OSHIMA Takumi 大島巧

Researcher Number	40107082
Other IDs
Affiliation (based on the past Project Information) *help	2013: 大阪大学, 工学研究科, 教授 2009 – 2010: Osaka University, 工学研究科, 教授 2008: Osaka University, 大学院・工学研究科, 教授 1998 – 2001: 大阪大学, 大学院・工学研究科, 教授
Review Section/Research Field	Principal Investigator Synthetic chemistry / Organic chemistry Except Principal Investigator Organic chemistry / Functional materials/Devices
Keywords	Principal Investigator ルイス酸 / 置換基効果 / 反応速度 / ホモキノン / キノン / Substituent Effects / Kinetics / Endo-selectivity / Regioselectivity / Cation Recognition … More / Diels-Alder Reaction / Homoquinone / [2+2] photocycloaddition / カチオン包摂 / クラウンエーテル / ディールス・アルダー反応 / 光水素引抜 / 電子移動 / 反応制御 / 1,3-双極子付加反応 / 光水素引抜反応 / クラウン化ベンゾフェノン / 骨格転位反応 / プロトン移動 / 光付加反応 / 光誘起電子移動 / ピリドノクラウンエーテル / カルベン / 6π電子環化 / 熱分解 / 光分解 / 1, 3-双極子付加 / ジアゾアルカン / ナフトキノン / 速度加速効果 / Endo選択生 / 配向選択生 / カチオン認識 / ディールス-アルダー反応 / [2+2]光環化付加 / 酸触媒反 / エポキシケトン / 酸触媒反応 / 隣接基関与 / 多環状化合物 / 転位反応 / 酸触媒 / エポキシド … More Except Principal Investigator フラーレン / 分子軌道計算 / 反応機構解析 / 酸化反応 / 酸触媒反応 / 酸触媒芳香族化反応 / ambident求核性 / エナミン / 反ブレッド則 / ambident反応性 / 酸化的脱アミノ化 / anti-Bredt二重結合 / 位置選択的反応 / 構造有機化学 / 液晶 / 電気・電子デバイス / 自己組織化 Less

Exploration for Regioselective fullerene derivatives via of synthetic intermediates fulleroid/azafulleroid having high reactive anti-Bredt double bonds
- Principal Investigator
  
  NAOHIKO Ikuma
- Project Period (FY)
  2012 – 2013
- Research Category
  
  Grant-in-Aid for Young Scientists (B)
- Research Field
  
  Organic chemistry
- Research Institution
  Osaka University
Development of Synthetic Method for New Polycyclic Compounds based on Rearrangements of Quinone-fused Epoxy KetonesPrincipal Investigator
- Principal Investigator
  
  OSHIMA Takumi
- Project Period (FY)
  2008 – 2010
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Organic chemistry
- Research Institution
  Osaka University
Synthesis of novel fullerene liquid crystals and their charge-transfer delivertives
- Principal Investigator
  
  IKUMA Naohiko
- Project Period (FY)
  2008 – 2009
- Research Category
  
  Grant-in-Aid for Young Scientists (Start-up)
- Research Field
  
  Functional materials/Devices
- Research Institution
  Osaka University
Development of New Organic Reactions by Use of Electron Acceptor QuinonesPrincipal Investigator
- Principal Investigator
  
  OSHIMA Takumi
- Project Period (FY)
  1998 – 2001
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Osaka University

All 2014 2013 2012 2011 2010 2009 2008 Other

All Journal Article Presentation

[Journal Article] First synthesis and aggregation behaviour of periconjugated triazoliumfullerene2014
- Author(s)
  Naohiko Ikuma, Saori Inaba, Ken Kokubo, Takumi Oshima
- Journal Title
  
  Chemical Communications
  
  Volume: 50 Issue: 5 Pages: 581-583
- DOI
  10.1039/c3cc45783d
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] First synthesis and aggregation behaviour of periconjugated triazoliumfullerene2014
- Author(s)
  Naohiko Ikuma, Saori Inaba, Ken Kokubo, Takumi Oshima
- Journal Title
  
  Chem. Commun.
  
  Volume: 50 Pages: 581-583
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Magic number effect on cluster formation of polyhydroxylated fullerenes in water–alcohol binary solution2013
- Author(s)
  Yuji Nakamura, Hiroshi Ueno, Ken Kokubo, Naohiko Ikuma, Takumi Oshima
- Journal Title
  
  J Nanopart. Res.
  
  Volume: 15 Pages: 1755-1755
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Synthesis and Characterization of New Acetalized [60]Fullerenes2013
- Author(s)
  Ken Kokubo, Hiroyuki Masuda, Naohiko Ikuma, Tsubasa Mikie and Takumi Oshima
- Journal Title
  
  Tetrahedron Lett.
  
  Pages: 3510-3513
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Synthesis of a New Class of Fullerene Derivative Li^+@C_<60>O^–(OH)_7 as a'Cation-Encapsulated Anion Nanoparticle'2013
- Author(s)
  Hiroshi Ueno, Ken Kokubo, Eunsang Kwon, Yuji Nakamura, Naohiko Ikuma, Takumi Oshima
- Journal Title
  
  Nanoscale
  
  Volume: 5 Pages: 2317-2321
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Synthesis and Characterization of New Acetalized [60]Fullerenes2013
- Author(s)
  Ken Kokubo, Hiroyuki Masuda, Naohiko Ikuma, Tsubasa Mikie and Takumi Oshima
- Journal Title
  
  Tetrahedron Letters
  
  Volume: 54 Issue: 27 Pages: 3510-3513
- DOI
  10.1016/j.tetlet.2013.04.093
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Synthesis of a New Class of Fullerene Derivative Li+@C60O-(OH)7 as a “Cation-Encapsulated Anion Nanoparticle”2013
- Author(s)
  H. Ueno, K. Kokubo, E. Kwon, Y. Nakamura, N. Ikuma, T. Oshima
- Journal Title
  
  Nanoscale
  
  Volume: 5 Issue: 6 Pages: 2317-2321
- DOI
  10.1039/c3nr33608e
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-23651111, KAKENHI-PROJECT-24750039
[Journal Article] Ionic conductivity of [Li^+@C_<60>](PF_6^−) in organic solvents and its electrochemical reduction to Li^+@C_<60>˙^−2013
- Author(s)
  Hiroshi Ueno, Ken Kokubo, Yuji Nakamura, Kei Ohkubo, Naohiko Ikuma, Hiroshi Moriyama, Shunichi Fukuzumi, Takumi Oshima
- Journal Title
  
  Chem. Commun.
  
  Volume: 49 Pages: 7376-7378
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Magic number effect on cluster formation of polyhydroxylated fullerenes in water–alcohol binary solution2013
- Author(s)
  Yuji Nakamura, Hiroshi Ueno, Ken Kokubo, Naohiko Ikuma, Takumi Oshima
- Journal Title
  
  Journal of Nanoparticle Research
  
  Volume: 15 Issue: 6 Pages: 1755-1755
- DOI
  10.1007/s11051-013-1755-6
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Ionic conductivity of [Li+ @C60](PF6 ) in organic solvents and its electrochemical reduction to Li+ @C602013
- Author(s)
  Hiroshi Ueno, Ken Kokubo,Yuji Nakamura, Kei Ohkubo, Naohiko Ikuma,Hiroshi Moriyama,Shunichi Fukuzumi,Takumi Oshima
- Journal Title
  
  Chem. Commun.
  
  Volume: 49 Issue: 67 Pages: 7376-7378
- DOI
  10.1039/c3cc43901a
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-23550211, KAKENHI-PROJECT-24750039
[Journal Article] Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid2012
- Author(s)
  Naohiko Ikuma, Satoko Sumioka, Haruyasu Asahara, Takumi Oshima
- Journal Title
  
  Tetrahedron Letters
  
  Volume: 53 Issue: 28 Pages: 3581-3584
- DOI
  10.1016/j.tetlet.2012.05.007
- NAID
  120005728980
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes2012
- Author(s)
  Naohiko Ikuma, Tsubasa Mikie, Yuta Doi, Koji Nakagawa, Ken Kokubo, Takumi Oshima
- Journal Title
  
  Org. Lett.
  
  Volume: 14 Pages: 6040-6043
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Versatile Domino Rearrangement of Diphenylhomobenzoquinone Epoxides Induced by CF3SO32012
- Author(s)
  Haruyasu Asahara, Satoshi Matsui, Yoshiro Masuda, Naohiko Ikuma, Takumi Oshima
- Journal Title
  
  Eurpean Journal of Organic Chemistry
  
  Volume: 2012 Issue: 21 Pages: 3916-3919
- DOI
  10.1002/ejoc.201200455
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Synthesis of a Lithium-Encapsulated Fullerenol and the Effect of the Internal Lithium Cation on Its Aggregation Behavior2012
- Author(s)
  H. Ueno, Y. Nakamura, N. Ikuma, K. Kokubo, T. Oshima
- Journal Title
  
  Nano Res.
  
  Volume: 5 Issue: 8 Pages: 558-564
- DOI
  10.1007/s12274-012-0241-2
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-23651111, KAKENHI-PROJECT-24750039
[Journal Article] Synthesis of a lithium-encapsulated fullerenol and the effect of the internal lithium cation on its aggregation behavior2012
- Author(s)
  Hiroshi Ueno, Yuji Nakamura, Naohiko Ikuma, Ken Kokubo, Takumi Oshima
- Journal Title
  
  Nano Res.
  
  Volume: 5 Pages: 558-564
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid2012
- Author(s)
  Naohiko Ikuma, Satoko Sumioka, Haruyasu Asahara, Takumi Oshima
- Journal Title
  
  Tetrahedron Lett.
  
  Volume: 53 Pages: 3581-3584
- NAID
  120005728980
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes2012
- Author(s)
  Naohiko Ikuma, Tsubasa Mikie, Yuta Doi, Koji Nakagawa, Ken Kokubo, Takumi Oshima
- Journal Title
  
  Organic Letters
  
  Volume: 14 Issue: 23 Pages: 6040-6043
- DOI
  10.1021/ol302928d
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Versatile Domino Rearrangement of Diphenylhomobenzoquinone Epoxides Induced by CF_3SO_3H2012
- Author(s)
  Haruyasu Asahara, Satoshi Matsui, Yoshiro Masuda, Naohiko Ikuma, Takumi Oshima
- Journal Title
  
  Eur. J. Org. Chem.
  
  Pages: 3916-3919
- Data Source
  KAKENHI-PROJECT-24750039
[Journal Article] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroids vs Methanofullerene and C602010
- Author(s)
  Naohiko Ikuma, Yasunori Susami, Takumi Oshima
- Journal Title
  
  Org. Biomol. Chem. 8
  
  Pages: 1394-1398
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20850025
[Journal Article] Kinetic Evidence for Dihapto η2 π-Aryl Participation in Acid-Catakyzed Ring Opening of Diarylhomobenzoquinone Epoxides2010
- Author(s)
  H.Asahara, K.Saito, T.Oshima
- Journal Title
  
  J.Org.Chem. 75
  
  Pages: 733-740
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] A New Approach to Benzofurane Synthesis : Lewis Acid Mediated Cycloaddition of Benzoquinones with Stilbene Oxides2010
- Author(s)
  K.Kokubo, K.Harada, E.Mochizuk, T.Oshima
- Journal Title
  
  Tetrahedron Lett. 51
  
  Pages: 955-958
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroids vs Methanofullerene and C_<60>2010
- Author(s)
  N.Ikuma, Y.Susami, T.Oshima
- Journal Title
  
  Org.Biomol.Chem. 8
  
  Pages: 1394-1398
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] フラーレン類の抗酸化評価および汎用化粧品成分の光分解抑制効果青江央江2009
- Author(s)
  都賀谷京子、後藤忠示、伊藤雅之、小久保研、山名修一、大島巧
- Journal Title
  
  日本香粧品学会誌 33
  
  Pages: 149-154
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] One-Step Synthesis of Water-Soluble Fullerenols bearingNitrogen-Containing Substituents2009
- Author(s)
  K. Matsubayashi, K. Kokubo, H. Tategaki, S. Kawahama, T. Oshima
- Journal Title
  
  Fullerrenes, Nanotubes and CarbonNanostructures (In press)
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Antimicrobial Activity of Fullerenes and Their Hydroxylated Derivatives2009
- Author(s)
  H.Aoshima, K.Kokubo, S.Shirakawa, M.Ito, S.Yamana, T.Oshima
- Journal Title
  
  Biocontrol Science 14
  
  Pages: 69-72
- NAID
  10025217636
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] One-step Synthesis of Water-soluble Fullerenols Bearing Nitrogen-containing Substituents2009
- Author(s)
  K.Matsubayashi, T.Goto, K.Togaya, K.Kokubo, T.Oshima
- Journal Title
  
  Fullerenes Nanotubes And Carbon Nanostructures 17
  
  Pages: 440-456
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Structural Effects on Thermal Rearrangements of Fulleroids to Methanofullerenes. The Prominent Role of Cyclopropyl vs Aryl Substituent2008
- Author(s)
  H.Kitamura, T.Oshima
- Journal Title
  
  Org.Lett. 10
  
  Pages: 293-296
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Facile Synthesis of Highly Water Soluble Fullerenes More Than Half-Covered by Hydroxy Groups2008
- Author(s)
  K.Kokubo, K.Matsubayashi, H.Tategaki, H.Takada, T.Oshima
- Journal Title
  
  ACS Nano 2
  
  Pages: 293-296
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Mechanistic Evidence for Remote π-Aryl Participation inAcid-catalyzed Eing Opening of Homobenzoquinone Epoxide2008
- Author(s)
  T. Oshima, H. Asahara, T. Koizumi, S. Miyamoto
- Journal Title
  
  Chea. Co maun.
  
  Pages: 1804-1806
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Mechanistic Evidence for Remoto p-Aryl Participation in Acid-Catalyzed Ring Opening of Homobenzoquinone Epoxide2008
- Author(s)
  T.Oshima, H.Asahara, T.Koizumi, S.Miyamoto
- Journal Title
  
  Chem.Commun.
  
  Pages: 1804-1806
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Effects of Pin-up Oxygen on [60]Fullerene for Enhanced Antioxidant Activity2008
- Author(s)
  K.Matsubayashi, T.Goto, K.Togaya, K.Kokubo, T.Oshima
- Journal Title
  
  Nanoscale Res.Lett. 3
  
  Pages: 237-241
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] AlCl_3-Catalyzed Tandem Acetylation of Hydroarylated[60]Fullerenes2008
- Author(s)
  K. Kokubo, S. Tochika, M. Kato, Y. Sol, T. Oshima
- Journal Title
  
  Org. Lett. 15
  
  Pages: 3335-3338
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] AlCl_3-Catalyzed Tandem Acetylation of Hydroxylated [60]Fullerene2008
- Author(s)
  K.Kokubo, S.Tochika, M.Kato, Y.Sol, T.Oshima
- Journal Title
  
  Org.Lett. 10
  
  Pages: 3335-3338
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Conformational Effects in Acid-Mediated Ring Opening of Epoxides : Prominent Role of the Oxirane Walsh Orbital2008
- Author(s)
  T.Oshima, H.Asahara, E.Kubo, S.Miyamoto, K.Togaya
- Journal Title
  
  Org.Lett. 10
  
  Pages: 2413-2416
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] structural Effects on Thermal Rearrangements of Fulle-roids to Methanofullerenes. The Prominent role of Cyclopropyl vs Aryl Substituent2008
- Author(s)
  H. Kitamura, T. Oshima
- Journal Title
  
  Org. Lett. 10
  
  Pages: 293-296
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Conformational Effects in Acid-Mediated Eing Opening ofEpoxides : Prominent Role of the Oxirane Walsh Orbital2008
- Author(s)
  T. Oshima, H. Asahara, E. Kubo, S. Miyamoto, K. Togaya
- Journal Title
  
  Org. Lett. 10
  
  Pages: 2413-2416
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Effects of Pin-up Oxygen on [60]Fullerene for EnhancedAntioxidant Activity2008
- Author(s)
  K., Matsubayashi, T. Goto, K. Togaya, K. Kokubo, T. Oshima
- Journal Title
  
  Nanoscale Res. Lett. 3
  
  Pages: 237-241
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Journal Article] Facile Synthesis of highly Water Soluble FullerenesMore Than Half-Covered by Hydroxy Groups2008
- Author(s)
  K. Kokubo, K. Matsubayashi, H. Tategaki, H. Takada, T. Oshima
- Journal Title
  
  ACS Nano 2
  
  Pages: 327-333
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] [3+2]環化付加反応によるトリアゾリウムフラーレンカチオンのワンポット合成と会合特性2014
- Author(s)
  伊熊直彦, 稲場沙織, 小久保研, 大島巧
- Organizer
  第94回日本化学会春季年会
- Place of Presentation
  名古屋大学
- Year and Date
  2014-03-29
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アザフレロイドの酸化的脱アミノ化によるフラーレン再生反応2013
- Author(s)
  藤岡公一, 伊熊直彦, 三澤勇介, 小久保研, 大島巧
- Organizer
  第24回基礎有機化学討論会
- Place of Presentation
  学習院大学
- Year and Date
  2013-09-06
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 芳香族ジエナミンとC60の熱[2+2]環化付加反応2013
- Author(s)
  伊熊直彦, 山本浩之, 三木江翼, 小久保研, 大島巧
- Organizer
  第44回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  東京大学伊藤国際学術研究センター（東京都文京区）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アザフレロイドの過酸による酸化反応2013
- Author(s)
  藤岡公一, 伊熊直彦, 三澤勇介, 小久保研, 大島巧
- Organizer
  第93回日本化学会春季年会
- Place of Presentation
  立命館大学
- Year and Date
  2013-03-24
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 芳香族ジエナミンとフラーレンの熱的[2+2]環化付加反応と、アミノシクロブタン生成物の酸または酸化剤による反応2013
- Author(s)
  山本浩之・伊熊直彦・山下翔・小久保研・大島巧
- Organizer
  第24回基礎有機化学討論会
- Place of Presentation
  学習院大学
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] リチウム内包フラーレン溶液のイオン伝導度測定と電気化学的手法によるリチウム内包フラーレンラジカルアニオンの合成2013
- Author(s)
  上野裕, 小久保研, 大久保敬, 伊熊直彦, 森山広思, 福住俊一, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Year and Date
  2013-08-06
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 芳香族ジエナミンとフラーレンの熱的[2+2]環化付加反応と、アミノシクロブタン生成物の酸または酸化剤による反応2013
- Author(s)
  山本浩之, 伊熊直彦, 山下翔, 小久保研, 大島巧
- Organizer
  第24回基礎有機化学討論会
- Place of Presentation
  学習院大学
- Year and Date
  2013-09-06
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アザフレロイド生成機構の解明と、架橋窒素の金属配位能を利用した有機金属試薬の選択的付加反応2013
- Author(s)
  中川晃二, 伊熊直彦, 藤岡公一, 小久保研, 大島巧
- Organizer
  第24回基礎有機化学討論会
- Place of Presentation
  学習院大学
- Year and Date
  2013-09-06
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] リチウム内包フラーレン溶液のイオン伝導度測定と電気化学的手法によるリチウム内包フラーレンラジカルアニオンの合成2013
- Author(s)
  上野裕, 小久保研, 大久保敬, 伊熊直彦, 森山広思, 福住俊一, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 有機薄膜太陽電池を指向したスピロ環を有するフラーレン誘導体の合成と評価2013
- Author(s)
  増田寛之, 小久保研, 伊熊直彦, 三木江翼, 佐伯昭記, 関修平, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Year and Date
  2013-08-06
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 1-アリル-4-(N-アルキルアミノ)フラーレンの合成と物性2013
- Author(s)
  三木江翼, 佐伯昭紀, 伊熊直彦, 小久保研, 大島巧, 関修平
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 1-アリル-4-(N-アルキルアミノ)フラーレンの合成と物性2013
- Author(s)
  三木江翼, 佐伯昭紀, 伊熊直彦, 小久保研, 大島巧, 関修平
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Year and Date
  2013-08-06
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 有機薄膜太陽電池を指向したスピロ環を有するフラーレン誘導体の合成と評価2013
- Author(s)
  増田寛之, 小久保研, 伊熊直彦, 三木江翼, 佐伯昭記, 関修平, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] ペリ共役性フレロトリアゾリウムの one-pot 合成と自己集合性2013
- Author(s)
  伊熊直彦, 稲場沙織, 小久保研, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 芳香族ジエナミンとC60の熱[2+2]環化付加反応2013
- Author(s)
  伊熊直彦, 山本浩之, 三木江翼, 小久保研, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  東京大学
- Year and Date
  2013-03-13
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] C60 regeneration by oxidative deamination of azafulleroids with peracids and substituent effects of azafulleroids2013
- Author(s)
  藤岡公一, 伊熊直彦, 三澤勇介, 小久保研, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 含窒素フラーレン類の塩基性を利用した酸触媒反応2013
- Author(s)
  伊熊直彦, 土井佑太, 三木江翼, 中川晃二, 小久保研, 大島巧
- Organizer
  日本化学会第93回春季年会
- Place of Presentation
  立命館大学びわこ・くさつキャンパス（滋賀県草津市）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] C60 regeneration by oxidative deamination of azafulleroids with peracids and substituent effects of azafulleroids2013
- Author(s)
  藤岡公一, 伊熊直彦, 三澤勇介, 小久保研, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Year and Date
  2013-08-06
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アザフレロイドの過酸による酸化反応2013
- Author(s)
  藤岡公一、伊熊直彦, 三澤勇介, 小久保研, 大島巧
- Organizer
  日本化学会第93回春季年会
- Place of Presentation
  立命館大学びわこ・くさつキャンパス（滋賀県草津市）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] ペリ共役性フレロトリアゾリウムのone-pot合成と自己集合性2013
- Author(s)
  伊熊直彦, 稲場沙織, 小久保研, 大島巧
- Organizer
  第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  大阪大学
- Year and Date
  2013-08-06
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アザフレロイドのFriedel-Crafts反応を基盤とする高効率な芳香環付加反応2012
- Author(s)
  土井佑太, 伊熊直彦, 三木江翼, 小久保研, 大島巧
- Organizer
  第23回基礎有機化学討論会
- Place of Presentation
  京都テレサ
- Year and Date
  2012-09-20
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] トリアゾリノフラーレンの熱脱窒素機構に関する速度論的研究2012
- Author(s)
  中川晃二・伊熊直彦・三木江翼・田中伸英・小久保研・大島巧
- Organizer
  第２３回基礎有機化学討論会
- Place of Presentation
  京都テルサ（京都府京都市）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アセトフェノン由来ジエナミンのフラーレンへの熱的[2+2]環化付加反応2012
- Author(s)
  山本浩之・伊熊直彦・三木江翼・小久保研・大島巧
- Organizer
  第２３回基礎有機化学討論会
- Place of Presentation
  京都テルサ（京都府京都市）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アザフレロイドのambidentな塩基性に起因する酸触媒芳香族化反応2012
- Author(s)
  伊熊直彦, 土井佑太, 三木江翼, 中川晃二, 小久保研, 大島巧
- Organizer
  第43回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  東北大学百周年記念会館（宮城県仙台市）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] Thermal [2+2] Cycloaddition of C_<60> with Aryl Dienamines2012
- Author(s)
  Hiroyuki Yamamoto, Tsubasa Mikie, Naohiko Ikuma, Ken Kokubo, Takumi Oshima
- Organizer
  IKCOC-12
- Place of Presentation
  リーガロイヤルホテル京都
- Year and Date
  2012-11-15
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] Kinetic Studies on the Thermal Denitrogenation of Triazolinofullerenes2012
- Author(s)
  Koji Nakagawa, Naohiko Ikuma, Tsubasa Mikie, Nobuhide Tanaka, Ken Kokubo, Takumi Oshima
- Organizer
  IKCOC-12
- Place of Presentation
  リーガロイヤルホテル京都
- Year and Date
  2012-11-13
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アセトフェノン由来ジエナミンのフラーレンへの熱的[2+2]環化付加反応2012
- Author(s)
  山本浩之, 伊熊直彦, 三木江翼, 小久保研, 大島巧
- Organizer
  第23回基礎有機化学討論会
- Place of Presentation
  京都テレサ
- Year and Date
  2012-09-20
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アザフレロイドのambidentな塩基性に起因する酸触媒芳香族化反応2012
- Author(s)
  伊熊直彦, 土井佑太, 三木江翼, 中川晃二, 小久保研, 大島巧
- Organizer
  第43回フラーレン・ナノチューブ・グラフェン総合シンポジウム
- Place of Presentation
  東北大学
- Year and Date
  2012-09-05
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] Kinetic Studies on the Thermal Denitrogenation of Triazolinofullerenes2012
- Author(s)
  Koji Nakagawa, Naohiko Ikuma, Tsubasa Mikie, Nobuhide Tanaka, Ken Kokubo, Takumi Oshima
- Organizer
  12th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12)
- Place of Presentation
  リーガロイヤルホテル京都（京都府京都市）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] Thermal [2+2] Cycloaddition of C60 with Aryl Dienamines2012
- Author(s)
  Hiroyuki Yamamoto, Tsubasa Mikie, Naohiko Ikuma, Ken Kokubo, Takumi Oshima
- Organizer
  12th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12)
- Place of Presentation
  リーガロイヤルホテル京都（京都府京都市）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] トリアゾリノフラーレンの熱脱窒素機構に関する速度論的研究2012
- Author(s)
  中川晃二, 伊熊直彦, 三木江翼, 田中伸英, 小久保研, 大島巧
- Organizer
  第23回基礎有機化学討論会
- Place of Presentation
  京都テレサ
- Year and Date
  2012-09-20
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] アザフレロイドのFriedel-Crafts反応を基盤とする高効率な芳香環付加反応2012
- Author(s)
  土井佑太・伊熊直彦・三木江翼・小久保研・大島巧
- Organizer
  第２３回基礎有機化学討論会
- Place of Presentation
  京都テルサ（京都府京都市）
- Data Source
  KAKENHI-PROJECT-24750039
[Presentation] 2-メチルマロン酸エステル[60]フラーレン二付加体の位置化学ならびに電子的特性2011
- Author(s)
  小久保研、アラストリヤー、大島巧
- Organizer
  日本化学会91回春季年会
- Place of Presentation
  横浜
- Year and Date
  2011-03-28
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] マルチアリール化[60]フラーレン誘導体の熱および酸化的安定性2011
- Author(s)
  小久保研、柏原宮人、矢野智美、田中克知、伊熊直彦、大島巧
- Organizer
  第40回フラーレン・ナノチューブシンポジウム
- Place of Presentation
  名古屋市
- Year and Date
  2011-03-09
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] 蛍光標識水酸化フラーレンの合成およびその光物理特性2011
- Author(s)
  小久保研、白川翔吾、伊熊直彦、大島巧
- Organizer
  日本化学会第91回春季年会
- Place of Presentation
  横浜
- Year and Date
  2011-03-28
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] フラーレンとその誘導体のDiels-Alder反応における極性・ハロゲン溶媒の効果2011
- Author(s)
  伊熊直彦、三木江翼、アラスト・セイエド・リヤー、小久保研、大島巧
- Organizer
  日本化学会第91回春季年会
- Place of Presentation
  横浜
- Year and Date
  2011-03-28
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] モルホリノシクロアルケンとC60フラーレンの熱[2+2]環化付加2011
- Author(s)
  三木江翼、浅原時泰、長尾和明、伊熊直彦、小久保研、大島巧
- Organizer
  第40回フラーレン・ナノチューブシンポジウム
- Place of Presentation
  名古屋市
- Year and Date
  2011-03-09
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] トリアゾリノフラーレンの酸触媒脱窒素反応2011
- Author(s)
  三木江翼、田中伸英、伊熊直彦、小久保研、大島巧
- Organizer
  日本化学会第91回春季年会
- Place of Presentation
  横浜
- Year and Date
  2011-03-28
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] 非水溶性低度水酸化フラレノールの簡便合成とそのナノ粒子特性2010
- Author(s)
  小林直記、小久保研、大島巧
- Organizer
  第38回フラーレン・ナノチューブ総合シンポジウム
- Place of Presentation
  名古屋市
- Year and Date
  2010-03-04
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] フレロイドの酸化反応における速度論的研究2010
- Author(s)
  住岡慧子, 伊熊直彦, 小久保研, 大島巧
- Organizer
  日本化学会第90回春季年会
- Year and Date
  2010-03-28
- Data Source
  KAKENHI-PROJECT-20850025
[Presentation] ジアリールホモベンゾキノンエポキシドの酸触媒開環反応におけるη^2タイプπ-Ar基関与に対する速度論的考察2010
- Author(s)
  浅原時泰、斉藤浩太、大島巧
- Organizer
  日本化学会第90回春年会
- Place of Presentation
  東大阪市
- Year and Date
  2010-03-26
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] 高い電子受容性を有する[60]フラーレン二付加体の合成2010
- Author(s)
  アラストS.リヤー、小久保研、Hao Geng、Hsing-Lin Wang、大島巧、Long Y.Chiang
- Organizer
  第38回フラーレン・ナノチューブ総合シンポジウム
- Place of Presentation
  名古屋市
- Year and Date
  2010-03-04
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] フレロイドの酸化反応における速度論的研究2010
- Author(s)
  住岡慧子、伊熊直彦、小久保研、大島巧
- Organizer
  日本化学会第90回春年会
- Place of Presentation
  東大阪市
- Year and Date
  2010-03-28
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] フレロイド、メタノフラーレン及びアザフレロイドと各種ジエンとのDiels-Alder反応における速度論的研究2010
- Author(s)
  田中伸英, 伊熊直彦, 小久保研, 大島巧
- Organizer
  日本化学会第90回春季年会
- Year and Date
  2010-03-28
- Data Source
  KAKENHI-PROJECT-20850025
[Presentation] フレロイドのmCPBA 酸化反応における橋頭位選択的エステル化2010
- Author(s)
  伊熊直彦、住岡慧子、浅原時泰、小久保研、大島巧
- Organizer
  第39回フラーレン・ナノチューブシンポジウム
- Place of Presentation
  京都市
- Year and Date
  2010-09-05
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] 部分塩素化水酸化フラーレンの合成およびそのアレルゲン除去能2010
- Author(s)
  森田一翔、小久保研、野口武、大島巧
- Organizer
  日本化学会第90回春年会
- Place of Presentation
  東大阪市
- Year and Date
  2010-03-27
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] Synthesis of Fullerenols Having Fluorophore Moiety2010
- Author(s)
  K.Kokubo, S.Shirakawa, I.Morita, N.Ikuma, T.Oshima
- Organizer
  PACIFICHEM
- Place of Presentation
  Hawaii, USA
- Year and Date
  2010-12-17
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] フレロイド、メタノフラーレン及びアザフレロイドと各種ジエンとのDiels-Alder反応における速度論的研究2010
- Author(s)
  田中伸英、伊熊直彦、小久保研、大島巧
- Organizer
  日本化学会第90回春年会
- Place of Presentation
  東大阪市
- Year and Date
  2010-03-28
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] Synthesis of Highly Soluble Multiarylated [60]Fullerene Derivatives Directed to Resist Materials2010
- Author(s)
  M.Kashihara, M.Kato, T.Yano, K.Tanaka, K.Kokubo, N.Ikuma, T.Oshima
- Organizer
  PACIFICHEM
- Place of Presentation
  Hawaii, USA
- Year and Date
  2010-12-17
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] Kinetics and Regioselectivity of Fulleroid in Diels-Alder Reaction and mCPBA Oxidation : Influence of Strain at the Bridgehead Olefin2010
- Author(s)
  N.Ikuma, Y.Susami, K.Kokubo, T.Oshima
- Organizer
  PACIFICHEM
- Place of Presentation
  Hawaii, USA
- Year and Date
  2010-12-17
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] ジアリールシクロブタン縮環キノンの分子内[2+2]光付加環化反応における置換基効果2009
- Author(s)
  浅原時泰、大久保敬、福住俊一、大島巧
- Organizer
  2009年光化学討論会
- Place of Presentation
  桐生市
- Year and Date
  2009-09-16
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] AlCl_3-catalyzed Tandem Acetylation of Hydroarylated [60]Fullerens2009
- Author(s)
  K.Kokubo, S.Tochika, M.Kashihara, N.Ikuma, T.Oshima
- Organizer
  IKOOC-11
- Place of Presentation
  Kyoto
- Year and Date
  2009-11-11
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] Synthesis and Structural Analysis of novel [60]Fullerene Bisadducts2009
- Author(s)
  K.Kokubo, R.S.Arasto, H.Geng, H.-L.Wang, T.Oshima, L.Y.Chiang
- Organizer
  IKOOC-11
- Place of Presentation
  Kyoto
- Year and Date
  2009-11-12
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] Kinetic Evaluation of Fractionalipso/ortho π-Aryl Participation in Acid-Catalyzed Ring-opening of Diarylhomobenzoquinone epoxides2009
- Author(s)
  H.Asahara, K.Saito, T.Oshima
- Organizer
  IKOOC-11
- Place of Presentation
  Kyoto
- Year and Date
  2009-11-12
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroid2009
- Author(s)
  Naohiko. Ikuma, Yasunori Susami, Ken Kokubo, Takumi Oshima
- Organizer
  the 11th International KYOTO conference on New Aspests of Organic Chemistry (IKCOC-11)
- Year and Date
  2009-11-12
- Data Source
  KAKENHI-PROJECT-20850025
[Presentation] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroid2009
- Author(s)
  N.Ikuma, Y.Susami, K.Kokubo, T.Oshima
- Organizer
  IKOOC-11
- Place of Presentation
  Kyoto
- Year and Date
  2009-11-12
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] ヒドロアリール化フラーレン誘導体のFriedel-Craftsアセチル化反応ならびに新規環化反応2008
- Author(s)
  加藤万依, 遠近真矢, 小久保研, 大島巧
- Organizer
  第3回三大学連携学生研究会、アトミック・ポリスケールテクノロジー連携研究会
- Place of Presentation
  東京理科大学、長万部キャンバス、北海道
- Year and Date
  2008-08-22
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] ジアリールホモキノン土ポキシドの酸触媒骨格転位反応の速度置換基効果2008
- Author(s)
  斎藤浩太, 浅原時泰, 大島巧
- Organizer
  第19回基礎有機化学討論会
- Place of Presentation
  大阪大学、大阪
- Year and Date
  2008-10-03
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] β-カロテン退色法を用いた水溶性フラーレン誘導体の抗酸化能の評価2008
- Author(s)
  都賀谷京子, 小久保研, アラストセイェドリヤー, 大島巧
- Organizer
  第3回三大学連携学生研究会、アトミック・ポリスケールテクノロジー連携研究会
- Place of Presentation
  東京理科大学、長万部キャンパス、北海道
- Year and Date
  2008-08-22
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] ジアリールホモキノンエポキシドの酸触媒骨格転位反応の速度置換基効果2008
- Author(s)
  斉藤浩太、浅原時泰、大島巧
- Organizer
  第19回基礎有機化学討論会
- Place of Presentation
  大阪
- Year and Date
  2008-10-03
- Data Source
  KAKENHI-PROJECT-20550040
[Presentation] 含窒素フラーレン類の塩基性を利用した酸触媒反応
- Author(s)
  伊熊直彦, 土井佑太, 三木江翼, 中川晃二, 小久保研, 大島巧
- Data Source
  KAKENHI-PROJECT-24750039

1. IKUMA Naohiko (70505990)

# of Collaborated Projects: 2 results

# of Collaborated Products: 52 results
2. KOKUBO Ken (20304008)

# of Collaborated Projects: 2 results

# of Collaborated Products: 49 results
3. 森山廣思

# of Collaborated Projects: 0 results

# of Collaborated Products: 1 results

OSHIMA Takumi 大島 巧

Research Projects

Research Products

Co-Researchers

Exploration for Regioselective fullerene derivatives via of synthetic intermediates fulleroid/azafulleroid having high reactive anti-Bredt double bonds

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Development of Synthetic Method for New Polycyclic Compounds based on Rearrangements of Quinone-fused Epoxy KetonesPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Synthesis of novel fullerene liquid crystals and their charge-transfer delivertives

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Development of New Organic Reactions by Use of Electron Acceptor QuinonesPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] First synthesis and aggregation behaviour of periconjugated triazoliumfullerene2014

Author(s)

Journal Title

DOI

Data Source

[Journal Article] First synthesis and aggregation behaviour of periconjugated triazoliumfullerene2014

Author(s)

Journal Title

Data Source

[Journal Article] Magic number effect on cluster formation of polyhydroxylated fullerenes in water–alcohol binary solution2013

Author(s)

Journal Title

Data Source

[Journal Article] Synthesis and Characterization of New Acetalized [60]Fullerenes2013

Author(s)

Journal Title

Data Source

[Journal Article] Synthesis of a New Class of Fullerene Derivative Li^+@C_<60>O^–(OH)_7 as a'Cation-Encapsulated Anion Nanoparticle'2013

Author(s)

Journal Title

Data Source

[Journal Article] Synthesis and Characterization of New Acetalized [60]Fullerenes2013

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Synthesis of a New Class of Fullerene Derivative Li+@C60O-(OH)7 as a “Cation-Encapsulated Anion Nanoparticle”2013

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Ionic conductivity of [Li^+@C_<60>](PF_6^−) in organic solvents and its electrochemical reduction to Li^+@C_<60>˙^−2013

Author(s)

Journal Title

Data Source

[Journal Article] Magic number effect on cluster formation of polyhydroxylated fullerenes in water–alcohol binary solution2013

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Ionic conductivity of [Li+ @C60](PF6 ) in organic solvents and its electrochemical reduction to Li+ @C602013

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid2012

Author(s)

Journal Title

DOI

NAID

Data Source

[Journal Article] Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes2012

OSHIMA Takumi 大島巧