Shigehisa Hiroki 重久浩樹

… Alternative Names

SHIGEHISA Hiroki 重久浩樹

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Researcher Number	60612471
Other IDs
Affiliation (Current)	2025: 武蔵野大学, 薬学部, 講師
Affiliation (based on the past Project Information) *help	2020 – 2024: 武蔵野大学, 薬学部, 講師 2018: 武蔵野大学, 薬学部, 講師 2017: 武蔵野大学, 薬学研究所, 講師 2012 – 2015: 武蔵野大学, 薬学研究所, 助教
Review Section/Research Field	Principal Investigator Chemical pharmacy / Medium-sized Section 33:Organic chemistry and related fields / Basic Section 33020:Synthetic organic chemistry-related / Basic Section 47010:Pharmaceutical chemistry and drug development sciences-related Except Principal Investigator Chemical pharmacy
Keywords	Principal Investigator 有機化学 / 有機合成化学 / 創薬化学 / 有機金属化学 / 複素環化学 / 不斉合成 / 触媒的不斉合成 / 不斉反応 / コバルト触媒反応 / コバルト / オレフィン / 複素環 … More Except Principal Investigator … More 動的化学分割反応 / 動的光学分割反応 / アルカロイド / 不斉全合成 / パラジウム錯体 / 不斉配位子 / 動的光学分割 Less

MHAT／RPC化学の新展開Principal Investigator
- Principal Investigator
  
  重久浩樹
- Project Period (FY)
  2023 – 2027
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Review Section
  
  Basic Section 33020:Synthetic organic chemistry-related
- Research Institution
  Musashino University
新規脱離基活性化法によるキラル第３級アルコールの立体反転戦略Principal Investigator
- Principal Investigator
  
  重久浩樹
- Project Period (FY)
  2023 – 2025
- Research Category
  
  Grant-in-Aid for Challenging Research (Exploratory)
- Review Section
  
  Medium-sized Section 33:Organic chemistry and related fields
- Research Institution
  Musashino University
Development of highly reactive and stereoselective catalytic reaction toward formation and introduction of 4 membered ringPrincipal Investigator
- Principal Investigator
  
  Shigehisa Hiroki
- Project Period (FY)
  2020 – 2023
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Review Section
  
  Basic Section 47010:Pharmaceutical chemistry and drug development sciences-related
- Research Institution
  Musashino University
Studies on enantioselective hydrofunctionalization of olefins using cobalt hydridePrincipal Investigator
- Principal Investigator
  
  Shigehisa Hiroki
- Project Period (FY)
  2017 – 2018
- Research Category
  
  Grant-in-Aid for Young Scientists (B)
- Research Field
  
  Chemical pharmacy
- Research Institution
  Musashino University
Catalytic enantioselective synthesis of chiral heterocycles using oxidative nucleophilc addition to carbon radicalPrincipal Investigator
- Principal Investigator
  
  SHIGEHISA hiroki
- Project Period (FY)
  2014 – 2015
- Research Category
  
  Grant-in-Aid for Young Scientists (B)
- Research Field
  
  Chemical pharmacy
- Research Institution
  Musashino University
Development and Application of Dynamic Kinetic Resolution Reaction via chiral pi-allylpalladium complex
- Principal Investigator
  
  HIROYA Kou
- Project Period (FY)
  2012 – 2014
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Chemical pharmacy
- Research Institution
  Musashino University

All 2024 2023 2021 2018 2016 2015 2014 2013 2012 Other

All Journal Article Presentation

[Journal Article] Investigating cyclization selectivity by ligand tuning based on MHAT/RPC mechanism2024
- Author(s)
  Sugimura Takuma、Shigehisa Hiroki
- Journal Title
  
  Tetrahedron Letters
  
  Volume: 135 Pages: 154902-154902
- DOI
  10.1016/j.tetlet.2023.154902
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-23K26661
[Journal Article] Synthesis of five-, six-, and seven-membered cyclic isoureas via MHAT/RPC promoted cycloisomerization2024
- Author(s)
  Mimata Nao、Shigehisa Hiroki
- Journal Title
  
  Tetrahedron Letters
  
  Volume: 135 Pages: 154890-154890
- DOI
  10.1016/j.tetlet.2023.154890
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-23K26661
[Journal Article] Constructing Four-Membered Heterocycles by Cycloisomerization2023
- Author(s)
  Ayami Osato, Takashi Fujihara, and Hiroki Shigehisa
- Journal Title
  
  ACS Catalysis
  
  Volume: 13 Issue: 7 Pages: 4101-4110
- DOI
  10.1021/acscatal.2c06404
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20K06976
[Journal Article] Studies on Catalytic Activation of Olefins Using Cobalt Complex2018
- Author(s)
  Hiroki Shigehisa
- Journal Title
  
  Chemical and Pharmaceutical Bulletin
  
  Volume: 66 Issue: 4 Pages: 339-346
- DOI
  10.1248/cpb.c17-01006
- NAID
  130006602036
- ISSN
  0009-2363, 1347-5223
- Language
  English
- Peer Reviewed / Open Access
- Data Source
  KAKENHI-PROJECT-17K15426
[Journal Article] Markovnikov-Selective Addition of Fluorous Solvents to Unactivated Olefins Using a Co Catalyst2016
- Author(s)
  Hiroki Shigehisa, Harue Kikuchi, Kou Hiroya
- Journal Title
  
  Chemical and Pharmaceutical Bulletin
  
  Volume: 64 Issue: 4 Pages: 371-374
- DOI
  10.1248/cpb.c15-01024
- NAID
  130005141025
- ISSN
  0009-2363, 1347-5223
- Language
  English
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15K07872, KAKENHI-PROJECT-26860017
[Journal Article] The Revised Structure of Trichodermatide A2015
- Author(s)
  Hiroki Shigehisa, Harue Kikuchi, Tsuyoshi Suzuki, Kou Hiroya
- Journal Title
  
  European Journal of Organic Chemistry
  
  Volume: No.35 Issue: 35 Pages: 7670-7673
- DOI
  10.1002/ejoc.201501281
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15K07872, KAKENHI-PROJECT-26860017
[Journal Article] Functional Group Tolerant Markovnikov-Selective Hydrofunctionalization of Unactivated Olefins Using a Cobalt Complex as Catalyst2015
- Author(s)
  Hiroki Shigehisa
- Journal Title
  
  Synlett
  
  Volume: 26 Issue: 18 Pages: 2479-2484
- DOI
  10.1055/s-0035-1560171
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-26860017
[Journal Article] Markovnikov-selective Addition Reaction to Olefins Using Cobalt Complex2015
- Author(s)
  重久浩樹、廣谷功
- Journal Title
  
  Journal of Synthetic Organic Chemistry, Japan
  
  Volume: 73 Issue: 8 Pages: 788-797
- DOI
  10.5059/yukigoseikyokaishi.73.788
- NAID
  130005098862
- ISSN
  0037-9980, 1883-6526
- Language
  Japanese
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-26860017
[Journal Article] Catalytic Hydroamination of Unactivated Olefins Using a Co Catalyst for Complex Molecule Synthesis2014
- Author(s)
  Hiroki Shigehisa, Natsumi Koseki, Nao Shimizu, Mayu Fujisawa, Makoto Niitsu, Kou Hiroya
- Journal Title
  
  Journal of the American Chemical Society
  
  Volume: 136 Issue: 39 Pages: 13534-13537
- DOI
  10.1021/ja507295u
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24590029, KAKENHI-PROJECT-26860017
[Journal Article] Cobalt-Catalyzed Hydrofluorination of Unactivated Olefins: A Radical Approach of Fluorine Transfer.2013
- Author(s)
  Hiroki Shigehisa, Eriko Nishi, Mayu Fujisawa, Kou Hiroya
- Journal Title
  
  Organic Letters
  
  Volume: 15 Issue: 20 Pages: 5158-5161
- DOI
  10.1021/ol402696h
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24590029
[Journal Article] Stereocontrolled Synthesis of Trichodermatide A2013
- Author(s)
  Hiroki Shigehisa, Yoshihiro Suwa, Naho Furiya, Yuki Nakaya, Minoru Fukushima, Yusuke Ichihashi, Kou Hiroya
- Journal Title
  
  Angewandte Chemie International Edition
  
  Volume: 52 Issue: 13 Pages: 3646-3649
- DOI
  10.1002/anie.201210099
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24590029
[Journal Article] Hydroalkoxylation of Unactivated Olefins with Carbon Radicals and Carbocation Species as Key Intermediates.2013
- Author(s)
  Hiroki Shigehisa, Tatsuya Aoki, Sumiko Yamaguchi, Nao Shimizu, Kou Hiroya
- Journal Title
  
  Journal of the American Chemical Society
  
  Volume: 135 Issue: 28 Pages: 10306-10309
- DOI
  10.1021/ja405219f
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] アルキニルチオエステルのハロ環化反応／酸化的芳香化反応によるチオフェン合成2024
- Author(s)
  栗原実愛理、井手愛梨、重久浩樹
- Organizer
  日本薬学会第144年会
- Data Source
  KAKENHI-PROJECT-23K26661
[Presentation] MHAT/RPC機構による環状アセタール合成2024
- Author(s)
  杉村拓磨、Szarlan Bartlomiej、重久浩樹
- Organizer
  日本薬学会第144年会
- Data Source
  KAKENHI-PROJECT-23K26661
[Presentation] MHAT/RPC promoted [n + 2] annulation: Access to cyclic acetal2023
- Author(s)
  Takuma Sugimura, Hiroki Shigehisa
- Organizer
  IKCOC-15
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-23K26661
[Presentation] 環化異性化反応による４員環複素環の構築法2023
- Author(s)
  大里彩水、藤原隆司、重久浩樹
- Organizer
  日本化学会第103春季年会
- Data Source
  KAKENHI-PROJECT-20K06976
[Presentation] アルケニルチオエステルのハロ環化反応2023
- Author(s)
  三枝鈴南子、重久浩樹
- Organizer
  日本薬学会第143年会
- Data Source
  KAKENHI-PROJECT-20K06976
[Presentation] アルケニルチオエステルのブロモ環化反応2023
- Author(s)
  重久浩樹、三枝鈴南子、藤原隆司
- Organizer
  第52回複素環化学討論会
- Data Source
  KAKENHI-PROJECT-23K26661
[Presentation] MHAT/RPCを基盤にした複素環合成2021
- Author(s)
  重久浩樹
- Organizer
  第65回日本薬学会関東支部大会
- Invited
- Data Source
  KAKENHI-PROJECT-20K06976
[Presentation] コバルト錯体を用いた不活性オレフィンの分子内ヒドロアルコキシル化・ヒドロアシルオキシ化反応2016
- Author(s)
  林美希、大川陽菜、重久浩樹、廣谷功
- Organizer
  日本薬学会第136年会
- Place of Presentation
  パシフィコ横浜（神奈川）
- Year and Date
  2016-03-26
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] コバルト錯体を用いた不活性オレフィンの分子内ヒドロアリール化反応2016
- Author(s)
  阿野卓哉、本間皓、重久浩樹、廣谷功
- Organizer
  日本薬学会第136年会
- Place of Presentation
  パシフィコ横浜（神奈川）
- Year and Date
  2016-03-26
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] 海洋性ポリケチドTrichodermatide Aの構造改訂2016
- Author(s)
  菊池陽媛、鈴木毅史、重久浩樹、廣谷功
- Organizer
  日本薬学会第136年会
- Place of Presentation
  パシフィコ横浜（神奈川）
- Year and Date
  2016-03-26
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] 海洋性天然物Trichodermatide Aの構造改訂2015
- Author(s)
  菊池陽媛、鈴木毅史、重久浩樹、廣谷功
- Organizer
  第59会日本薬学会関東支部大会
- Place of Presentation
  日本大学薬学部（千葉）
- Year and Date
  2015-09-12
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] コバルト触媒を用いたオレフィンの分子内ヒドロアルコキシル化反応とヒドロアシルオキシ化反応2015
- Author(s)
  林美希、大川陽菜、重久浩樹、廣谷功
- Organizer
  第59会日本薬学会関東支部大会
- Place of Presentation
  日本大学薬学部（千葉）
- Year and Date
  2015-09-12
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] コバルト触媒によるオレフィンの選択的付加反応の開発と天然物合成2015
- Author(s)
  重久浩樹
- Organizer
  第8回化学系若手研究者講演会
- Place of Presentation
  千葉大学薬学部（千葉）
- Year and Date
  2015-09-18
- Invited
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] コバルト触媒を用いたオレフィンのヒドロアリール化反応2015
- Author(s)
  阿野卓哉、本間皓、重久浩樹、廣谷功
- Organizer
  第59会日本薬学会関東支部大会
- Place of Presentation
  日本大学薬学部（千葉）
- Year and Date
  2015-09-12
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] コバルト触媒を利用したオレフィンの分子内ヒドロアミノ化反応2014
- Author(s)
  清水　奈緒，小関　菜摘，藤澤　真優，新津　真琴，重久　浩樹，廣谷　功
- Organizer
  第58回日本薬学会関東支部大会
- Place of Presentation
  昭和薬科大学（東京都町田市）
- Year and Date
  2014-10-04
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] コバルト触媒を利用したオレフィンの分子内ヒドロアミノ化反応2014
- Author(s)
  清水奈緒、小関菜摘、藤澤真優、新津真琴、重久浩樹、廣谷功
- Organizer
  第58回日本薬学会関東支部大会
- Place of Presentation
  昭和薬科大学（東京）
- Year and Date
  2014-10-04
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] コバルト触媒を用いたオレフィンのヒドロフッ素化反応2014
- Author(s)
  西　恵理子，藤澤　真優，重久　浩樹，廣谷　功
- Organizer
  第58回日本薬学会関東支部大会
- Place of Presentation
  昭和薬科大学（東京都町田市）
- Year and Date
  2014-10-04
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] コバルト触媒を用いたオレフィンのヒドロフッ素化反応2014
- Author(s)
  西恵理子、藤澤真優、重久浩樹、廣谷功
- Organizer
  第58回日本薬学会関東支部大会
- Place of Presentation
  昭和薬科大学（東京）
- Year and Date
  2014-10-04
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] ラジカルとカチオンを経由する不活性オレフィンの触媒的ヒドロアルコキシル化反応2013
- Author(s)
  青木　竜也，山口　寿美子，清水　奈緒，重久　浩樹，廣谷　功
- Organizer
  第57回日本薬学会関東支部大会
- Place of Presentation
  帝京大学板橋キャンパス（東京都）
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] コバルト錯体と求電子的フッ素化剤を用いた官能基許容性の高いオレフィンへの付加反応2013
- Author(s)
  重久　浩樹，青木　竜也，山口　寿美子，清水　奈緒，西　恵理子，藤澤　真優，廣谷　功
- Organizer
  第60回有機金属化学討論会
- Place of Presentation
  学習院創立百周年記念会館正堂（東京都）
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] 閉環－官能基化反応による3位ヘテロ原子置換インドール類の合成2012
- Author(s)
  廣谷　功，伊藤　晋，荻原　謙太郎，鵜木　萌，重久　浩樹
- Organizer
  第42回複素環化学討論会
- Place of Presentation
  京都テルサ（京都市）
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] 不斉ジヒドロキシル化―非対称化連続反応を利用するベンジル位不斉第四級炭素構築法の開発2012
- Author(s)
  廣谷　功，高橋　絵里菜，市橋　佑介，重久　浩樹，土井　隆行
- Organizer
  第51回日本薬学会東北支部大会
- Place of Presentation
  青森大学薬学部（青森市）
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] 触媒的不斉導入によるベンジル位不斉第四級炭素構築法の開発研究2012
- Author(s)
  廣谷　功，高橋　絵里菜，市橋　佑介，重久　浩樹，土井　隆行
- Organizer
  第42回複素環化学討論会
- Place of Presentation
  京都テルサ（京都市）
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] (–)-Trichodermatide A の全合成2012
- Author(s)
  重久　浩樹，諏訪好泰，降矢奈穂，中谷有岐，福島稔，市橋佑介，廣谷功
- Organizer
  第42回複素環化学討論会
- Place of Presentation
  京都テルサ（京都市）
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] Co錯体/F+試薬/SiH試薬を用いたオレフィンの触媒的分子内ヒドロアミノ化反応
- Author(s)
  重久　浩樹，小関　菜摘，清水　奈緒，藤澤　真優，新津　真琴，廣谷　功
- Organizer
  第44回複素環化学討論会
- Place of Presentation
  札幌市民ホール（札幌市）
- Year and Date
  2014-09-10 – 2014-09-12
- Data Source
  KAKENHI-PROJECT-24590029
[Presentation] Co 錯体/F+ 試薬/SiH 試薬を用いたオレフィンの触媒的分子内ヒドロアミノ化反応
- Author(s)
  重久浩樹、小関菜摘、清水奈緒、藤澤真優、新津真琴、廣谷功
- Organizer
  第44回複素環化学討論会
- Place of Presentation
  札幌市民ホール（北海道）
- Year and Date
  2014-09-10 – 2014-09-12
- Data Source
  KAKENHI-PROJECT-26860017
[Presentation] コバルト触媒を利用したオレフィンの分子内ヒドロアミノ化反応
- Author(s)
  重久浩樹、清水奈緒、小関菜摘、藤澤真優、新津真琴、廣谷功
- Organizer
  日本薬学会第135年会
- Place of Presentation
  デザインクリエ―ティブセンター神戸（兵庫）
- Year and Date
  2015-03-25 – 2015-03-28
- Data Source
  KAKENHI-PROJECT-26860017

1. HIROYA Kou (70192721)

# of Collaborated Projects: 1 results

# of Collaborated Products: 14 results
2. 美多剛 (00548183)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
3. 藤原隆司 (70280914)

# of Collaborated Projects: 1 results

# of Collaborated Products: 1 results

Shigehisa Hiroki 重久 浩樹

SHIGEHISA Hiroki 重久 浩樹

Research Projects

Research Products

Co-Researchers

MHAT／RPC化学の新展開Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

新規脱離基活性化法によるキラル第３級アルコールの立体反転戦略Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Development of highly reactive and stereoselective catalytic reaction toward formation and introduction of 4 membered ringPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Studies on enantioselective hydrofunctionalization of olefins using cobalt hydridePrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Catalytic enantioselective synthesis of chiral heterocycles using oxidative nucleophilc addition to carbon radicalPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Development and Application of Dynamic Kinetic Resolution Reaction via chiral pi-allylpalladium complex

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] Investigating cyclization selectivity by ligand tuning based on MHAT/RPC mechanism2024

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Synthesis of five-, six-, and seven-membered cyclic isoureas via MHAT/RPC promoted cycloisomerization2024

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Constructing Four-Membered Heterocycles by Cycloisomerization2023

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Studies on Catalytic Activation of Olefins Using Cobalt Complex2018

Author(s)

Journal Title

DOI

NAID

ISSN

Language

Data Source

[Journal Article] Markovnikov-Selective Addition of Fluorous Solvents to Unactivated Olefins Using a Co Catalyst2016

Author(s)

Journal Title

DOI

NAID

ISSN

Language

Data Source

[Journal Article] The Revised Structure of Trichodermatide A2015

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Functional Group Tolerant Markovnikov-Selective Hydrofunctionalization of Unactivated Olefins Using a Cobalt Complex as Catalyst2015

Author(s)

Journal Title

Shigehisa Hiroki 重久浩樹

SHIGEHISA Hiroki 重久浩樹