Tsurugi Hayato 劔隼人

… Alternative Names

TSURUGI Hayato 劔隼人

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Researcher Number	60432514
Other IDs
Affiliation (Current)	2025: 大阪大学, 大学院工学研究科, 教授
Affiliation (based on the past Project Information) *help	2024 – 2025: 大阪大学, 大学院工学研究科, 教授 2021 – 2023: 大阪大学, 大学院基礎工学研究科, 准教授 2013 – 2021: 大阪大学, 基礎工学研究科, 准教授 2010: Osaka University, 大学院・基礎工学研究科, 講師 2009 – 2010: 大阪大学, 基礎工学研究科, 講師
Review Section/Research Field	Principal Investigator Science and Engineering / Transformative Research Areas, Section (II) / Synthetic chemistry / Basic Section 33020:Synthetic organic chemistry-related / Medium-sized Section 33:Organic chemistry and related fields / Transition State Control
Keywords	Principal Investigator 光触媒 / 触媒反応 / カルボン酸 / 金属クラスター錯体 / クラスター錯体 / 前周期遷移金属 / 脱炭酸 / セリウム / 金属クラスター / ラジカル反応 … More / 低原子価錯体 / DFT計算 / 金属酸化物 / アルコキシド架橋 / 炭素－水素結合活性化 / 還元反応 / 表面有機金属化学 / 有機ケイ素還元剤 / 二核錯体 / 酸化還元 / 前周期遷移金属錯体 / ラジカル発生 / 易酸化性官能基 / 反応中間体 / 環化付加 / 金属錯体触媒 / ヘテロール合成 / 可視光 / アルコール / 光励起 / クラスター / ジルコニウム / 多核錯体 / 脱炭酸反応 / ラジカル / ヒドラジン化反応 / 酸素化反応 / αカルボニルラジカル / 光照射 / 酸素酸化 / DFT / アミノアルケン / 不斉錯体触媒 / アミン / 不斉触媒反応 / MOF / ヒドリド種 / 二酸化炭素還元 / 希土類金属錯体 / アゴスティック相互作用 / ヒドリド錯体 / 銅 / 非対称配位圏 / 酸素化 / 遷移状態 / イミド架橋 / 炭素―水素結合活性化 / 構造変化 / メタラサイクル / アルコール酸化 / 酸素架橋 / カチオン性錯体 / ハフニウム錯体 / シグマ結合メタセシス / 金属－炭素結合 / ニッケルナノ粒子 / 有機ケイ素 / 還元 / 還元的炭素―炭素結合形成 / 遷移金属錯体 / 有機ケイ素化合物 / 異種金属錯体 / 配位高分子 / 異種金属多核錯体 / メタラシクロペンタジエン / 金属間結合 / 多核金属クラスター / 有機分子還元剤 / 固体触媒 / ピロール合成 / イミド配位子 / 還元的活性化 / メタロリガンド / アゾ化合物 / 環化付加反応 / メタセシス反応 / 還元的切断 / 炭素－ハロゲン結合切断 / 金属間多重結合 / 脱ハロゲン化 / クラスター触媒 / カップリング反応 / 炭素-水素結合活性化 Less

Development of Radical Transformations by Photo-active Metal Cluster CatalystsPrincipal Investigator
- Principal Investigator
  
  劔隼人
- Project Period (FY)
  2024 – 2026
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Review Section
  
  Basic Section 33020:Synthetic organic chemistry-related
- Research Institution
  Osaka University
Development of Transition Metal Catalysts for Synthesizing Polysubstituted Heteroles Using Degitalized Intermediate ParametersPrincipal Investigator
- Principal Investigator
  
  劔隼人
- Project Period (FY)
  2024 – 2025
- Research Category
  
  Grant-in-Aid for Transformative Research Areas (A)
- Review Section
  
  Transformative Research Areas, Section (II)
- Research Institution
  The University of Osaka
Controlled Radical Generation from Carboxylic Acids with Readily Oxidizable Functional Groups by Metal Cluster PhotocatalystsPrincipal Investigator
- Principal Investigator
  
  劔隼人
- Project Period (FY)
  2024 – 2025
- Research Category
  
  Grant-in-Aid for Transformative Research Areas (A)
- Review Section
  
  Transformative Research Areas, Section (II)
- Research Institution
  The University of Osaka
Development of asymmetric early transition metal catalysts for synthesizing chiral aminoalkenesPrincipal Investigator
- Principal Investigator
  
  劔隼人
- Project Period (FY)
  2022 – 2023
- Research Category
  
  Grant-in-Aid for Transformative Research Areas (A)
- Review Section
  
  Transformative Research Areas, Section (II)
- Research Institution
  Osaka University
Development of cerium-containing MOFs as photo-catalysts for transformation of light alkanesPrincipal Investigator
- Principal Investigator
  
  TSURUGI HAYATO
- Project Period (FY)
  2021 – 2022
- Research Category
  
  Grant-in-Aid for Challenging Research (Exploratory)
- Review Section
  
  Medium-sized Section 33:Organic chemistry and related fields
- Research Institution
  Osaka University
Development of O2-oxidation catalyzed by homo and heteronuclear multimetallic cerium complexesPrincipal Investigator
- Principal Investigator
  
  Tsurugi Hayato
- Project Period (FY)
  2020 – 2022
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Review Section
  
  Basic Section 33020:Synthetic organic chemistry-related
- Research Institution
  Osaka University
Precise Design of Asymmetric Coordination Sphere by Complexation of Mononuclear and Cluster Complexes for Developing Novel Catalytic TransformationPrincipal Investigator
- Principal Investigator
  
  劔隼人
- Project Period (FY)
  2019 – 2020
- Research Category
  
  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
- Review Section
  
  Science and Engineering
- Research Institution
  Osaka University
Development of Novel Metal Hydride Catalysts Composed of Transition Metal Hydrides and Perovskite OxidesPrincipal Investigator
- Principal Investigator
  
  劔隼人
- Project Period (FY)
  2019 – 2020
- Research Category
  
  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
- Review Section
  
  Science and Engineering
- Research Institution
  Osaka University
Development of flexibly designable organic reducing agents and their application(Fostering Joint International Research)Principal Investigator
- Principal Investigator
  
  Tsurugi Hayato
- Project Period (FY)
  2016 – 2019
- Research Category
  
  Fund for the Promotion of Joint International Research (Fostering Joint International Research)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Osaka University
同種・異種金属元素ブロックの機能開発と高分子化による高性能触媒材料の創出Principal Investigator
- Principal Investigator
  
  劔隼人
- Project Period (FY)
  2015 – 2016
- Research Category
  
  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
- Review Section
  
  Science and Engineering
- Research Institution
  Osaka University
Development of metal cluster catalysts by controlling the transition state for C-H bond activation on metal clustersPrincipal Investigator
- Principal Investigator
  
  Tsurugi Hayato
- Project Period (FY)
  2015 – 2019
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Transition State Control
- Research Institution
  Osaka University
Development of Structurally Tunable Organic-based ReductantsPrincipal Investigator
- Principal Investigator
  
  Tsurugi Hayato
- Project Period (FY)
  2014 – 2017
- Research Category
  
  Grant-in-Aid for Young Scientists (A)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Osaka University
金属間多重結合含有クラスターを元素ブロックとしたレドックス活性高分子材料の創出Principal Investigator
- Principal Investigator
  
  劔隼人
- Project Period (FY)
  2013 – 2014
- Research Category
  
  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
- Review Section
  
  Science and Engineering
- Research Institution
  Osaka University
Development of High- and Low-valent Early Transition Metal Catalysts for Carbon-Carbon Bond Forming ReactionPrincipal Investigator
- Principal Investigator
  
  TSURUGI Hayato
- Project Period (FY)
  2009 – 2010
- Research Category
  
  Grant-in-Aid for Young Scientists (B)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Osaka University

All 2023 2022 2021 2020 2019 2018 2017 2016 2015 2014

All Journal Article Presentation

[Journal Article] Chromium-catalyzed olefination of arylaldehydes with haloforms assisted by 2,3,5,6-tetramethyl-N,N′-bis(trimethylsilyl)-1,4-dihydropyrazine2023
- Author(s)
 Nishi Kohei、Tsurugi Hayato、Mashima Kazushi
- Journal Title
 
 Chemical Communications
 
 Volume: 59 Issue: 7 Pages: 908-911
- DOI
 10.1039/d2cc06104j
- Peer Reviewed
- Data Source
 KAKENHI-PROJECT-20H02742
[Journal Article] Chromium-Catalyzed syn-Selective Ring-Opening Aryl-/Alkylation of 7-Oxabenzonorbornadiene Derivatives with Grignard Reagents2023
- Author(s)
 Nishi Kohei、Tsurugi Hayato、Mashima Kazushi
- Journal Title
 
 ACS Catalysis
 
 Volume: 13 Issue: 5 Pages: 3093-3100
- DOI
 10.1021/acscatal.2c05029
- Peer Reviewed
- Data Source
 KAKENHI-PROJECT-20H02742
[Journal Article] N-Methylation of Aniline Derivatives with CO2 and Phenylsilane Catalyzed by Lanthanum Hydridotriarylborate Complexes bearing a Nitrogen Tridentate Ligand2022
- Author(s)
  Shinohara Koichi、Tsurugi Hayato、Mashima Kazushi
- Journal Title
  
  ACS Catalysis
  
  Volume: 12 Issue: 14 Pages: 8220-8228
- DOI
  10.1021/acscatal.2c01658
- Peer Reviewed
- Data Source
  KAKENHI-PLANNED-18H05517, KAKENHI-PROJECT-20H02742
[Journal Article] Syntheses and Redox Properties of Carboxylate-Ligated Hexanuclear Ce(IV) Clusters and Their Photoinduced Homolysis of the Ce(IV)-Ligand Covalent Bond2022
- Author(s)
  Tomomi Kawakami, Sota Tamaki, Satoru Shirase, Hayato, Tsurugi, Kazushi Mashima
- Journal Title
  
  Inorganic Chemistry
  
  Volume: 61 Issue: 50 Pages: 20461-20471
- DOI
  10.1021/acs.inorgchem.2c03163
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-22KJ2211, KAKENHI-PROJECT-20H02742
[Journal Article] Pyrazine Alkylation with Aldehydes and Haloalkanes Using N,N’ ‐Bis(trimethylsilyl)‐1,4‐dihydropyrazine Derivatives2022
- Author(s)
 Tsurugi Hayato、Matsuno Minami、Kawakami Tomomi、Mashima Kazushi
- Journal Title
 
 European Journal of Organic Chemistry
 
 Volume: 2022 Issue: 41
- DOI
 10.1002/ejoc.202200862
- Peer Reviewed
- Data Source
 KAKENHI-PROJECT-20H02742
[Journal Article] Renaissance of Homogeneous Cerium Catalysts with Unique ????Ce(IV/III) Couple: Redox-Mediated Organic Transformations Involving Homolysis of Ce(IV)?Ligand Covalent Bonds2021
- Author(s)
  Tsurugi Hayato、Mashima Kazushi
- Journal Title
  
  Journal of the American Chemical Society
  
  Volume: 143 Issue: 21 Pages: 7879-7890
- DOI
  10.1021/jacs.1c02889
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20H02742
[Journal Article] Cerium(IV) Carboxylate Photocatalyst for Catalytic Radical Formation from Carboxylic Acids: Decarboxylative Oxygenation of Aliphatic Carboxylic Acids and Lactonization of Aromatic Carboxylic Acids2020
- Author(s)
  Satoru Shirase, Sota Tamaki, Koichi Shinohara, Keishi Hirosawa, Hayato Tsurugi, Tetsuya Satoh, Kazushi Mashima
- Journal Title
  
  Journal of the American Chemical Society
  
  Volume: 142 Issue: 12 Pages: 5668-5675
- DOI
  10.1021/jacs.9b12918
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-18J11584, KAKENHI-PLANNED-15H05808, KAKENHI-PUBLICLY-18H04267, KAKENHI-PUBLICLY-19H04578
[Journal Article] Synthesis, Structure, and Reactivity of Dicationic Bimetallic Tetrabenzyldihafnium Complexes Bearing a Chelating (2-Hydroxyethyl)amido Ligand2020
- Author(s)
  Mariko Inoue, Michael J. Lopez, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Organometallics
  
  Volume: 39 Pages: 614-622
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15KT0064
[Journal Article] Cobalt‐Catalyzed E‐Selective Cross‐Dimerization of Terminal Alkynes: A Mechanism Involving Cobalt(0/II) Redox Cycles2020
- Author(s)
  Yohei Ueda
- Journal Title
  
  Angewandte Chemie International Edition
  
  Volume: 59 Issue: 4 Pages: 1552-1556
- DOI
  10.1002/anie.201913835
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-17J03451, KAKENHI-PLANNED-15H05808, KAKENHI-PUBLICLY-19H05057
[Journal Article] Reactivity of terminal imido complexes of group 4?6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules2020
- Author(s)
  Kawakita Kento、Parker Bernard F.、Kakiuchi Yuya、Tsurugi Hayato、Mashima Kazushi、Arnold John、Tonks Ian A.
- Journal Title
  
  Coordination Chemistry Reviews
  
  Volume: 407 Pages: 213118-213118
- DOI
  10.1016/j.ccr.2019.213118
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KK0186
[Journal Article] Synthesis and Characterization of Alkoxide-Bridged Heterometallic Clusters of Cerium and Copper2019
- Author(s)
  Tsurugi Hayato、Ikeda Yuri、Shinohara Koichi、Shirase Satoru、Toya Nozomi、Tanaka Shinji、Mashima Kazushi
- Journal Title
  
  Inorganic Chemistry
  
  Volume: 58 Issue: 19 Pages: 12565-12572
- DOI
  10.1021/acs.inorgchem.9b01213
- Peer Reviewed
- Data Source
  KAKENHI-PLANNED-15H05808, KAKENHI-PUBLICLY-19H04578
[Journal Article] Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles2019
- Author(s)
  Kento Kawakita, Evan P. Beaumier, Yuya Kakiuchi, Hayato Tsurugi, Ian A. Tonks, Kazushi Mashima
- Journal Title
  
  Journal of the American Chemical Society
  
  Volume: 141 Issue: 10 Pages: 4194-4198
- DOI
  10.1021/jacs.8b13390
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KK0186, KAKENHI-INTERNATIONAL-15K21707, KAKENHI-PROJECT-16J04365
[Journal Article] Synthesis of Pyridylimido Complexes of Tantalum and Niobium by Reductive Cleavage of the N?N Bond of 2,2′-Azopyridine: Precursors for Early?Late Heterobimetallic Complexes2019
- Author(s)
  Kawakita Kento、Kakiuchi Yuya、Beaumier Evan P.、Tonks Ian A.、Tsurugi Hayato、Mashima Kazushi
- Journal Title
  
  Inorganic Chemistry
  
  Volume: 58 Issue: 22 Pages: 15155-15165
- DOI
  10.1021/acs.inorgchem.9b02043
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KK0186, KAKENHI-PLANNED-15H05808, KAKENHI-INTERNATIONAL-15K21707
[Journal Article] Cβ?Cβ Bond Fission of Metallacyclopentadiene over a Low-Valent Ditantalum Scaffold2019
- Author(s)
  Laskar Payel、Yamamoto Keishi、Nishi Kohei、Ikeda Hideaki、Tsurugi Hayato、Mashima Kazushi
- Journal Title
  
  Organometallics
  
  Volume: 38 Issue: 3 Pages: 722-729
- DOI
  10.1021/acs.organomet.8b00914
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15KT0064
[Journal Article] Activation of O2 by Organosilicon Reagents Yields Quantitative Amounts of H2O2 or (Me3Si)2O2 for Efficient O‐Transfer Reactions2018
- Author(s)
  Keishi Yamamoto, Shinji Tanaka, Hiromu Hosoya, Hayato Tsurugi, Kazushi Mashima, Christophe Coperet
- Journal Title
  
  Helvetica Chimica Acta
  
  Volume: 101 Issue: 12
- DOI
  10.1002/hlca.201800156
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KK0186, KAKENHI-INTERNATIONAL-15K21707, KAKENHI-PLANNED-15H05808
[Journal Article] Organosilicon Reducing Reagents for Stereoselective Formations of Silyl Enol Ethers from α-Halo Carbonyl Compounds2018
- Author(s)
  Paramanik Suman, Rej Supriya, Shun Kando, Hayato Tsurugi, and Kazushi Mashima
- Journal Title
  
  The Journal of Organic Chemistry
  
  Volume: 83 Issue: 4 Pages: 2409-2417
- DOI
  10.1021/acs.joc.7b03005
- Peer Reviewed
- Data Source
  KAKENHI-PLANNED-15H05808, KAKENHI-PROJECT-26708012
[Journal Article] Silica-Supported Isolated Molybdenum Di-oxo Species: Formation and Activation with Organosilicon Agent for Olefin Metathesis2018
- Author(s)
  Keishi Yamamoto, Ka Wing Chan, Victor Mougel, Haruki Nagae, Hayato Tsurugi, Olga V. Safonova, Kazushi Mashima, and Christophe Coperet
- Journal Title
  
  Chem. Commun.
  
  Volume: 54 Issue: 32 Pages: 3989-3992
- DOI
  10.1039/c8cc01876f
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-INTERNATIONAL-15K21707, KAKENHI-PLANNED-15H05808, KAKENHI-PROJECT-15KK0186, KAKENHI-PROJECT-16H06934
[Journal Article] Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Oxo-Bridged Dinuclear Cerium Complexes with Pentadentate Schiff-Base Ligands under a Dioxygen Atmosphere2018
- Author(s)
  Shirase Satoru、Shinohara Koichi、Tsurugi Hayato、Mashima Kazushi
- Journal Title
  
  ACS Catalysis
  
  Volume: 8 Issue: 8 Pages: 6939-6947
- DOI
  10.1021/acscatal.8b01718
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15KT0064, KAKENHI-PLANNED-15H05808
[Journal Article] Dehalogenation of vicinal dihalo compounds by 1,1'-bis(trimethylsilyl)-1H,1'H-4,4'-bipyridinylidene for giving alkenes and alkynes in a salt-free manner2017
- Author(s)
  Supriya Rej, Suman Pramanik, Hayato Tsurugi, and Kazushi Mashima
- Journal Title
  
  Chemical Communications
  
  Volume: 53 Issue: 98 Pages: 13157-13160
- DOI
  10.1039/c7cc07377a
- Peer Reviewed
- Data Source
  KAKENHI-PLANNED-15H05808, KAKENHI-PROJECT-26708012
[Journal Article] Propargylic C(sp3)-H Bond Activation for Preparing η3-Propargyl/Allenyl Complexes of Yttrium2017
- Author(s)
  Nagae Haruki、Kundu Abhinanda、Tsurugi Hayato、Mashima Kazushi
- Journal Title
  
  Organometallics
  
  Volume: 36 Issue: 16 Pages: 3061-3067
- DOI
  10.1021/acs.organomet.7b00395
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15KT0064, KAKENHI-PROJECT-16H06934
[Journal Article] Mixed Ligated Tris(amidinate)dimolybdenum Complexes as Catalysts for Radical Addition of CCl4 to 1-Hexene: Leaving Ligand Lability Controls Catalyst Activity2017
- Author(s)
  Supriya Rej, Moumita Majumdar, Shun Kando, Yoshitaka Sugino, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Inorg. Chem.
  
  Volume: 56 Issue: 1 Pages: 634-644
- DOI
  10.1021/acs.inorgchem.6b02525
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PUBLICLY-15H00743, KAKENHI-PLANNED-15H05808
[Journal Article] Arylimido-Bridged Dinuclear Ti(μ-NAr)2Ti Scaffold for Alkyne Insertion into ortho-C-H Bond of Arylimido Ligands2017
- Author(s)
  Haruki Nagae, Wataru Hato, Kento Kawakita, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Chemistry - A European Journal
  
  Volume: 23 Issue: 3 Pages: 586-596
- DOI
  10.1002/chem.201603580
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-16J04365, KAKENHI-PROJECT-15KT0064, KAKENHI-PLANNED-15H05808, KAKENHI-PROJECT-16H06934
[Journal Article] Inorganic-Salt-Free Reduction in Main-Group Chemistry: Synthesis of a Dibismuthene and a Distibene2017
- Author(s)
  Paresh Kumar Majhi, Hideaki Ikeda, Takahiro Sasamori, Hayato Tsurugi, Kazushi Mashima, Norihiro Tokitoh
- Journal Title
  
  Organometallics
  
  Volume: 36 Issue: 7 Pages: 1224-1226
- DOI
  10.1021/acs.organomet.7b00147
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PUBLICLY-15H00743, KAKENHI-PROJECT-16H04110, KAKENHI-PROJECT-16F16335
[Journal Article] C(sp3)-H Alkenylation Catalyzed by Cationic Alkylhafnium Complexes: Stereoselective Synthesis of Trisubstituted Alkenes from 2,6-Dimethylpyridines and Internal Alkynes2016
- Author(s)
  Michael J. Lopez, Ai Kondo, Haruki Nagae, Koji Yamamoto, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Organometallics
  
  Volume: 35 Issue: 22 Pages: 3816-3827
- DOI
  10.1021/acs.organomet.6b00655
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-15KT0064
[Journal Article] Synthesis and Reactions of Ditantalum-Allyl Complexes Derived from Intramolecular C-H Bond Activation of the Methylene of the Ethyl Group2016
- Author(s)
  Keishi Yamamoto, Haruki Nagae, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Organometallics
  
  Volume: 35 Issue: 14 Pages: 2384-2390
- DOI
  10.1021/acs.organomet.6b00402
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-15KT0064
[Journal Article] Low Temperature Activation of Supported Metathesis Catalysts by Organosilicon Reducing Agents2016
- Author(s)
  Victor Mougel, Ka-Wing Chan, Georges Siddiqi, Kento Kawakita, Haruki Nagae, Hayato Tsurugi, Kazushi Mashima, Olga Safonova, Christophe Coperet
- Journal Title
  
  ACS Central Science
  
  Volume: 2 Issue: 8 Pages: 569-576
- DOI
  10.1021/acscentsci.6b00176
- Peer Reviewed / Acknowledgement Compliant / Open Access / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-16J04365, KAKENHI-PROJECT-26708012, KAKENHI-INTERNATIONAL-15K21707, KAKENHI-PLANNED-15H05808
[Journal Article] Alkyne-induced Facile C-C Bond Formation of Two η2-Alkynes on Dinuclear Tantalum Bis(alkyne) Complexes to Give Dinuclear Tantallacyclopentadienes2016
- Author(s)
  Keishi Yamamoto, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Organometallics
  
  Volume: 35 Issue: 10 Pages: 1573-1581
- DOI
  10.1021/acs.organomet.6b00182
- Peer Reviewed
- Data Source
  KAKENHI-PUBLICLY-15H00743, KAKENHI-PLANNED-15H05808
[Journal Article] λSynthesis and Characterization of Paramagnetic Tungsten Imido Complexes Bearing α-Diimine Ligands2016
- Author(s)
  Tanahashi, H.; Ikeda, H.; Tsurugi, H.; Mashima, K.
- Journal Title
  
  Inorg. Chem.
  
  Volume: 55 Issue: 4 Pages: 1446-1452
- DOI
  10.1021/acs.inorgchem.5b02145
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-26248028, KAKENHI-PROJECT-26708012
[Journal Article] Synthesis and Characterization of Heterobimetallic Tantalum-Rhodium and Tantalum-Iridium Complexes Connected by a Tantallacyclopentadiene Fragment2016
- Author(s)
  Keishi Yamamoto, Kosuke Higashida, Haruki Nagae, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Helv. Chim. Acta 2016, 99 (11), 848-858.
  
  Volume: 99 Issue: 11 Pages: 848-858
- DOI
  10.1002/hlca.201600180
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PUBLICLY-15H00743, KAKENHI-PLANNED-15H05808
[Journal Article] Direct Evidence for [4+2] Cycloaddition Mechanism of Alkynes to Tantallacyclopentadiene on Dinuclear Tantalum Complexes as a Model of Alkyne Cyclotrimerization2015
- Author(s)
  Keishi Yamamoto, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Chem. Eur. J.
  
  Volume: 21 Issue: 32 Pages: 11369-11377
- DOI
  10.1002/chem.201501164
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PUBLICLY-15H00743, KAKENHI-PLANNED-15H05808, KAKENHI-PROJECT-14J03566
[Journal Article] Mixed-ligand Complexes of Paddlewheel Dinuclear Molybdenum as Hydrodehalogenation catalysts for Polyhaloalkanes2015
- Author(s)
  Hayato Tsurugi, Akio Hayakawa, Shun Kando, Yoshitaka Sugino, Kazushi Mashima
- Journal Title
  
  Chem. Sci.
  
  Volume: 6 Issue: 6 Pages: 3434-3439
- DOI
  10.1039/c5sc00721f
- Peer Reviewed / Open Access
- Data Source
  KAKENHI-PLANNED-22105010, KAKENHI-PUBLICLY-25102526, KAKENHI-PUBLICLY-15H00743, KAKENHI-PLANNED-15H05808
[Journal Article] Synthesis of Alkyl and Alkylidene Complexes of Tungsten Bearing Imido and Redox-Active α-Diimine or o-Iminoquinone Ligands and Their Application as Catalysts for Ring-Opening Metathesis Polymerization of Norbornene2015
- Author(s)
  Hiromasa Tanahashi, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Organometallics
  
  Volume: 34 Issue: 4 Pages: 731-741
- DOI
  10.1021/om501010n
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-13J00904, KAKENHI-PROJECT-26248028, KAKENHI-PROJECT-26708012
[Journal Article] Salt-free Reduction of Base Transition Metal Compounds: Generation of Amorphous Ni Nanoparticles for Catalytic C―C Bond Formation2015
- Author(s)
  Taiga Yurino, Yohei Ueda, Yoshiki Shimizu, Shinji Tanaka, Haruka Nishiyama, Hayato Tsurugi, Kazuhiko Sato, and Kazushi Mashima
- Journal Title
  
  Angew. Chem. Int. Ed.
  
  Volume: 54 Issue: 48 Pages: 14437-14441
- DOI
  10.1002/ange.201507902
- Peer Reviewed
- Data Source
  KAKENHI-PLANNED-15H05808, KAKENHI-PROJECT-26708012
[Journal Article] Reduction of (tBuN=)NbCl3(py)2 in a Salt-Free Manner for Generating Nb(IV) Dinuclear Complexes and Their Reactivity toward Benzo[c]cinnoline2015
- Author(s)
  Teruhiko Saito, Haruka Nishiyama, Kento Kawakita, Michael Nechayev, Benjamin Kriegel, Hayato Tsurugi, John Arnold, Kazushi Mashima.
- Journal Title
  
  Inorganic Chemistry
  
  Volume: 54 Issue: 12 Pages: 6004-6009
- DOI
  10.1021/acs.inorgchem.5b00812
- Peer Reviewed / Acknowledgement Compliant / Open Access / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-14J02837, KAKENHI-PROJECT-26248028, KAKENHI-PROJECT-26708012
[Journal Article] Cerium(IV) Hexanuclear Clusters from Cerium(III) Precursors: Molecular Models for Oxidative Growth of Ceria Nanoparticles2015
- Author(s)
  Laurent Mathey, Mitali Paul, Christophe Copéret, Hayato Tsurugi, Kazushi Mashima
- Journal Title
  
  Chem. Eur. J.
  
  Volume: 21 Issue: 38 Pages: 13454-13461
- DOI
  10.1002/chem.201501731
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PUBLICLY-15H00743, KAKENHI-PLANNED-15H05808
[Presentation] N-Methylation of Amines via CO2 Fixation Catalyzed by Lanthanum Hydridotriarylborate Complexes Supported by a N,N”-Diarylethylenetriamine Ligand2022
- Author(s)
  Koichi SHINOHARA, Hayato TSURUGI, Kazushi MASHIMA
- Organizer
  日本化学会第102春季年会
- Data Source
  KAKENHI-PUBLICLY-19H05057
[Presentation] Substituent Effects on the Redox Property of Oxo-bridged Hexanuclear Cerium Complexes with Ortho- and Para-substituted Benzoate Ligands2022
- Author(s)
  Tomomi Kawakami, Sota Tamaki, Hayato Tsurugi, Kazushi Mashima
- Organizer
  日本化学会第102春季年会
- Data Source
  KAKENHI-PROJECT-20H02742
[Presentation] Synthesis, Redox Property, and Photo-responsivity of Oxo-bridged Hexanuclear Cerium Clusters2021
- Author(s)
  Tomomi Kawakami, Sota Tamaki, Hayato Tsurugi, Kazushi Mashima
- Organizer
  錯体化学会第71回討論会
- Data Source
  KAKENHI-PROJECT-20H02742
[Presentation] Redox Characterization of Oxo-bridged Hexanuclear Cerium Clusters2021
- Author(s)
  Tomomi Kawakami, Sota Tamaki, Hayato Tsurugi, Kazushi Mashima
- Organizer
  日本化学会第101春季年会
- Data Source
  KAKENHI-PUBLICLY-19H04578
[Presentation] CO2 Fixation into Amine via Hydrosilylation of CO2 Catalyzed by Lanthanum Hydridotriarylborate Complexes with an N,N’’-Bis(pentafluorophenyl)diethylenetriamine Ligand2021
- Author(s)
  Koichi Shinohara, Hayato Tsurugi, and Kazushi Mashima
- Organizer
  第67回有機金属化学討論会
- Data Source
  KAKENHI-PUBLICLY-19H05057
[Presentation] Redox Characterization of Oxo-bridged Hexanuclear Cerium Clusters2021
- Author(s)
  Tomomi Kawakami, Sota Tamaki, Hayato Tsurugi, Kazushi Mashima
- Organizer
  日本化学会第101春季年会
- Data Source
  KAKENHI-PROJECT-20H02742
[Presentation] (E)-Selective Cross-dimerization of Terminal Alkynes Catalyzed by a Cobalt Complex with a Sterically Demanding Phenanthroline Ligand2020
- Author(s)
  Yohei Ueda, Hayato Tsurugi, Kazushi Mashima
- Organizer
  日本化学会第100春季年会
- Data Source
  KAKENHI-PUBLICLY-19H05057
[Presentation] Mechanistic Study on Vanadium-catalyzed [2+2+1]-cycloaddition of Alkynes and Azobenzenes2019
- Author(s)
  KAWAKITA, Kento; KAKIUCHI, Yuya; BEAUMIER, Evan; TONKS, Ian; TSURUGI, Hayato; MASHIMA, Kazushi
- Organizer
  日本化学会第99春季年会
- Data Source
  KAKENHI-PROJECT-15KK0186
[Presentation] Cerium(III) Complex with a N,N”-Bis(pentafluorophenyl)diethylenetriamine as a Catalyst for Hydrosilylation of Ketones2019
- Author(s)
  Koichi SHINOHARA, Hayato TSURUGI, Kazushi MASHIMA
- Organizer
  錯体化学会第69回討論会
- Data Source
  KAKENHI-PUBLICLY-19H05057
[Presentation] Synthesis and Characterization of Dinuclear Bezylhafnium Complexes derived from Benzylation of (2-Hydroxyethyl)imine by Tetrabenzylhafnium2019
- Author(s)
  Mariko Inoue, Michael J. Lopez, Hayato Tsurugi, Kazushi Mashima
- Organizer
  錯体化学会第69回討論会
- Data Source
  KAKENHI-PROJECT-15KT0064
[Presentation] Catalytic Aerobic Oxidation of Alcohols to Carbonyl Compounds with in-situ Generated Oxo-bridged Dinuclear Cerium Complex2018
- Author(s)
  Satoru Shirase, Koichi Shinohara, Hayato Tsurugi, Kazushi Mashima
- Organizer
  The 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC14)
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KT0064
[Presentation] Ortho-C-H Bond Aminoalkylation of Pyridine Derivatives Catalyzed by Yttrium Complexes with N,N’-Diarylethylenediamido Ligands2018
- Author(s)
  Hayato Tsurugi, Mariko Inoue, Abhinanda Kundu, Haruki Nagae, Kazushi Mashima
- Organizer
  The 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC14)
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KT0064
[Presentation] Catalytic C(sp3)-H Bond Alkenylation of α-Methylpyridine Derivatives2018
- Author(s)
  Hayato Tsurugi, Mariko Inoue, Michael J. Lopez, Haruki Nagae, Kazushi Mashima
- Organizer
  The 4th International Symposium on C-H Activation (ISCHA4)
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KT0064
[Presentation] Catalytic Oxidation of Alcohols to Aldehydes by Cerium Complexes with Pentadentate Schiff-base Ligands under O2 atmosphere2018
- Author(s)
  Satoru Shirase, Koichi Shinohara, Yuri Ikeda, Hayato Tsurugi, Kazushi Mashima
- Organizer
  XXVIII International Conference on Organometallic Chemistry (ICOMC2018)
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KT0064
[Presentation] Preparation and Characterization of Highly Active Olefin Metathesis Catalyst Using Well-defined Tungsten Oxo Surface Species with Organosilicon Reductants2017
- Author(s)
  Haruki Nagae, Victor Mougel, Ka-Wing Chan, Georges Siddiqi, Kento Kawakita, Hayato Tsurugi, Olga Safonova, Christophe Coperet, Kazushi Mashima
- Organizer
  日本化学会第97春季年会
- Place of Presentation
  慶応義塾大学、神奈川県横浜市
- Year and Date
  2017-03-16
- Data Source
  KAKENHI-PROJECT-26708012
[Presentation] Synthesis and Reactivity of Dinuclear Organometallic Element Block2017
- Author(s)
  Hayato Tsurugi, Keishi Yamamoto, Kazushi Mashima
- Organizer
  The 2nd International Symposium on Polymeric Materials Based on Element Blocks
- Place of Presentation
  京都工芸繊維大学、京都府京都市
- Year and Date
  2017-01-18
- Int'l Joint Research
- Data Source
  KAKENHI-PUBLICLY-15H00743
[Presentation] Low-valent Titanocene-catalyzed Salt-free Reformatsky Reaction2017
- Author(s)
  Hiromu Hosoya, Haruka Nishiyama, Kento Kawakita, Hayato Tsurugi, Kazushi Mashima
- Organizer
  The 19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS19)
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-26708012
[Presentation] Azo N=N Bond Cleavage Mediated by Low-valent Group 5 Metal Species2017
- Author(s)
  Kento Kawakita, Hayato Tsurugi, Kazushi Mashima
- Organizer
  The 19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS19)
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-26708012
[Presentation] Mixed-ligated Paddlewheel Mo2 Complexes as Catalysts for Radical Addition Reaction2016
- Author(s)
  Rej Supriya, Hayato Tsurugi, Kazushi Mashima
- Organizer
  27th International Conference on Organometallic Chemistry (ICOMC2016)
- Place of Presentation
  Melbourne, Australia
- Year and Date
  2016-07-17
- Int'l Joint Research
- Data Source
  KAKENHI-PUBLICLY-15H00743
[Presentation] Catalytic C(sp3)-H Hydroalkylation of Internal Alkynes using 2,6-Dimethyl-N-heterocycles Catalyzed by a Cationic Alkylhafnium Complex2016
- Author(s)
  Michael J. Lopez, Ai Kondo, Koji Yamamoto, Hayato Tsurugi, Kazushi Mashima
- Organizer
  Third International Symposium on C-H Activation
- Place of Presentation
  Montreal, Canada
- Year and Date
  2016-05-30
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KT0064
[Presentation] Radical addition and hydrodehalogenation reactions catalyzed by niobium and tantalum complexes bearing α-diimine ligand2016
- Author(s)
  Haruka Nishiyama, Teruhiko Saito, Hayato Tsurugi, Kazushi Mashima
- Organizer
  28th International Conference on Organometallic Chemistry (ICOMC2016)
- Place of Presentation
  Melbourne, Australia
- Year and Date
  2016-07-17
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-26708012
[Presentation] Application of 1-methyl-3,6-bis(trimethylsilyl)-cyclohexa-2,5-diene for reducing tungsten(VI) imido chloride: simple procedure for synthesizing ring-opening polymerization catalysts with 1,4-diaza-1,3-butadiene ligands2016
- Author(s)
  Hideaki Ikeda, Hiromasa Tanahashi, Hayato Tsurugi, Kazushi Mashima
- Organizer
  20th International Symposium on Homogeneous Catalysis (ISHC XX)
- Place of Presentation
  京都テルサ、京都府京都市
- Year and Date
  2016-07-10
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-26708012
[Presentation] Ortho-C-H Bond Vinylation of Arylimido Ligands Bridging Two Titanium Centers2016
- Author(s)
  Hayato Tsurugi, Haruki Nagae, Kazushi Mashima
- Organizer
  Third International Symposium on C-H Activation
- Place of Presentation
  Montreal, Canada
- Year and Date
  2016-05-30
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15KT0064
[Presentation] Organosilicon Reagents as Reductants of Early Transition Metal Complexes in a Salt-free Manner for Generating Catalytically Active Species2016
- Author(s)
  Kento Kawakita, Teruhiko Saito, Haruka Nishiyama, Hayato Tsurugi, Kazushi Mashima
- Organizer
  20th International Symposium on Homogeneous Catalysis (ISHC XX)
- Place of Presentation
  京都テルサ、京都府京都市
- Year and Date
  2016-07-10
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-26708012
[Presentation] Salt-free reduction of transition metal complexes for generating catalytically active low-valent species2016
- Author(s)
  Hayato Tsurugi
- Organizer
  The 96th CSJ Annual Meeting, Asian International Symposium-Coordination Chemistry, Organometallic Chemistry
- Place of Presentation
  同志社大学（京都府、京田辺市）
- Year and Date
  2016-03-24
- Invited
- Data Source
  KAKENHI-PROJECT-26708012
[Presentation] Paddlewheel Mo2-catalyzed hydrodehalogenation reaction of polyhaloalkanes2015
- Author(s)
  Hayato Tsurugi, Shun Kando, Rej Supriya, Akio Hayakawa, Yoshitaka Sugino, and Kazushi Mashima
- Organizer
  The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem2015)
- Place of Presentation
  Honolulu, Hawaii
- Year and Date
  2015-12-14
- Int'l Joint Research
- Data Source
  KAKENHI-PUBLICLY-15H00743
[Presentation] Evidence for [4+2] cycloaddition mechanism of alkynes to tantallacyclopentadiene as a model of alkyne cyclotrimerization2015
- Author(s)
  Keishi Yamamoto, Hayato Tsurugi, and Kazushi Mashima
- Organizer
  17th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC 17)
- Place of Presentation
  Utrecht, the Netherlands
- Year and Date
  2015-07-12
- Int'l Joint Research
- Data Source
  KAKENHI-PUBLICLY-15H00743
[Presentation] Salt-free Reduction of Tantalum and Tungsten Halides for Generating Low-valent Catalytically Active Species2014
- Author(s)
  Hayato Tsurugi
- Organizer
  41st International Conference on Coordination Chemistry
- Place of Presentation
  Suntec Singapore Convention & Ehxibition Centre, Singapore
- Year and Date
  2014-07-20
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-26708012
[Presentation] Hydrodehalogenation Reaction of Haloalkanes Catalyzed by Mixed-ligated Paddlewheel Dimolybdenum Complexes2014
- Author(s)
  Tsurugi, H.; Kando, S.; Hayakawa, A.; Sugino, Y.; Mashima, K.
- Organizer
  The 1st International Symposium on Interactive Materials Science Cadet Program
- Place of Presentation
  ホテル阪急エキスポパーク
- Year and Date
  2014-11-17
- Invited
- Data Source
  KAKENHI-PUBLICLY-25102526

1. SHIMA Takanori

# of Collaborated Projects: 0 results

# of Collaborated Products: 1 results
2. 真島和志

# of Collaborated Projects: 0 results

# of Collaborated Products: 7 results

Tsurugi Hayato 劔 隼人

TSURUGI Hayato 劔 隼人

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Co-Researchers

Development of Radical Transformations by Photo-active Metal Cluster CatalystsPrincipal Investigator

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Development of Transition Metal Catalysts for Synthesizing Polysubstituted Heteroles Using Degitalized Intermediate ParametersPrincipal Investigator

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Controlled Radical Generation from Carboxylic Acids with Readily Oxidizable Functional Groups by Metal Cluster PhotocatalystsPrincipal Investigator

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Development of asymmetric early transition metal catalysts for synthesizing chiral aminoalkenesPrincipal Investigator

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Development of cerium-containing MOFs as photo-catalysts for transformation of light alkanesPrincipal Investigator

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Development of O2-oxidation catalyzed by homo and heteronuclear multimetallic cerium complexesPrincipal Investigator

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Precise Design of Asymmetric Coordination Sphere by Complexation of Mononuclear and Cluster Complexes for Developing Novel Catalytic TransformationPrincipal Investigator

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Development of Novel Metal Hydride Catalysts Composed of Transition Metal Hydrides and Perovskite OxidesPrincipal Investigator

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Development of flexibly designable organic reducing agents and their application(Fostering Joint International Research)Principal Investigator

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同種・異種金属元素ブロックの機能開発と高分子化による高性能触媒材料の創出Principal Investigator

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Development of metal cluster catalysts by controlling the transition state for C-H bond activation on metal clustersPrincipal Investigator

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Development of Structurally Tunable Organic-based ReductantsPrincipal Investigator

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金属間多重結合含有クラスターを元素ブロックとしたレドックス活性高分子材料の創出Principal Investigator

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Tsurugi Hayato 劔隼人

TSURUGI Hayato 劔隼人