SAKABA Hiroyuki 坂場裕之

Researcher Number	60162301
Affiliation (based on the past Project Information) *help	2012: 東北大学, 理学(系)研究科(研究院), 准教授 2010 – 2012: 東北大学, 大学院・理学研究科, 准教授 2003 – 2004: 東北大学, 大学院・理学研究科, 助教授 1999 – 2000: 東北大学, 大学院・理学研究科, 助教授 1998: 東北大学, 大学院理学研究科, 助教授 1997: 東北大学, 大学院・理学研究科, 助教授
Review Section/Research Field	Principal Investigator Inorganic chemistry / Inorganic chemistry Except Principal Investigator 物質変換
Keywords	Principal Investigator Si-H結合活性化 / ヒドロシラン / シリレン錯体 / Si-H bond activation / シリル(シリレン)錯体 / シラアリル錯体 / シラプロパルギル錯体 / モリブデン錯体 / タングステン錯体 / Alkene hydride complexes … More / Interligand hypervalent interaction / Silapropargyl complexes / Silaallyl complexes / Silyl(silylene) complexes / Silylene complexes / Hydrosilanes / 配位子間超原子価相互作業 / 架橋アルキニル錯体 / アルケン挿入 / ヒドリドアルケン錯体 / ジヒドリド(シリル)錯体 / ヒドリド(シリル)錯体 / アルケンヒドリド錯体 / 配位子間超原子価相互作用 / hydrosilane / C-H bond activation / thiophene / insertion reaction / silylene complex / molybdenum complex / tungsten complex / レニウム / ヘテロ二核錯体 / シレニル錯体 / ヒドリド錯体 / シリル錯体 / 再分配反応 / モリブデン / タングステン / ヒドリド(シリレン)錯体 / C-H結合活性化 / チオフェン / 挿入反応 / カルビン錯体 / ビニリデン錯体 / 三員環錯体 / H/D交換反応 / アゴスティック相互作用 / シラアリル錯体 / ゲルミレン錯体 … More Except Principal Investigator 反応中間体の安定化 / アルキル置換メタロセン / チタノセン誘導体 / 配位不飽和錯体 / パラフィンマトリックス / アルキル置換チタノセン Less

Study on the Synthesis and Reactivity of Transition Metal Complexes with Novel Ligands Containing Group 14 ElementsPrincipal Investigator
- Principal Investigator
  
  SAKABA Hiroyuki
- Project Period (FY)
  2010 – 2012
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University
Synthesis of metal complexes with highly reactive silicon species as ligands via Si-H bond activation and their reactivityPrincipal Investigator
- Principal Investigator
  
  SAKABA Hiroyuki
- Project Period (FY)
  2003 – 2004
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University
Studies on the Reactivity of a Labile Tungsten Acetonitrile ComplexPrincipal Investigator
- Principal Investigator
  
  SAKABA Hiroyuki
- Project Period (FY)
  1998 – 2000
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Inorganic chemistry
- Research Institution
  Tohoku University
パラフィン中で安定化する配位不飽和錯体の生成とその構造および反応性の研究
- Principal Investigator
  
  HORINO Hiroshi
- Project Period (FY)
  1997 – 1999
- Research Category
  
  Grant-in-Aid for Exploratory Research
- Research Field
  
  物質変換
- Research Institution
  Tohoku University

All 2013 2012 2011 2010 2005 2003 Other

All Journal Article Presentation

[Journal Article] Reactions of Tungsten Acetylide-Silylene Complexes with Pyridines: Direct Observation of Silylene/Silyl Migration in Tungsten Acetylide and Carbyne/Vinylidene Frameworks2012
- Author(s)
  坂場裕之 ,尾池浩幸,新井康弘,權垠相
- Journal Title
  
  Organometallics
  
  Volume: Vol.31, No.23 Issue: 23 Pages: 8172-8177
- DOI
  10.1021/om300772c
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22550051
[Journal Article] Synthesis, Structure, and Bonding Nature of Ethynediyl-Bridged Bis (silylene) Dinuclear Complexes of Tungsten and Molybdenum2011
- Author(s)
  坂場裕之, 他
- Journal Title
  
  Organometallics
  
  Volume: 30 Pages: 4515-4531
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22550051
[Journal Article] Synthesis, Structure, and Bonding Nature of Ethynediyl-Bridged Bis(silylene) Dinuclear Complexes of Tungsten and Molybdenum2011
- Author(s)
  坂場裕之,尾池浩幸,河合正昭,高見将人,甲千寿子,Mausumi Ray, 中尾嘉秀, 佐藤啓文,榊茂好
- Journal Title
  
  Organometallics
  
  Volume: Vol.30, No.17 Issue: 17 Pages: 4515-4531
- DOI
  10.1021/om200096z
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22550051
[Journal Article] Conversion of an Acetylide-Silylene Complex to an Alkenylcarbyne Complex by Consecutive Ketone Addition and Base-Induced Silanone Elimination2010
- Author(s)
  坂場裕之
- Journal Title
  
  Organometallics
  
  Volume: 29 Pages: 4115-4119
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22550051
[Journal Article] Conversion of an Acetylide-Silylene Complex to an Alkenylcarbyne Complex by Consecutive Ketone Addition and Base-Induced Silanone Elimination2010
- Author(s)
  坂場裕之,矢部真炎,尾池浩幸,甲千寿子
- Journal Title
  
  Organometallics
  
  Volume: Vol.29, No.18 Issue: 18 Pages: 4115-4119
- DOI
  10.1021/om1005879
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22550051
[Journal Article] η^1:η^2-Alkynyl-Bridged W-Si Complexes : Formation, Structure, and Reaction with Acetone2005
- Author(s)
  Hiroyuki Sakaba
- Journal Title
  
  Journal of the American Chemical Society 127(印刷中)
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15550045
[Journal Article] η^1:η^2-Alkynyl-Bridged W-Si Complexes : Formation, Structure and Reaction with Acetone2005
- Author(s)
  Hiroyuki Sakaba
- Journal Title
  
  Journal of the American Chemical Society 127(in press)
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-15550045
[Journal Article] Novel η^3-1-Silaallyl Tungsten Complexes via Si-H Bond Activation of Hydrovinylsilanes : Structure and Reactivity toward Methanol2003
- Author(s)
  Hiroyuki Sakaba
- Journal Title
  
  Journal of the American Chemical Society 125
  
  Pages: 2842-2843
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15550045
[Presentation] アセチリド-シリレンタングステン錯体とアセトンの反応に及ぼす置換基および溶媒効果2013
- Author(s)
  中川圭太,權垠相,豊田耕三,坂場裕之
- Organizer
  日本化学会第93春季年会
- Place of Presentation
  草津市
- Year and Date
  2013-03-22
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] アセチリド-シリレンタングステン錯体の構造と反応性に及ぼす置換基効果2012
- Author(s)
  中川圭太,權垠相,坂場裕之
- Organizer
  平成24年度化学系学協会東北大会
- Place of Presentation
  秋田市
- Year and Date
  2012-09-16
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] W-Si-N三員環錯体の合成,構造と反応性2011
- Author(s)
  外崎宏樹,權垠相,坂場裕之
- Organizer
  平成23年度化学系学協会東北大会
- Place of Presentation
  仙台市
- Year and Date
  2011-09-18
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] ヒドリド(シレン)タングステン錯体の合成と反応性2011
- Author(s)
  吉田孝利,永井満家,坂場裕之
- Organizer
  第58回有機金属化学討論会
- Place of Presentation
  名古屋市
- Year and Date
  2011-09-08
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] アセチリドーゲルミレンタングステン錯体の合成、構造と反応性2011
- Author(s)
  坂場裕之
- Organizer
  日本化学会第91春季年会
- Place of Presentation
  神奈川大学(神奈川県)
- Year and Date
  2011-03-29
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] アセチリド‐ゲルミレンタングステン錯体の合成、構造と反応性2011
- Author(s)
  新井康広,菅沼憲正,權垠相,坂場裕之
- Organizer
  日本化学会第91春季年会
- Place of Presentation
  横浜市
- Year and Date
  2011-03-29
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] シラアリルモリブデンおよびタングステン錯体の合成,構造とアミンに対する反応性2010
- Author(s)
  坂場裕之
- Organizer
  第57回有機金属化学討論会
- Place of Presentation
  中央大学(東京都)
- Year and Date
  2010-09-16
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] シラアリルモリブデンおよびタングステン錯体の合成,構造とアミンに対する反応性2010
- Author(s)
  外崎宏樹,權垠相,坂場裕之
- Organizer
  第57回有機金属化学討論会
- Place of Presentation
  東京
- Year and Date
  2010-09-16
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] アセチリド-シリレンタングステン錯体の構造と反応性に及ぼす置換基効果
- Author(s)
  坂場裕之（代表者）
- Organizer
  平成24年度化学系学協会東北大会
- Place of Presentation
  秋田大学（秋田県）
- Data Source
  KAKENHI-PROJECT-22550051
[Presentation] アセチリド-シリレンタングステン錯体とアセトンの反応に及ぼす置換基および溶媒効果
- Author(s)
  坂場裕之（代表者）
- Organizer
  日本化学会第93春季年会
- Place of Presentation
  立命館大学（滋賀県）
- Data Source
  KAKENHI-PROJECT-22550051

1. HORINO Hiroshi (40005765)

# of Collaborated Projects: 2 results

# of Collaborated Products: 0 results
2. 長南幸安 (30250674)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results

SAKABA Hiroyuki 坂場 裕之

Research Projects

Research Products

Co-Researchers

Study on the Synthesis and Reactivity of Transition Metal Complexes with Novel Ligands Containing Group 14 ElementsPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Synthesis of metal complexes with highly reactive silicon species as ligands via Si-H bond activation and their reactivityPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Studies on the Reactivity of a Labile Tungsten Acetonitrile ComplexPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

パラフィン中で安定化する配位不飽和錯体の生成とその構造および反応性の研究

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] Reactions of Tungsten Acetylide-Silylene Complexes with Pyridines: Direct Observation of Silylene/Silyl Migration in Tungsten Acetylide and Carbyne/Vinylidene Frameworks2012

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Synthesis, Structure, and Bonding Nature of Ethynediyl-Bridged Bis (silylene) Dinuclear Complexes of Tungsten and Molybdenum2011

Author(s)

Journal Title

Data Source

[Journal Article] Synthesis, Structure, and Bonding Nature of Ethynediyl-Bridged Bis(silylene) Dinuclear Complexes of Tungsten and Molybdenum2011

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Conversion of an Acetylide-Silylene Complex to an Alkenylcarbyne Complex by Consecutive Ketone Addition and Base-Induced Silanone Elimination2010

Author(s)

Journal Title

Data Source

[Journal Article] Conversion of an Acetylide-Silylene Complex to an Alkenylcarbyne Complex by Consecutive Ketone Addition and Base-Induced Silanone Elimination2010

Author(s)

Journal Title

DOI

Data Source

[Journal Article] η^1:η^2-Alkynyl-Bridged W-Si Complexes : Formation, Structure, and Reaction with Acetone2005

Author(s)

Journal Title

Description

Data Source

[Journal Article] η^1:η^2-Alkynyl-Bridged W-Si Complexes : Formation, Structure and Reaction with Acetone2005

Author(s)

Journal Title

Description

Data Source

[Journal Article] Novel η^3-1-Silaallyl Tungsten Complexes via Si-H Bond Activation of Hydrovinylsilanes : Structure and Reactivity toward Methanol2003

Author(s)

Journal Title

Description

Data Source

[Presentation] アセチリド-シリレンタングステン錯体とアセトンの反応に及ぼす置換基および溶媒効果2013

Author(s)

Organizer

Place of Presentation

Year and Date

Data Source

[Presentation] アセチリド-シリレンタングステン錯体の構造と反応性に及ぼす置換基効果2012

Author(s)

Organizer

Place of Presentation

Year and Date

Data Source

[Presentation] W-Si-N三員環錯体の合成,構造と反応性2011

Author(s)

SAKABA Hiroyuki 坂場裕之