二座配位子をもつ鉄錯体: 合成およびニトリルの二重ヒドロホウ素化に対する触媒活性2022
- Author(s)
  早坂光平，小室貴士，橋本久子
- Organizer
  錯体化学会第72回討論会
- Data Source
  KAKENHI-PROJECT-22K05123
[Presentation] へミラビルなSiOSi三座配位子をもつイリジウム錯体：合成およびC(sp3)－H重水素化に対する触媒活性2022
- Author(s)
  小室貴士，麻上淳平，東周論，古山啓介，佐藤啓太，飛田博実，橋本久子
- Organizer
  第68回有機金属化学討論会
- Data Source
  KAKENHI-PROJECT-22K05123
[Presentation] Designing Multidentate Silyl Ligands for Metal Catalysts toward Functionalization of Strong Bonds2022
- Author(s)
  Komuro Takashi
- Organizer
  錯体化学会第72回討論会
- Invited
- Data Source
  KAKENHI-PROJECT-22K05123
[Presentation] Group 9 metal complexes bearing silyl-1,8-naphthyridine Si,N-chelate ligands: synthesis and reactivity based on cooperation of metal and pendant nitrogen base2021
- Author(s)
  Sato Keita, Komuro Takashi, Tobita Hiromi, Hashimoto Hisako
- Organizer
  The 2021 International Chemical Congress of Pacific Basin Societies
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] シリル(1,8-ナフチリジン)ロジウム錯体のボラン付加体の反応性2021
- Author(s)
  佐藤啓太，小室貴士，橋本久子，飛田博実
- Organizer
  日本化学会第101春季年会
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] Iron and ruthenium complexes bearing a silyl(N-heterocyclic carbene) chelate ligand: synthesis and catalysis for double hydroboration of nitriles2021
- Author(s)
  早坂光平, 小室貴士, 橋本久子
- Organizer
  令和3年度化学系学協会東北大会
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] シリルキレート錯体の配位子設計に基づく特異な触媒機能の開発2020
- Author(s)
  小室貴士
- Organizer
  錯体化学若手の会第5回ウェブ勉強会
- Invited
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] シリル(1,8-ナフチリジン)イリジウム錯体を触媒としたアルケンの水素化：金属-塩基性窒素協働作用による活性向上2020
- Author(s)
  佐藤啓太，小室貴士，橋本久子，飛田博実
- Organizer
  錯体化学会第70回討論会
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] キサンテンを基本骨格としたビス（シリル）キレート配位子を持つポリヒドリドレニウム錯体の合成と反応2020
- Author(s)
  東　周論，小室　貴士，飛田　博実
- Organizer
  日本化学会第100春季年会(2020)
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] シリル(1,8-ナフチリジン)二座配位子を持つ9族遷移金属錯体：金属-配位子協働作用に基づく反応性2020
- Author(s)
  佐藤啓太，小室貴士，大沢智博，橋本久子，飛田博実
- Organizer
  第24回ケイ素化学協会シンポジウム
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] A Silyl-1,8-Naphthyridine Iridium Catalyst: Hydrogenation of Alkenes via Metal-Ligand Cooperation2020
- Author(s)
  佐藤啓太，小室貴士，橋本久子，飛田博実
- Organizer
  令和2年度化学系学協会東北大会
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] シリル(1,8-ナフチリジン)多座配位子を持つイリジウムおよびロジウム錯体の合成, 構造および反応2019
- Author(s)
  佐藤　啓太，小室　貴士，飛田　博実
- Organizer
  錯体化学会第69回討論会
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] Synthesis and Properties of Rhenium Complexes Bearing a Bis(silyl)xanthene Ligand2019
- Author(s)
  東　周論，小室　貴士，飛田　博実
- Organizer
  2019年度化学系学協会東北大会
- Data Source
  KAKENHI-PROJECT-19K05490
[Presentation] シリル-NHCキレート配位子を持つイリジウム錯体の合成，構造および反応性2019
- Author(s)
  桜庭　幹太，小室　貴士，飛田　博実
- Organizer
  日本化学会第99春季年会(2019)
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] Silyl-Pyridine-Amine/Pyridine Pincer Ligated Iridium Complexes as Catalysts for C-H/C-D Bond Activation2018
- Author(s)
  Takashi Komuro, Daiki Mochizuki, Tomohiro Osawa, Hiromi Tobita
- Organizer
  43rd International Conference on Coordination Chemistry (ICCC2018)
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] ビス(シリル)キサンテン配位子を持つイリジウム錯体を触媒とするホスフィンの位置選択的なC-H重水素化反応2018
- Author(s)
  東　周論，麻上　淳平，小室　貴士，飛田　博実
- Organizer
  錯体化学会第68回討論会
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] シリル(2,2'-ビピリジン)ピンサー配位子を持つイリジウム錯体の合成および反応性2018
- Author(s)
  望月　大輝，小室　貴士，飛田　博実
- Organizer
  日本化学会第98春季年会
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] Transition-Metal Complexes with Silyl(2,2'-Bipyridine) Pincer Ligands: Synthesis and Catalysis for Functionalization of C-H/C-D Bonds2018
- Author(s)
  Takashi Komuro, Daiki Mochizuki, Hiromi Tobita
- Organizer
  International Congress on Pure & Applied Chemistry (ICPAC) 2018
- Invited / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] シリル(N-ヘテロ環式カルベン)キレート配位子を持つルテニウムカルボニル錯体の合成，構造および性質2018
- Author(s)
  髙橋　香澄，小室　貴士，飛田　博実
- Organizer
  日本化学会第98春季年会
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] Metal Complexes with a Bis(silyl)xanthene Supporting Ligand: Catalysis for Hydroboration of Nitriles and C-H Deuteration of Trialkylphosphine2018
- Author(s)
  Takashi Komuro, Takeo Kitano, Hironori Higashi, Junpei Asagami, Hiromi Tobita
- Organizer
  International Congress on Pure & Applied Chemistry Langkawi (ICPAC Langkawi) 2018
- Invited / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] 16電子ビス(シリル)ルテニウム錯体を触媒としたニトリルのヒドロホウ素化反応2017
- Author(s)
  北野　健夫，小室　貴士，飛田　博実
- Organizer
  第64回有機金属化学討論会
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] Synthesis of precursors of silyl-carbene chelate ligand and their reactions with ruthenium complexes2017
- Author(s)
  髙橋　香澄，小室　貴士，飛田　博実
- Organizer
  平成29年度化学系学協会東北大会
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] Iridium complexes having a bis(silyl) chelate ligand: synthesis and catalysis for C-H deuteration2017
- Author(s)
  小室　貴士，麻上　淳平，飛田　博実
- Organizer
  平成29年度化学系学協会東北大会
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] 16電子ビス(シリル)ルテニウム錯体を触媒としたニトリルのヒドロホウ素化およびヒドロシリル化反応2017
- Author(s)
  北野　健夫，小野　力摩，小室　貴士，飛田　博実
- Organizer
  日本化学会第97春季年会(2017)
- Place of Presentation
  慶應義塾大学日吉キャンパス（神奈川県横浜市）
- Year and Date
  2017-03-16
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] ortho-C-H Silylation/Hydrosilylation of Diarylalkynes Catalyzed by Ruthenium Complexes Bearing a Bis(silyl) Chelate Ligand2017
- Author(s)
  Takashi Komuro, Takeo Kitano, Hiromi Tobita
- Organizer
  18th International Symposium on Silicon Chemistry
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] Arene C-H borylation catalyzed by iridium complexes bearing a silyl-bipyridine pincer ligand2017
- Author(s)
  望月　大輝，小室　貴士，飛田　博実
- Organizer
  平成29年度化学系学協会東北大会
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] シリル-ビピリジンSiNN型ピンサー配位子を有する9族金属錯体の合成および触媒的C-Hホウ素化への応用2017
- Author(s)
  望月　大輝，小室　貴士，飛田　博実
- Organizer
  日本化学会第97春季年会(2017)
- Place of Presentation
  慶應義塾大学日吉キャンパス（神奈川県横浜市）
- Year and Date
  2017-03-18
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] 非対称なビス(シリル)キレート配位子を持つイリジウム錯体の合成，構造および反応2017
- Author(s)
  麻上　淳平，小室　貴士，飛田　博実
- Organizer
  日本化学会第97春季年会(2017)
- Place of Presentation
  慶應義塾大学日吉キャンパス（神奈川県横浜市）
- Year and Date
  2017-03-18
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] キサンテン骨格で連結されたホスフィン(シリル)キレート配位子を持つイリジウム錯体の合成と反応2016
- Author(s)
  菊地　彗，小室　貴士，飛田　博実
- Organizer
  日本化学会第96春季年会(2016)
- Place of Presentation
  同志社大学　京田辺キャンパス（京都府京田辺市）
- Year and Date
  2016-03-25
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] Synthesis and Structures of Dinuclear Late-Transition-Metal Complexes Supported by a Naphthyridine-Based Bis(silyl) Chelate Ligand2016
- Author(s)
  Indra Kusuma，小室　貴士，飛田　博実
- Organizer
  錯体化学会第66回討論会
- Place of Presentation
  福岡大学七隈キャンパス（福岡県福岡市）
- Year and Date
  2016-09-10
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] シリルキレート配位子の金属活性化能を利用した錯体触媒の創製と反応開発2016
- Author(s)
  小室　貴士
- Organizer
  第33回無機・分析化学コロキウム
- Place of Presentation
  東北大学川渡共同セミナーセンター（宮城県大崎市）
- Year and Date
  2016-06-03
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] Unusual Double-Silylation of Arylalkynes Catalyzed by Ruthenium Bis(silyl) Complexes: Development and Mechanistic Studies2016
- Author(s)
  北野　健夫，小室　貴士，飛田　博実
- Organizer
  平成28年度化学系学協会東北大会
- Place of Presentation
  いわき明星大学（福島県いわき市）
- Year and Date
  2016-09-10
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] シラン-ビピリジンSiNN型ピンサー配位子を持つルテニウム錯体：合成およびアルケンとの反応2016
- Author(s)
  望月　大輝，小室　貴士，飛田　博実
- Organizer
  日本化学会第96春季年会(2016)
- Place of Presentation
  同志社大学　京田辺キャンパス（京都府京田辺市）
- Year and Date
  2016-03-24
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] Ruthenium Catalysts Supported by a Xanthene-Based Bis(silyl) Chelate Ligand for C-H Silylation of Diarylalkynes2016
- Author(s)
  Takashi Komuro, Takeo Kitano, Hiromi Tobita
- Organizer
  International Symposium on Pure & Applied Chemistry (ISPAC) 2016
- Place of Presentation
  Kuching, Sarawak, Malaysia
- Year and Date
  2016-08-16
- Invited / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] シリル-ビピリジンピンサー配位子を持つルテニウム錯体の合成，構造およびアルケンとの反応2016
- Author(s)
  望月　大輝，小室　貴士，飛田　博実
- Organizer
  第20回ケイ素化学協会シンポジウム
- Place of Presentation
  安芸グランドホテル（広島県廿日市市）
- Year and Date
  2016-10-07
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] シリルキレート配位子で活性化された金属触媒の創製と不活性結合変換反応の開発2016
- Author(s)
  小室　貴士
- Organizer
  第20回ケイ素化学協会シンポジウム
- Place of Presentation
  安芸グランドホテル（広島県廿日市市）
- Year and Date
  2016-10-08
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] シリルキレート配位子の金属活性化能を利用した錯体触媒の創製と反応開発2016
- Author(s)
  小室　貴士
- Organizer
  第33回無機・分析化学コロキウム
- Place of Presentation
  東北大学川渡共同セミナーセンター（宮城県大崎市）
- Year and Date
  2016-06-03
- Data Source
  KAKENHI-PROJECT-16K05714
[Presentation] SiNN型ピンサー配位子を有する配位不飽和な9族金属錯体の合成：重ベンゼンのC-D結合活性化と触媒的H/D交換2016
- Author(s)
  大沢　智博，小室　貴士，飛田　博実
- Organizer
  日本化学会第96春季年会(2016)
- Place of Presentation
  同志社大学　京田辺キャンパス（京都府京田辺市）
- Year and Date
  2016-03-26
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] 空配位座の発生が容易なSiNNピンサー型配位子を持つIr錯体を用いた触媒的H/D交換反応2015
- Author(s)
  大沢　智博，小室　貴士，飛田　博実
- Organizer
  第5回CSJ化学フェスタ2015
- Place of Presentation
  タワーホール船堀（東京都江戸川区）
- Year and Date
  2015-10-13
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] HemilabileなSiNNピンサー型配位子を有する９族金属錯体の合成と触媒機能2015
- Author(s)
  小室　貴士，大沢　智博，飛田　博実
- Organizer
  第19回ケイ素化学協会シンポジウム
- Place of Presentation
  ラフォーレ琵琶湖（滋賀県守山市）
- Year and Date
  2015-10-23
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] ビス(シリル)キサンテン誘導体xantsilが配位したルテニウム錯体を触媒とするエン-インカップリング反応2015
- Author(s)
  北野健夫，小室貴士，飛田博実
- Organizer
  日本化学会第95春季年会
- Place of Presentation
  船橋
- Year and Date
  2015-03-28
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] SiNNピンサー型配位子を持つイリジウム錯体を触媒としたヒドロシランおよびヒドロボランの重水素化反応2015
- Author(s)
  大沢　智博，小室　貴士，飛田　博実
- Organizer
  錯体化学会第65回討論会
- Place of Presentation
  奈良女子大学（奈良県奈良市）
- Year and Date
  2015-09-21
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] ビス(シリル)ルテニウム錯体を触媒としたアリールアルキンの一段階C-Hシリル化/ヒドロシリル化2015
- Author(s)
  北野　健夫，小室　貴士，飛田　博実
- Organizer
  第62回有機金属化学討論会
- Place of Presentation
  関西大学千里山キャンパス（大阪府吹田市）
- Year and Date
  2015-09-09
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] ビス(シリル)キレート配位子を持つロジウムおよびイリジウム錯体の合成と触媒作用2015
- Author(s)
  麻上　淳平，小室　貴士，飛田　博実
- Organizer
  第19回ケイ素化学協会シンポジウム
- Place of Presentation
  ラフォーレ琵琶湖（滋賀県守山市）
- Year and Date
  2015-10-23
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] C-H silylation reactions of arylalkynes catalyzed by 16-electron ruthenium complexes having a xanthene-based bis(silyl) ligand xantsil2015
- Author(s)
  Takeo Kitano, Takashi Komuro, Hiromi Tobita
- Organizer
  The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
- Place of Presentation
  Honolulu, Hawaii, USA
- Year and Date
  2015-12-17
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] 歪んだシーソー型構造を持つ配位不飽和ロジウムおよびイリジウムビス(シリル)錯体の合成と触媒機能2015
- Author(s)
  麻上　淳平，小室　貴士，飛田　博実
- Organizer
  錯体化学会第65回討論会
- Place of Presentation
  奈良女子大学（奈良県奈良市）
- Year and Date
  2015-09-21
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] Iridium catalyst featuring a hemilabile SiNN-pincer ligand for Si-H deuteration of hydrosilanes with benzene-d62015
- Author(s)
  Takashi Komuro, Tomohiro Osawa, Ryuju Suzuki, Hiromi Tobita
- Organizer
  The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
- Place of Presentation
  Honolulu, Hawaii, USA
- Year and Date
  2015-12-19
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] Si,O,Si型三座配位子を持つルテニウム錯体を触媒としたアリールアルキンのC-Hシリル化反応2014
- Author(s)
  北野健夫，小室貴士，飛田博実
- Organizer
  第18回ケイ素化学協会シンポジウム
- Place of Presentation
  那須
- Year and Date
  2014-10-17
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] ケイ素およびリンを配位原子とするキサンテン誘導体がキレート配位した遷移金属錯体の合成，構造および反応2014
- Author(s)
  小室貴士，新井崇史，菊地彗，飛田博実
- Organizer
  第18回ケイ素化学協会シンポジウム
- Place of Presentation
  那須
- Year and Date
  2014-10-17
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] Ruthenium Complexes Bearing a Non-Spectator Si,O,P-Chelate Ligand: Interconversion between a Hydrido(η2-silane) Complex and a Silyl Complex2014
- Author(s)
  Takashi Komuro, Takafumi Arai, Kei Kikuchi, Hiromi Tobita
- Organizer
  XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
- Place of Presentation
  札幌
- Year and Date
  2014-07-14
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] シリル配位部分を持つキサンテン誘導体がキレート配位した白金錯体の合成および構造2014
- Author(s)
  菊地彗，小室貴士，飛田博実
- Organizer
  錯体化学会第64回討論会
- Place of Presentation
  東京
- Year and Date
  2014-09-18
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] (η^3-α-シラベンジル)モリブデン錯体とアルケンとの反応2013
- Author(s)
  菅野雄斗,小室貴士,飛田博実
- Organizer
  日本化学会第93春季年会
- Place of Presentation
  立命館大学びわこ・くさつキャンパス
- Year and Date
  2013-03-22
- Data Source
  KAKENHI-PROJECT-23750053
[Presentation] An {η^3-α-Silabenzyl}molybdenum Complex: A Synthetic Equivalent of Both Silyl and Silylene Complexes due to the Lability of Its Mo-C and Si-C Bonds2012
- Author(s)
  小室貴士,菅野雄斗,飛田博実
- Organizer
  XXV International Conference on Organometallic Chemistry (ICOMC 2012)
- Place of Presentation
  リスボン,ポルトガル
- Year and Date
  2012-09-04
- Data Source
  KAKENHI-PROJECT-23750053
[Presentation] (η^3-α-シラベンジル)モリブデン錯体とアルデヒドとの反応:触媒的ヒドロシリル化への応用2012
- Author(s)
  菅野雄斗,小室貴士,飛田博実
- Organizer
  第59回有機金属化学討論会
- Place of Presentation
  大阪大学吹田キャンパス
- Year and Date
  2012-09-14
- Data Source
  KAKENHI-PROJECT-23750053
[Presentation] η^3-α-シラベンジル配位子を持つモリブデンおよびタングステン錯体とカルボニル化合物との反応:中心金属の違いが反応性に及ぼす影響2012
- Author(s)
  菅野雄斗,小室貴士,飛田博実
- Organizer
  日本化学会第92春季年会
- Place of Presentation
  慶應義塾大学日吉キャンパス・矢上キャンパス
- Year and Date
  2012-03-26
- Data Source
  KAKENHI-PROJECT-23750053
[Presentation] 金属上でのSi-H結合の段階的活性化:異なるMn…H…Si相互作用を持つ3種類のマンガン錯体の単離と構造決定2011
- Author(s)
  小室貴士,大河原聡,飛田博実
- Organizer
  第58回有機金属化学討論会
- Place of Presentation
  名古屋大学東山キャンパス
- Year and Date
  2011-09-08
- Data Source
  KAKENHI-PROJECT-23750053
[Presentation] 金属上でのSi-H結合の段階的活性化：異なるMn…H…Si相互作用を持つ3種類のマンガン錯体の単離と構造決定2011
- Author(s)
  小室貴士
- Organizer
  第58回有機金属化学討論会
- Place of Presentation
  名古屋
- Data Source
  KAKENHI-PROJECT-23750053
[Presentation] 金属―ケイ素―リン三員環錯体の合成および反応性制御2009
- Author(s)
  小室貴士
- Organizer
  第26回無機・分析化学コロキウム
- Place of Presentation
  大崎
- Year and Date
  2009-06-05
- Data Source
  KAKENHI-PROJECT-20750040
[Presentation] オリゴフェニレンユニットで連結された(イミノアシル)タングステン二核錯体の合成と性質2009
- Author(s)
  小室貴士
- Organizer
  日本化学会第89春季年会(2009)
- Place of Presentation
  船橋
- Year and Date
  2009-03-27
- Data Source
  KAKENHI-PROJECT-20750040
[Presentation] (η^3-α-シラベンジル)タングステン錯体の合成と反応2009
- Author(s)
  小室貴士
- Organizer
  第13回ケイ素化学協会シンポジウム
- Place of Presentation
  唐津
- Year and Date
  2009-10-30
- Data Source
  KAKENHI-PROJECT-20750040
[Presentation] Synthesis and Reactions of(η^3-α-Silabenzyl)tungsten Complexes2009
- Author(s)
  小室貴士
- Organizer
  The 4th International Symposium for Young Elements Chemists 2009 Workshop on Organometallic Chemistry
- Place of Presentation
  春日
- Year and Date
  2009-10-28
- Data Source
  KAKENHI-PROJECT-20750040
[Presentation] Synthesis and Reactivity of Group 6 Metal Complexes Having a Hemilabile Bis(silyl) Chelate Ligand2008
- Author(s)
  小室貴士
- Organizer
  XXIII International Conference on Organometallic Chemistry
- Place of Presentation
  Rennes, France
- Year and Date
  2008-07-17
- Data Source
  KAKENHI-PROJECT-20750040
[Presentation] Silylene Complexes: Versatile Intermediates for the New-Type Activation of Polar Organic Molecules2008
- Author(s)
  M. Ochiai, T. Watanabe, E. Suzuki, H. Hashimoto, T. Komuro, H. Tobita
- Organizer
  The 10th Eurasia Conference on Chemical Sciences(EuAsC2S-10)
- Place of Presentation
  Manila, Philippine
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Presentation] Generation of 16-Electron Tungsten-Sily1 Complexes and Their Reactivity Toward Organic Molecules2008
- Author(s)
  小室貴士
- Organizer
  Global COE and IREMC Symposium on Functional Materials and Analytical Approaches for Molecular Complex Chemistr
- Place of Presentation
  仙台
- Year and Date
  2008-11-06
- Data Source
  KAKENHI-PROJECT-20750040
[Presentation] A New Hydrosilylation Reaction of Arylacetylene Accompanied by C-H Bond Activation Catalyzed by a Xantsil Ruthenium Complex2007
- Author(s)
  K. Ohta, N. Yamahira, T. Komuro, M. Okazaki, H. Tbbita
- Organizer
  14th IUPAC Symposium on Organometallic Chemistry Directed Towards Organic Synthesis(OMCOS14)
- Place of Presentation
  Nara
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18350027
[Presentation] Hydrosilylation of Arylalkynes Catalyzed by Ruthenium-Phosphine Complexes Having a Bis(silyl) Chelate Ligand "Xantsil": Comparison of Their Catalytic Performance Depending on Phosphine Ligands
- Author(s)
  Takeo Kitano, Nathalie Mager, Takashi Komuro, Hiromi Tobita
- Organizer
  International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
- Place of Presentation
  Tohoku University, Sendai
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] An {η3-α-Silabenzyl}molybdenum Complex: A Synthetic Equivalent of Both Silyl and Silylene Complexes due to the Lability of Its Mo-C and Si-C Bonds
- Author(s)
  小室　貴士
- Organizer
  XXV International Conference on Organometallic Chemistry (ICOMC 2012)
- Place of Presentation
  Lisbon, Portugal
- Data Source
  KAKENHI-PROJECT-23750053
[Presentation] アリル錯体を前駆体としたホスフィンビス（シリル）ルテニウム錯体の合成と性質
- Author(s)
  北野健夫，小室貴士，飛田博実
- Organizer
  日本化学会第94春季年会
- Place of Presentation
  名古屋大学東山キャンパス，名古屋
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] キサンテン骨格で連結されたホスフィン（シリル）配位子を持つルテニウム錯体の合成と性質
- Author(s)
  新井崇史，小室貴士，飛田博実
- Organizer
  錯体化学会第63回討論会
- Place of Presentation
  琉球大学千原キャンパス，沖縄
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] SiOSi型三座配位子を持つ16電子ルテニウム-ビス(シリル)錯体の触媒性能に及ぼすホスフィン配位子の効果
- Author(s)
  北野健夫，Mager Nathalie，小室貴士，飛田博実
- Organizer
  第3回CSJ化学フェスタ2013
- Place of Presentation
  タワーホール船堀，東京
- Data Source
  KAKENHI-PROJECT-25410058
[Presentation] Synthesis and Properties of a Ruthenium(II) Complex Bearing a Xanthene-Based Silyl(thiolato) Chelate Ligand
- Author(s)
  Takafumi Arai, Takashi Komuro, Hiromi Tobita
- Organizer
  International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
- Place of Presentation
  Tohoku University, Sendai
- Data Source
  KAKENHI-PROJECT-25410058

1. TOBITA Hiromi (30180160)

# of Collaborated Projects: 2 results

# of Collaborated Products: 12 results
2. HASHIMOTO Hisako (60291085)

# of Collaborated Projects: 2 results

# of Collaborated Products: 1 results
3. WATANABE Takahito (90425413)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
4. NAKAJIMA Yumiko

# of Collaborated Projects: 0 results

# of Collaborated Products: 1 results

KOMURO Takashi 小室 貴士

Research Projects

Research Products

Co-Researchers

豊富遷移金属－ケイ素キレート錯体触媒の高機能化と強固結合切断反応への活用Principal Investigator

Principal Investigator

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Development of highly reactive complexes of 3d transition metals by use of silicon-based multidentate ligands and exploration of catalytic functions of these complexesPrincipal Investigator

Principal Investigator

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Development of Catalysts Bearing Metal Centers Activated by Silicon-Based Supporting Ligands and Their Use for Transformation of C-H BondsPrincipal Investigator

Principal Investigator

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Review Section

Research Institution

Development of Transformations of Inert Bonds Catalyzed by Chelate Complexes Involving Silyl Coordinating MoietiesPrincipal Investigator

Principal Investigator

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Development and Catalytic Functions of Reactive Metal-Silicon Complexes Supported by Chelate Ligands Bearing a Substitution-Labile MoietyPrincipal Investigator

Principal Investigator

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Elucidation of reactivity of new metal/silicon complexes having two types of labile bond and their application as catalystsPrincipal Investigator

Principal Investigator

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Reaction Search and Function Development for the Unsaturated Bonding Systems between Transition Metals and Heavier Group 14 Elements

Principal Investigator

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Research Institution

Development of Catalytic Reactions Promoted by Ruthenium Complexes Having a Multidentate Silyl LigandPrincipal Investigator

Principal Investigator

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Research Institution

Construction of Novel Silicon-Transition Metal Multiple Bonds, Elucidation of the Mechanisms for Their Reactions, and Their Expansion to Catalytic Reactions

Principal Investigator

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Research Institution

[Journal Article] Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles2024

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C-H borylation of arenes2022

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms2022

Author(s)

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DOI

Data Source

[Journal Article] Iridium Complexes with a Naphthyridine-Based Si,N-Ligand: Synthesis and Catalytic Activity toward Olefin Hydrogenation2022

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Catalysts for Regio- and Stereoselective C(sp3)-H Deuteration of Tricyclohexylphosphine with Benzene-d6 Generated via Dehydrochlorination of Chlorido(dihydrido)iridium Complexes Containing a Xanthene-Based Bis(silyl) Chelate Ligand2021

Author(s)

KOMURO Takashi 小室貴士