Nagae Haruki 長江春樹

Researcher Number	40779005
Other IDs
Affiliation (Current)	2025: 国立研究開発法人産業技術総合研究所, 材料・化学領域, 主任研究員
Affiliation (based on the past Project Information) *help	2022: 国立研究開発法人産業技術総合研究所, 材料・化学領域, 研究員 2020 – 2021: 大阪大学, 基礎工学研究科, 助教 2016 – 2017: 大阪大学, 基礎工学研究科, 助教
Review Section/Research Field	Principal Investigator Basic Section 33020:Synthetic organic chemistry-related / Organic chemistry
Keywords	Principal Investigator 異種二核金属錯体 / 銅 / ニッケル / カリウム / マンガン / エステル化 / アミド / 空気酸化 / 異種金属四核錯体 / 異種金属二核錯体 … More / 空気酸化反応 / 交互共重合 / 二酸化炭素 / エステル交換反応 / アミド結合活性化 / 異種金属錯体 / 多核金属錯体 / アルコキシ架橋錯体 / 非天然アミノ酸 / デュアル触媒 / 多核錯体 / 光触媒 / C-H空気酸化 / トランスエステル化 / アミド結合 / 炭素―水素結合活性化 / 炭素-水素結合活性化 / 不斉反応 / アルキル錯体 / アミド錯体 / アミノアルキル化反応 / 前周期遷移金属 / C-H結合活性化 Less

Development of alkoxy-bridged dinuclear non-precious metal complex catalysts for synthesis and alcoholysis of amide derivativesPrincipal Investigator
- Principal Investigator
  
  Nagae Haruki
- Project Period (FY)
  2020 – 2022
- Research Category
  
  Grant-in-Aid for Early-Career Scientists
- Review Section
  
  Basic Section 33020:Synthetic organic chemistry-related
- Research Institution
  National Institute of Advanced Industrial Science and Technology
  Osaka University
Development of Catalytic Reaction Mediated by Early Transition Metal via Sigma-bond Metathesis ReactionPrincipal Investigator
- Principal Investigator
  
  Nagae Haruki
- Project Period (FY)
  2016 – 2017
- Research Category
  
  Grant-in-Aid for Research Activity Start-up
- Research Field
  
  Organic chemistry
- Research Institution
  Osaka University

All 2023 2022 2021 2020 2018 2017 2016

All Journal Article Presentation

[Journal Article] Nickel-Catalyzed Asymmetric Allylic Alkylation of β-Dicarbonyl Compounds via C-C Bond Activation of 2-Allylated Cyclic 1,3-Diketones2023
- Author(s)
  Higashida Kosuke、Smail Valentin、Nagae Haruki、Carpentier Jean-Francois、Mashima Kazushi
- Journal Title
  
  ACS Catalysis
  
  Volume: 13 Issue: 3 Pages: 2156-2161
- DOI
  10.1021/acscatal.2c05664
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-20K15277
[Journal Article] Continuous Plug Flow Process for the Transesterification of Methyl Acrylate and 1,4-Butanediol by a Zn-Immobilized Catalyst for Producing 4-Hydroxybutyl Acrylate2022
- Author(s)
  Kato Taito、Nagae Haruki、Yonehara Koji、Kitano Tomoyuki、Nagashima Hiroki、Tanaka Shinji、Oku Tomoharu、Mashima Kazushi
- Journal Title
  
  Industrial and Engineering Chemistry Research
  
  Volume: 61 Issue: 51 Pages: 18625-18635
- DOI
  10.1021/acs.iecr.2c02583
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20K15277
[Journal Article] Chain Transfer Approach for Terminal Functionalization of Alternating Copolymerization of CO2 and Epoxide by Using Active Methylene Compounds as Chain Transfer Agents2022
- Author(s)
  Nagae Haruki、Akebi Shin-ya、Matsushiro Saki、Sakamoto Kazutaka、Iwasaki Takanori、Nozaki Kyoko、Mashima Kazushi
- Journal Title
  
  Macromolecules
  
  Volume: 55 Issue: 20 Pages: 9066-9073
- DOI
  10.1021/acs.macromol.2c01761
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20K15277
[Journal Article] Runge-Kutta analysis for optimizing the Zn-catalyzed transesterification conditions of MA and MMA with diols to maximize monoesterified products2021
- Author(s)
  Kato Taito、Akebi Shin-ya、Nagae Haruki、Yonehara Koji、Oku Tomoharu、Mashima Kazushi
- Journal Title
  
  Catalysis Science & Technology
  
  Volume: 11 Issue: 21 Pages: 6975-6986
- DOI
  10.1039/d1cy01180d
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20K15277
[Journal Article] Mechanistic Study of Ni and Cu Dual Catalyst for Asymmetric C-C Bond Formation; Asymmetric Coupling of 1,3-Dienes with C-nucleophiles to Construct Vicinal Stereocenters2021
- Author(s)
  Xia Jingzhao、Hirai Takahiro、Katayama Shoichiro、Nagae Haruki、Zhang Wanbin、Mashima Kazushi
- Journal Title
  
  ACS Catalysis
  
  Volume: 11 Issue: 11 Pages: 6643-6655
- DOI
  10.1021/acscatal.1c01626
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-20K15277
[Journal Article] Aerobic oxygenation of α-methylene ketones under visible-light catalysed by a CeNi<sub>3</sub> complex with a macrocyclic tris(salen)-ligand2021
- Author(s)
  Nagae Haruki、Sakamoto Kazutaka、Fujiwara Sakiko、Schindler Tobias、Kon Yoshihiro、Sato Kazuhiko、Okuda Jun、Mashima Kazushi
- Journal Title
  
  Chemical Communications
  
  Volume: 57 Issue: 85 Pages: 11169-11172
- DOI
  10.1039/d1cc04540g
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-20K15277
[Journal Article] Esterification of Tertiary Amides: Remarkable Additive Effects of Potassium Alkoxides for Generating Hetero Manganese?Potassium Dinuclear Active Species2020
- Author(s)
  Hirai Takahiro、Kato Daiki、Mai Binh Khanh、Katayama Shoichiro、Akiyama Shoko、Nagae Haruki、Himo Fahmi、Mashima Kazushi
- Journal Title
  
  Chemistry ? A European Journal
  
  Volume: 26 Issue: 47 Pages: 10735-10742
- DOI
  10.1002/chem.202001447
- Peer Reviewed / Open Access / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-19J10174, KAKENHI-PROJECT-20K15277
[Journal Article] Lanthanide Complexes Supported by a Trizinc Crown Ether as Catalysts for Alternating Copolymerization of Epoxide and CO2: Telomerization Controlled by Carboxylate2018
- Author(s)
  Haruki Nagae, Ryota Aoki, Shin-nosuke Akutagawa, Julian Kleemann, Risa Tagawa, Tobias Schindler, Gyeongshin Choi, Thomas P. Spaniol, Hayato Tsurugi, Jun Okuda and Kazushi Mashima
- Journal Title
  
  Angewandte Chemie International Edition
  
  Volume: 57 Issue: 9 Pages: 2492-2496
- DOI
  10.1002/anie.201709218
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934, KAKENHI-PLANNED-15H05808
[Journal Article] Silica-Supported Isolated Molybdenum Di-oxo Species: Formation and Activation with Organosilicon Agent for Olefin Metathesis2018
- Author(s)
  Keishi Yamamoto, Ka Wing Chan, Victor Mougel, Haruki Nagae, Hayato Tsurugi, Olga V. Safonova, Kazushi Mashima, and Christophe Coperet
- Journal Title
  
  Chem. Commun.
  
  Volume: 54 Issue: 32 Pages: 3989-3992
- DOI
  10.1039/c8cc01876f
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-INTERNATIONAL-15K21707, KAKENHI-PLANNED-15H05808, KAKENHI-PROJECT-15KK0186, KAKENHI-PROJECT-16H06934
[Journal Article] Propargylic C(sp3)-H Bond Activation for Preparing η3-Propargyl/Allenyl Complexes of Yttrium2017
- Author(s)
  Nagae Haruki、Kundu Abhinanda、Tsurugi Hayato、Mashima Kazushi
- Journal Title
  
  Organometallics
  
  Volume: 36 Issue: 16 Pages: 3061-3067
- DOI
  10.1021/acs.organomet.7b00395
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15KT0064, KAKENHI-PROJECT-16H06934
[Journal Article] Arylimido-Bridged Dinuclear Ti(μ-NAr)2Ti Scaffold for Alkyne Insertion into ortho-C-H Bond of Arylimido Ligands2017
- Author(s)
  Haruki Nagae, Wataru Hato, Kento Kawakita, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Chemistry - A European Journal
  
  Volume: 23 Issue: 3 Pages: 586-596
- DOI
  10.1002/chem.201603580
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-16J04365, KAKENHI-PROJECT-15KT0064, KAKENHI-PLANNED-15H05808, KAKENHI-PROJECT-16H06934
[Presentation] 大環状配位子に支持されたCeNi3四核金属錯体を光誘起触媒とするα-メチレンケトンの空気酸化反応2022
- Author(s)
  Nagae, H.; Sakamoto, K.; Kon, Y.; Sato, K.; Okuda, J.; Mashima, K.
- Organizer
  第38回希土類討論会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] カチオン性CaCo3異種四核錯体触媒によるCO2とプロピレンオキシドの交互共重合反応2022
- Author(s)
  Nagae, H.; Matsushiro, S.; Okuda, J.; Mashima, K.
- Organizer
  第71回高分子討論会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] 二酸化炭素とエポキシドの交互共重合反応における連鎖移動反応を利用した末端官能基化手法2022
- Author(s)
  Nagae, H.; Matsushiro, S.; Sakamoto, K.; Iwasaki, T.; Nozaki, K.; Mashima, K.
- Organizer
  第71回高分子学会年次大会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] Asymmetric Hydrofunctionalization of 1,3-Dienes and C-nucleophiles Mediated by Ni/Cu Cooperative Catalyst2022
- Author(s)
  Haruki Nagae
- Organizer
  International Congress on Pure & Applied Chemistry 2022
- Invited / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] CaCo3錯体触媒によるエポキシドとCO2の交互共重合反応におけるアンモニウム塩の添加効果2022
- Author(s)
  松代　咲希、長江　春樹、奥田　純、真島　和志
- Organizer
  日本化学会第102春季年会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] Mechanism of Asymmetric Coupling of 1,3-Dienes and C-Nucleophiles by Ni/Cu Cooperative Catalysts by DFT Calculations2021
- Author(s)
  Haruki Nagae, Jingzhao Xia, Shoichiro Katayama, Takahiro Hirai, Wanbin Zhang, and Kazushi Mashima
- Organizer
  The 101st CSJ Annual Meeting
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] Hetero-Tetranuclear Complex Catalyzed Alternating Copolymerization of CO 2 and Epoxide in the Presence of Active Methylene Compounds as the Chain Transfer Agent2021
- Author(s)
  Haruki Nagae, Shin-ya Akebi, Takanori Iwasaki, Kyoko Nozaki, Kazushi Mashima
- Organizer
  第70回高分子学会年次大会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] セリウムとニッケルを含有する異種四核金属錯体を光誘起触媒とした化学選択的酸素化反応2021
- Author(s)
  坂本　和隆、長江　春樹、今　善祐、佐藤　一彦、奥田　純、真島　和志
- Organizer
  第67回有機金属化学討論会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] Asymmetric Coupling of 1,3-Dienes and C-Nucleophiles by Ni/Cu Cooperative Catalysts Bearing Planer Chiral Diphosphine Ligand2021
- Author(s)
  Takahiro Hirai, Jingzhao Xia, Shoichiro Katayama, Haruki Nagae, Wanbin Zhang, Kazushi Mashima
- Organizer
  The 101st CSJ Annual Meeting
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] Asymmetric Coupling of 1,3-Dienes and C-Nucleophiles by Ni/Cu Cooperative Catalysts and Its Mechanistic Study2021
- Author(s)
  Haruki Nagae, Jingzhao Xia, Takahiro Hirai, Shoichiro Katayama, Wanbin Zhang, Kazushi Mashima
- Organizer
  第67回有機金属化学討論会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] 希土類金属を含有する異種四核金属錯体を触媒とした二酸化炭素とエポキシドの交互共重合反応2020
- Author(s)
  長江春樹、松代咲希、芥川心之介、奥田　純、真島和志
- Organizer
  第36回希土類討論会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] セリウムと第一遷移金属を含有する異種四核金属錯体を光誘起触媒としたベンジル位の空気酸化反応2020
- Author(s)
  坂本和隆・藤原早季子・長江春樹・今喜裕・佐藤一彦・奥田純・真島和志
- Organizer
  錯体化学会第70回討論会
- Data Source
  KAKENHI-PROJECT-20K15277
[Presentation] Direct ortho-C-H bond aminoalkylation of pyridine derivatives catalyzed by yttrium complexes with diamido ligands2018
- Author(s)
  Mariko Inoue, Abhinanda Kundu, Haruki Nagae, Hayato Tsurugi and Kazushi Mashima
- Organizer
  Biotechnology and Chemistry for Green Growth
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934
[Presentation] 二座ジアミド配位子を有する希土類金属錯体を触媒としたピリジン誘導体のアミノアルキル化反応と反応メカニズムの解明2017
- Author(s)
  長江春樹，Abhinanda Kundu，劒隼人，真島和志
- Organizer
  第33回希土類討論会
- Data Source
  KAKENHI-PROJECT-16H06934
[Presentation] Yttrium-amide complexes for direct C-H aminoalkylation of 2-substituted pyridine derivatives2017
- Author(s)
  Kazushi Mashima, Abhinanda Kundu, Haruki Nagae and Hayato Tsurugi
- Organizer
  XXVIII. Tade der Seltenen Erden-Terrae Rarae 2017
- Invited / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934
[Presentation] Direct aminomethylation for an ortho C-H bond of N-heteroaromatic compounds catalyzed by triamido complexes of group 3 metals2016
- Author(s)
  Abhinanda Kundu, Haruki Nagae, Hayato Tsurugi, and Kazushi Mashima
- Organizer
  Third International symposium on C-H activation
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934
[Presentation] C－H bond functionalization reaction mediated by rare-earth metal complexes2016
- Author(s)
  Haruki Nagae
- Organizer
  Pre-symposium of Rare Earths 2016
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934
[Presentation] Rare-earth metal catalyzed aminoalkylation reaction of ortho-C-H bonds in pyridines2016
- Author(s)
  Haruki Nagae, Abhinanda Kundu, Hayato Tsurugi, and Kazushi Mashima
- Organizer
  USA-Japan Joint Workshop on C-H Bond Activation
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934
[Presentation] Direct aminomethylation for an ortho C-H bond of N-heteroaromatic compounds catalyzed by triamido complexes of group 3 metals2016
- Author(s)
  Abhinanda Kundu, Haruki Nagae, Hayato Tsurugi, and Kazushi Mashima
- Organizer
  International Symposium on C-O Activation
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934
[Presentation] Direct C-H aminoalkyaltion of 2-substituted pyridine derivatives catalyzed by yttrium catalysts with N,N'-diarylethylenediamido ligands2016
- Author(s)
  Abhinanda Kundu, Haruki Nagae, Hayato Tsurugi, and Kazushi Mashima
- Organizer
  JSPS Japanese-German Graduate Externship International Symposium, Aachen, Germany
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934
[Presentation] C-H bond activation of N-heteroaromatics catalyzed by group 3 metal complexes2016
- Author(s)
  Kazushi Mashima, Haruki Nagae, Yu Shibata, and Hayato Tsurugi
- Organizer
  Rare earth 2016 in Sapporo
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16H06934

1. TSURUGI Hayato

# of Collaborated Projects: 0 results

# of Collaborated Products: 1 results
2. 真島和志

# of Collaborated Projects: 0 results

# of Collaborated Products: 1 results

Nagae Haruki 長江 春樹

Research Projects

Research Products

Co-Researchers

Development of alkoxy-bridged dinuclear non-precious metal complex catalysts for synthesis and alcoholysis of amide derivativesPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Development of Catalytic Reaction Mediated by Early Transition Metal via Sigma-bond Metathesis ReactionPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] Nickel-Catalyzed Asymmetric Allylic Alkylation of β-Dicarbonyl Compounds via C-C Bond Activation of 2-Allylated Cyclic 1,3-Diketones2023

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Continuous Plug Flow Process for the Transesterification of Methyl Acrylate and 1,4-Butanediol by a Zn-Immobilized Catalyst for Producing 4-Hydroxybutyl Acrylate2022

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Chain Transfer Approach for Terminal Functionalization of Alternating Copolymerization of CO2 and Epoxide by Using Active Methylene Compounds as Chain Transfer Agents2022

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Runge-Kutta analysis for optimizing the Zn-catalyzed transesterification conditions of MA and MMA with diols to maximize monoesterified products2021

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Mechanistic Study of Ni and Cu Dual Catalyst for Asymmetric C-C Bond Formation; Asymmetric Coupling of 1,3-Dienes with C-nucleophiles to Construct Vicinal Stereocenters2021

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Aerobic oxygenation of α-methylene ketones under visible-light catalysed by a CeNi<sub>3</sub> complex with a macrocyclic tris(salen)-ligand2021

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Esterification of Tertiary Amides: Remarkable Additive Effects of Potassium Alkoxides for Generating Hetero Manganese?Potassium Dinuclear Active Species2020

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Lanthanide Complexes Supported by a Trizinc Crown Ether as Catalysts for Alternating Copolymerization of Epoxide and CO2: Telomerization Controlled by Carboxylate2018

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Silica-Supported Isolated Molybdenum Di-oxo Species: Formation and Activation with Organosilicon Agent for Olefin Metathesis2018

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Propargylic C(sp3)-H Bond Activation for Preparing η3-Propargyl/Allenyl Complexes of Yttrium2017

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Arylimido-Bridged Dinuclear Ti(μ-NAr)2Ti Scaffold for Alkyne Insertion into ortho-C-H Bond of Arylimido Ligands2017

Author(s)

Journal Title

DOI

Data Source

[Presentation] 大環状配位子に支持されたCeNi3四核金属錯体を光誘起触媒とするα-メチレンケトンの空気酸化反応2022

Author(s)

Organizer

Data Source

[Presentation] カチオン性CaCo3異種四核錯体触媒によるCO2とプロピレンオキシドの交互共重合反応2022

Author(s)

Organizer

Data Source

[Presentation] 二酸化炭素とエポキシドの交互共重合反応における連鎖移動反応を利用した末端官能基化手法2022

Nagae Haruki 長江春樹