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KAJIMOTO Okitsugu  梶本 興亜

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Researcher Number 30029483
Other IDs
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Affiliation (based on the past Project Information) *help 2004: Kyoto University, Graduate School of Science Department of Chemistry, Professor, 大学院理学研究科, 教授
1995 – 2004: Kyoto University, Professor, 大学院・理学研究科, 教授
1998: 京都大学, 大学院理学研究科, 教授
1989 – 1997: Kyoto U., Fac. Science Professor, 理学部, 教授
1986 – 1989: 東京大学, 教養学部, 助教授
1986: 東大, 教養部, 助教授
Review Section/Research Field
Principal Investigator
物理化学一般 / Physical chemistry / Physical chemistry
Except Principal Investigator
Physical chemistry / 物理化学一般 / 構造化学
Keywords
Principal Investigator
クラスター / 電子移動反応 / 超臨界流体 / 電荷移動反応 / 溶媒効果 / ファンデルワールス分子 / 超音波ジェット / 内部回転 / Internal rotation / 9,9'-bianthryl … More / Intramolecular charge-transfer reactions / クラスタ- / 超音速ジェット / 内部回転ポテンシャル / ビアントラセン / 回転コヒーレンス / 溶媒和型クラスター / Cluster / 電荷移動 / 光分解 / 分子内反応 / 超音速自由噴流 / matrix / cluster ions / solvent effect / charge-transfer / proton-transfer / supercritical fluid / van der Waals complex / clusters / 異性化反応 / 液相化学反応 / クラスターイオン / 電荷移動錯体 / ファンデルクルース錯体 / ファンデルク-ルス錯体 / マトリックス / クラスタ-イオン / プロトン移動 / ファンデルワ-ルス錯体 / Sub-and supercritical water / Thermal decomposition of nitroethane / Claisen rearrqangement / Activation energy / Rate constants / A high-temperature and high-pressure NMR probe / A flow-NMR probe / 亜臨界水 / 超臨界水 / ニトロアルカンの熱分解 / Claisen転位 / 高温高圧NMR / 流通型NMR / Solvation cluster / Time-resolved fluorescence depletion / 超高速ジェット / 時間依存蛍光スペクトル / ビアントリル / 分子内振動緩和 / 分子内電荷移動反応 / 時間分解蛍光ディップ法 / Supersonic Jet / Charge Transfer Reaction / Internal Rotation / Bianthryl / Rotational Coherence / Rotational coherence spectroscopy / Solvation cluster, / ファンデルワ-ルス分子 / フリ-ジェット / 液相反応 / 回転コヒ-レンス法 / ファンデルクールス分子 / 溶媒和 / 回転コヒーレンス法 / Spectral Shift / Resonance Raman / Supercritical Fluid / Charge-transfer / 共鳴ラマン分光 / スペクトル移動 / 共鳴ラマン / 溶解度 / 電荷移動状態 / ジメチルアミノベンゾニトリル / ベンゾニトリル / LIFスペクトル / 溶媒和数 / O(^1D) / NO / N_2O / 生成物の状態分布 / 配向 / ファンヂルワールス分子 / レーザ誘起けい光 / 発光スペクトル / 分子内電荷移動 / 溶媒和分子 / 分子線 / 電子励起状態 / レーザー誘起蛍光 / 振動・回転エネルギー分布 / 水和金属クラスター / 疎水性水和 / 振動緩和 / SiH_2 / 振動励起 / 光解離 / フェニルシラン … More
Except Principal Investigator
クラスター / 反応動力学 / 亜酸化窒素分子 / 酸素原子 / Reaction Dynamics / 気相素反応 / ドップラー分光 / 微分散乱断面積 / 炭化水素分子 / ベクトル相関 / レーザー分光 / 分子間錯体 / Differential Cross Sections / Doppler Spectroscopy / Hydrocarbon / Nitrous Oxide / Oxygen / 水分子 / 水素分子 / ゆらぎ / カオス / 非線形動力学 / 少数多体系 / 電荷移動 / エキサイプレックス / 超音速ジェット / 溶媒効果 / Elementary chemical process / ウィグナーの閾値則 / TESICO法 / レーザ誘起蛍光 / ファンデルワールス分子 / マイクロ波分光 / 分子交差法 / トンネル効果 / 交叉分子線法 / 遷移状態 / 素反応 / Quasi-classical trajectory calculation / Rovibrational distribution / Gas-phase elementary reaction / Nitrogen molecule / Oxygen molecule / Nitric oxide / Nitrous oxide / Oxygen atom / 古典軌道計算 / 振動回転分布 / 窒素分子 / 酸素分子 / 一酸化窒素分子 / Polarization / Vector Correlation / 回転角運動量 / 偏光ドップラー分光 / 偏光分光 / Water / Hydrogen / physics and chemistry / experiment and theory / microcluster / manybody system / 協同現象 / 物理と化学 / 理論と実験 / molecular solid / semicondcuctor surface / molecular cluster / electronic structure / material chemistry / SOR Application / 星間分子生成 / 放射光・レーザー2重共鳴 / 多次元トンネル / 自由電子レーザー / 高分解能分光 / 分子計算化学 / 分子性固体 / 半導体表面 / 分子和クラスター / 電子構造動力学 / 物質化学 / 放射光利用化学 / Reactions in Solution / Collective Motion / Photodissociation / Electronic Relaxation / Semicalssical Theory / Reactive Scattering / Chemical Reaction / 反応系の集団運動 / 電子励起状態の緩和 / 反応理論 / 化学反応動力学 / 溶液内反応 / 水の集団運動 / 光解離反応 / 電子状態緩和 / 半古典理論 / 反応性散乱 / 化学反応 / ダイナミックス / 分子間相互作用 / 液体構造 / 表面反応 / 反応ダイナミクス / 振動エネルギー再分配 / 回転コヒーレンス / ビアントラセン / 細孔吸着 / 時間分解スペクトル / 分子間ポテンシャル / 分子シミュレーション / 二酸化炭素 / 溶液構造 / 超臨界流体 / 超音速自由膨張 / 光フラグメンテ-ション / クラスタ-イオン / 素反応過程 / 分子間力 / 分子クラスタ- / 求核置換反応 Less
  • Research Projects

    (31 results)
  • Research Products

    (20 results)
  • Co-Researchers

    (49 People)
  •  Development of flow-type high-temperature and high-pressure NMR probe and clarification of chemical reactions in sub-and supercritical waterPrincipal Investigator

    • Principal Investigator
      KAJIMOTO Okitsugu
    • Project Period (FY)
      2003 – 2004
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Physical chemistry
    • Research Institution
      Kyoto University
  •  STUDY OF REACTION DYNAMICS OF O(^1D) ATOM VIA THE COMPLETE ROVIBRATIONAL STATE DISTRIBUTION OF REACTION PRODUCTS

    • Principal Investigator
      FUJIMURA Yo
    • Project Period (FY)
      2001 – 2002
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Physical chemistry
    • Research Institution
      KYOTO UNIVERSITY
  •  STUDY OF REACTION DYNAMICS VIA MEASUREMENTS OF DIFFERENTIAL CROSS SECTIONS DEPENDENT ON ROTATIONAL ANGULAR MOMENTUM POLARIZATION OF REACTION PRODUCTS

    • Principal Investigator
      FUJIMURA Yo
    • Project Period (FY)
      1999 – 2000
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Physical chemistry
    • Research Institution
      KYOTO UNIVERSITY
  •  MEASUREMENTS OF STATE-RESOLVED DIFFERENTIAL CROSS SECTIONS VIA HIGH-RESOLUTION POLARIZED DOPPLER SPECTROSCOPY

    • Principal Investigator
      FUJIMURA Yo
    • Project Period (FY)
      1997 – 1998
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Physical chemistry
    • Research Institution
      KYOTO UNIVERSITY
  •  ファンデルワールス分子を用いて衝突の配向を制御した化学反応-ベクトル相関分光による反応ダイナミックスの解明-

    • Principal Investigator
      藤村 陽
    • Project Period (FY)
      1996
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyoto University
  •  ファンデルワールス分子を用いて衝突の配向を制御した化学反応-ベクトル相関分光による反応ダイナミックスの解明

    • Principal Investigator
      藤村 陽
    • Project Period (FY)
      1995
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyoto University
  •  液相におけるクラスター構造Principal Investigator

    • Principal Investigator
      梶本 興亜
    • Project Period (FY)
      1995 – 1997
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyoto University
  •  Chemistry of manybody system

    • Principal Investigator
      KAYA Koji
    • Project Period (FY)
      1995 – 1998
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Keio University
  •  超臨界流体の溶液構造の解明

    • Principal Investigator
      中西 浩一郎
    • Project Period (FY)
      1994
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyoto University
  •  ファンデルワールス分子を用いて衝突の配向を制御した化学反応-ベクトル相関分光による反応ダイナミックスの解明-

    • Principal Investigator
      藤村 陽
    • Project Period (FY)
      1994
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyoto University
  •  少数多体系の化学

    • Principal Investigator
      茅 幸二
    • Project Period (FY)
      1994
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Field
      Physical chemistry
    • Research Institution
      Keio University
  •  The Structure and Reactions of Large Clusters Studies by The Rotational Coherence MethodPrincipal Investigator

    • Principal Investigator
      KAJIMOTO Okitsugu
    • Project Period (FY)
      1994 – 1995
    • Research Category
      Grant-in-Aid for international Scientific Research
    • Research Institution
      KYOTO UNIVERSITY
  •  Collaborative Research in Five Fields of Molecular Science

    • Principal Investigator
      ITO Mitsuo
    • Project Period (FY)
      1994 – 1995
    • Research Category
      Grant-in-Aid for international Scientific Research
    • Research Institution
      Okazaki National Research Institute
  •  Dynamics of internal rotation related to the intramolecular charge-t transfer reactionsPrincipal Investigator

    • Principal Investigator
      KAJIMOTO Okitsugu
    • Project Period (FY)
      1994 – 1995
    • Research Category
      Grant-in-Aid for General Scientific Research (B)
    • Research Field
      Physical chemistry
    • Research Institution
      KYOTO UNIVERSITY
  •  ポンプ-プローブ法による回転コヒーレンス分光を用いた溶媒和型クラスターの構造決定

    • Principal Investigator
      FUJIMURA Yo
    • Project Period (FY)
      1993
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Field
      Physical chemistry
    • Research Institution
      Kyoto University
  •  An Approach to the microscopic features of liquid phase reactions using solvation clusters of known structurePrincipal Investigator

    • Principal Investigator
      KAJIMOTO Okitsugu
    • Project Period (FY)
      1991 – 1993
    • Research Category
      Grant-in-Aid for General Scientific Research (A)
    • Research Field
      物理化学一般
    • Research Institution
      KYOTO UNIVERSITY
  •  高振動励起状態にあるシラン系ラジカルの反応Principal Investigator

    • Principal Investigator
      梶本 興亜
    • Project Period (FY)
      1990
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyoto University
  •  分子集団の構造と反応における多体効果

    • Principal Investigator
      TSUCHIYA Soji
    • Project Period (FY)
      1990
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Field
      構造化学
    • Research Institution
      The University of Tokyo
  •  光フラグメンテ-ションを用いた二価イオンの解離性電子状態の研究

    • Principal Investigator
      本間 健二
    • Project Period (FY)
      1990
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Field
      構造化学
    • Research Institution
      Himeji Institute of Technology
  •  付着溶媒分子数を規定した二分子反応--求核置換反応における溶媒効果

    • Principal Investigator
      HONMA Kenji
    • Project Period (FY)
      1989
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Field
      物理化学一般
    • Research Institution
      The University of Tokyo
  •  弱い分子間錯体の生成とダイナミックス

    • Principal Investigator
      ITO Mitsuo
    • Project Period (FY)
      1989
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Tohoku University
  •  Theories of Chemical Reaction Dynamics

    • Principal Investigator
      KATO Shigeki
    • Project Period (FY)
      1989 – 1991
    • Research Category
      Grant-in-Aid for Co-operative Research (A)
    • Research Field
      物理化学一般
    • Research Institution
      KYOTO UNIVERSITY
      The University of Tokyo
  •  Charge-transfer State Formation in Supercritical FluidsPrincipal Investigator

    • Principal Investigator
      KAJIMOTO Okitsugu
    • Project Period (FY)
      1989 – 1990
    • Research Category
      Grant-in-Aid for General Scientific Research (B)
    • Research Field
      物理化学一般
    • Research Institution
      KYOTO UNIVERSITY
      The University of Tokyo
  •  弱い分子間錯体の生成とダイナミックス

    • Principal Investigator
      伊藤 光男
    • Project Period (FY)
      1988
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Tohoku University
  •  A New Molecular Approach toward Liquid-phase Chemical ReactionsPrincipal Investigator

    • Principal Investigator
      KAJIMOTO Okitsugu
    • Project Period (FY)
      1988 – 1989
    • Research Category
      Grant-in-Aid for Co-operative Research (A)
    • Research Field
      物理化学一般
    • Research Institution
      Kyoto University
      The University of Tokyo
  •  極性超臨界流体中での化学反応-平均溶媒和数測定によるその定量化-Principal Investigator

    • Principal Investigator
      梶本 興亜
    • Project Period (FY)
      1987
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Field
      物理化学一般
    • Research Institution
      The University of Tokyo
  •  弱い分子間錯体の生成とダイナミックス

    • Principal Investigator
      伊藤 光男
    • Project Period (FY)
      1987
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Tohoku University
  •  衝突状態にある分子対から開始する光化学反応Principal Investigator

    • Principal Investigator
      梶本 興亜
    • Project Period (FY)
      1986
    • Research Category
      Grant-in-Aid for Special Project Research
    • Research Institution
      The University of Tokyo
  •  溶媒分子の付着数を規定した化学反応-分子レベルでの溶媒効果-Principal Investigator

    • Principal Investigator
      梶本 興亜
    • Project Period (FY)
      1986
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Field
      物理化学一般
    • Research Institution
      The University of Tokyo
  •  衝突状態にある分子対から開始する光化学反応Principal Investigator

    • Principal Investigator
      梶本 興亜
    • Project Period (FY)
      1986 – 1988
    • Research Category
      Grant-in-Aid for Special Project Research
    • Research Institution
      The University of Tokyo
  •  The Studies on the Transition States in Chemical Reactions by Means of Spectroscopy and Dynamical Method

    • Principal Investigator
      SATO Shin
    • Project Period (FY)
      1985 – 1987
    • Research Category
      Grant-in-Aid for Co-operative Research (A)
    • Research Field
      物理化学一般
    • Research Institution
      Tokyo Institute of Technology

All 2006 2005 2004 2003

All Journal Article Book

  • [Book] 第5版 実験化学講座5 -化学実験のための基礎技術- 第2章 3. 超臨界流体中のミクロ物性と測定法2005

    • Author(s)
      網田富士嗣, 梶本興亜
    • Total Pages
      437
    • Publisher
      丸善株式会社
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Rates of Claisen rearrangement determined with a flow-type high-temperature and high-pressure NMR probe2006

    • Author(s)
      M.Mukaide, Y.Urasaki, K.Takegoshi, O.Kajimoto
    • Journal Title

      Supercrit. fluids (in press in J)

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Rates of Claisen rearrangement determined with a flow-type high-temperature and high-pressure NMR probe,2006

    • Author(s)
      M.Mukaide, Y.Urasaki, K.Takegoshi, O.Kajimoto
    • Journal Title

      J.Supercrit.fluids In press

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Development of a high-temperature and high-pressure NMR probe for studies of chemical reactions in supercritical water,2004

    • Author(s)
      Fujitsugu Amita, Hiroyuki Oka, Masanobu Mukaide, Yohei Urasaki, Kiyonori Takegoshi, Takehiko Terao, Okitsugu Kajimoto
    • Journal Title

      Rev.Sci.Instr 75

      Pages: 467-471

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Rotational dynamics of coumarin 153 in supercritical fluoroform2004

    • Author(s)
      N.Kometani, Y.Hoshihara, Y.Yonezawa, O.Kajimoto, K.Hara, N.Ito
    • Journal Title

      J.Phys.Chem.A 108・44

      Pages: 9479-9483

    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Developmemt of a high-temperature and high-pressure NMR probe for studies of chemical reactions in supercritical water2004

    • Author(s)
      Fujitsugu Amita, Hiroyuki Oka, Masanobu Mukaide, Yohei Urasaki, Kiyonori Takegoshi, Takehiko Terao, Okitsugu Kajimoto
    • Journal Title

      Rev. Sci. Instr. 75

      Pages: 467-471

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Experimental verification of the Smoluchowsi theory for a bimolecular diffusion-controlled reaction in liquid phase2004

    • Author(s)
      T.Arita, O.Kajimoto, M.Terazima, Y.Kimura
    • Journal Title

      J.Chem.Phys. 120

      Pages: 7071-7071

    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] A unique feature of ionic diffusion - controlled reactions in supercritical fluid2004

    • Author(s)
      T.Arita, O.Kajimoto
    • Journal Title

      The Review of High Pressure Science and Technology 14

      Pages: 37-44

    • NAID

      10012700172

    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Hydrogen generation from ethanol in supercritical water without catalyst,2003

    • Author(s)
      T.Arita, K.Nagami, O.Kajimoto
    • Journal Title

      Tetrahedron Letters 44

      Pages: 1083-1086

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Efficient and rapid C-Si bond cleavage in supercritical water,2003

    • Author(s)
      K.Itami, K.Terakawa, J.Yoshida, O.Kajimoto
    • Journal Title

      J. Amer Chem. Soc. 125(20)

      Pages: 6058-6059

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] UV absorption solvatochromic shift of 4-nitoroaniline in supercritical water,2003

    • Author(s)
      H.Oka, O.Kajimoto
    • Journal Title

      Phys.Chem.Chem.Phys. 5(12)

      Pages: 2535-2540

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Effecient and rapid C-Si bond cleavage in supercritical water,2003

    • Author(s)
      K.Itami, K.Tarakawa, J.Yoshida, O, Kajimoto
    • Journal Title

      J.Amer Chem.Soc., 125(20)

      Pages: 6058-6059

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Intramolecular vibrational redistribution of CH2I2 dissolved in supercritical Xe.2003

    • Author(s)
      K.Sekiguchi, A.shimojima, O.Kajimoto
    • Journal Title

      Chem.Phys.Lett 370

      Pages: 303-308

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] High-pressure studies on AOT reverse micellar aggregate by fluorescence probe method2003

    • Author(s)
      T.Yamasaki, 0.Kajimoto, K.Hara
    • Journal Title

      J. Photchem. Photobio. A 156

      Pages: 145-150

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Formation and decay of an aromatic vinyl cation in supercritical CF3H,2003

    • Author(s)
      T.Arita, O.Kajimoto
    • Journal Title

      J.Phys.Chem.A. 107(11)

      Pages: 1770-1775

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Formation and decay of an aromatic vinyl cation in supercritical CF_3H,2003

    • Author(s)
      T.Arita, 0.Kajimoto
    • Journal Title

      J. Phys. Chem. A 107(11)

      Pages: 1770-1775

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Intramolecular vibrational redistribution of CH_2I_2 dissolved in supercritical Xe.2003

    • Author(s)
      K.Sekiguchi, A.Shimojima, O.Kajimoto
    • Journal Title

      Chem. Phys. Lett. 370

      Pages: 303-308

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] High-pressure studies on AOT reverse micellar aggregate by fluorescence probe method,2003

    • Author(s)
      T.Yamasaki, O.Kajimoto, K.Hara
    • Journal Title

      J.Photchem.Photobio.A. 156

      Pages: 145-150

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] Hydrogen generation from ethanol in supercritical water without catalyst,2003

    • Author(s)
      T.Arita, K.Nakahara, K.Nagami, O.Kajimoto
    • Journal Title

      Tetrahedron Letters 44

      Pages: 1083-1086

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
  • [Journal Article] UV absorption solvatochromic shift of 4-nitroaniline in supercritical water2003

    • Author(s)
      H.Oka, O.Kajimoto
    • Journal Title

      Phys. Chem. Chem. Phys. 5(12)

      Pages: 2535-2540

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-15350011
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