MATSUBARA Yoshio 松原凱男

Researcher Number	80088450
External Links
Affiliation (based on the past Project Information) *help	2006 – 2007: 近畿大学, 理工学部, 教授 2002 – 2003: 近畿大学, 理工学部, 教授 1994 – 2000: Faculty of Science and Engineering, Kinki University, Professor, 理工学部, 教授 1992 – 1993: 近畿大学, 理工学部, 助教授 1988 – 1989: 近畿大学, 理工学部, 助教授
Review Section/Research Field	Principal Investigator 有機工業化学 / 有機工業化学 / Functional materials chemistry Except Principal Investigator 有機工業化学
Keywords	Principal Investigator 新規合成反応 / ジアザナフタレン環生成反応 / TCNE / 反応中間体 / ヒドラゾン(donor) / ジアザナフタレン合成 / 58π→52π→48π / Catalytic synthesis / アリルカルバミン酸 / TCNE(acceptor) … More / Acymmetric oxidation / oxygen active species / NIH shift / Epoxydation / Hydroxylation of benzene / Heterogeneous oxidation / Oxigenase mode / Non-enzymatically oxidation / モノオキシゲナーゼモデル / 不斉酸化 / 酸素活性種 / NIHシフト / エポキシ化反応 / ベンゼンの水酸化反応 / 不均一系酸化反応 / モノオキシゲナ-ゼモデル / 非酵素的酸化反応 / Photophysical data / Core part in the center / Electron conjugated system / Cross type / Acceptor group / Donor group / Strong fluorophores / 発光特性 / 4置換ベンゼンのコア / フェニルエチニル基のアーム / クロス型電子共役系 / アクセプター基 / ドナー基 / 強発光機能 / Mono, tetra and hexa-adducts / 1,3-Dipole Addition / Pyrrolidine Ring-Fused C_<60> / Strongly Fluorescent Derivatives / Creation of Nano-Luminophores / 新規C_<60>強発光体(量子収率0.012) / 1,3一双極子付加反応 / モノ、テトラ、ヘキサ付加体 / 1,3-双極子付加反応 / ピロリジン環縮合C_<60> / C_<60>の強発光体化 / ナノ発光体の創製 / Producing 4,4'-methylenebis (N,N-dimetylaniline) / Novel reaction / Imine metathesis / Tetrahalomethane system / N,N-dimethylanilin / Phenylhydrazones-TCNE system / Charge transfer complex / ハロメタン / ジメチルアニリン / ヒドラゾン類 / σ-アクセプター / π-アクセプター / π-ドナー / 4,4'-メチレンビス(N,N-ジメチルアニリン) / 新規反応 / イミンメタセシス / テトラハロメタン系 / N,N-ジメチルアニリン / フェニルヒドラゾンTCNE系 / 電荷移動錯体 / Three components reaction system / Carbonyl compounds / Phenylhydrazines / New synthetic reaction / Ring formation reaction / Diazanaphthalenes / カルボニル類 / 3成分系反応 / カルボニル / フェニルヒドラジン / ジアザナフタレン類 / Nitrilimine / 1,3,4-oxadiazolin-2-ones / Ammonium Carbonate / Copper (I) Complexies / Allylcarbamates / Carbon Dioxide / Fixation and Transformation / 有機-水二相系 / 炭酸ジアリル / アリル変換反応 / 1,3,4-オキサゾリン-2-オン類 / ニトリルイミン / アリルカルバミン酸エステル類 / アリルカルバミン酸類 / アリル変換法 / アスコルビン酸銅(I)錯体 / 銅(I)錯体触媒 / 二酸化炭素の固定・変換法 / Asymmetric Hydroxylation Catalyst / Optical Active 1-Buten-3-ol / Heterogeneous catalytic reaction Polymer supported copper(I) / Enzymimic Function / Copper(I) Complexies / Allyl derivatives / pi-アリル銅ハライド / 水酸化反応 / アリルハライド / アスコルビン酸 / 二酸化炭素固定 / 不斉水酸化反応 / π-アリル銅ハライド / 不均一系触媒 / アリル誘導体合成 / 銅(I)錯体 / 酵素類似触媒反応 / donor-acceptor dyad コンセプト / TCNE (acceptor) / donor-accepter dyadコンセプト / donor-accepter dyad コンセプト … More Except Principal Investigator Bicapped C_<60> / 8π系新色素インドロン / Indolone as new 8pi system / Tokiirohiratake / Pyrazoline ring fused C_<60> dyes / Fixing nitrogen / gamma-cyclodextrin-C_<60> dyes / 4npi (60pi, 8pi) dyes system / Supper Functional Dyes / 酸素発生型光合成 / 光物性および電気化学的挙動 / Supperatom / トキイロヒラタケ / ピラゾリン環縮合C_<60>色素 / N_2固定 / γ-シクロデキストリン-C_<60>錯体色素 / 4nπ(60π及び8π)系色素 / 超機能色素 / Photosynthesis of protein / Indolone, new 8pi aromatic pigment / C_<60>-Ni complex / Pyrazoline-fullerene / Dodeca-penta-radialene / [5] -radialene / Methylene-bisazulene / Azulenequinone / アズレンキノン、 / タンパクの光合成 / C_<60>-Ni錯体 / ピラゾリンフラーレン / ドデカペンタラジアレン / [5]-ラジアレン / メチレンビスアズレン / アズレンキノン Less

Creation of the cross type electron conjugated system strong fluorophore arranged donor- and acceptor- groupsPrincipal Investigator
- Principal Investigator
  
  MATSUBARA Yoshio
- Project Period (FY)
  2006 – 2007
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Functional materials chemistry
- Research Institution
  Kinki University
Creation of Nano-Luminophores from Five-Membered Heterocyde with C_<60>Principal Investigator
- Principal Investigator
  
  MATSUBARA Yoshio
- Project Period (FY)
  2002 – 2003
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  有機工業化学
- Research Institution
  Kinki University
Development of New Reactions Using Charge Transfer Complex Based on New ConceptPrincipal Investigator
- Principal Investigator
  
  MATSUBARA Yoshio
- Project Period (FY)
  1999 – 2000
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  有機工業化学
- Research Institution
  Faculty of Science and Engineering, Kinki University
芳香族ヒドラゾンとTCNEを用いるジアザナフタレン類の革新的新合成反応Principal Investigator
- Principal Investigator
  
  松原凱男
- Project Period (FY)
  1998 – 1999
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas (A)
- Research Institution
  Kinki University
芳香族ヒドラゾンとTCNEを用いるジアザナフタレン類の革新的新合成反応Principal Investigator
- Principal Investigator
  
  松原凱男
- Project Period (FY)
  1997
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Kinki University
芳香族ヒドラゾンとTCNEを用いるジアザナフタレン類の革新的新合成反応Principal Investigator
- Principal Investigator
  
  松原凱男
- Project Period (FY)
  1997 – 1998
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas (A)
- Research Institution
  Kinki University
Development of Innovative Synthetic Method of Diazanaphthalene Rings from Hydrazine-Carbonyl Analogs and TCNEPrincipal Investigator
- Principal Investigator
  
  MATSUBARA Yoshio
- Project Period (FY)
  1997 – 1998
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  有機工業化学
- Research Institution
  Kinki University
CREATION OF SUPPER FUNCTIONAL DYES BASED ON NEW CONCEPTPrincipal Investigator
- Principal Investigator
  
  MATSUBARA Yoshio, 吉田善一
- Project Period (FY)
  1995 – 1996
- Research Category
  
  Grant-in-Aid for Scientific Research (A)
- Research Field
  
  有機工業化学
- Research Institution
  KINKI UNIVERSITY
Development on Fixation and Transformation of Carbon Dioxide by Use of New Copper (I) Complex Catalytic SystemPrincipal Investigator
- Principal Investigator
  
  MATSUBARA Yoshio
- Project Period (FY)
  1994 – 1995
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  有機工業化学
- Research Institution
  Faculty of Science and Engineering, Kinki University
SYNTHESIS AND FUNCTION OF CHEMICAL MODIFIED NEW AROMATIC SYSTEMS
- Principal Investigator
  
  YOSHIDA Zenichi
- Project Period (FY)
  1993 – 1994
- Research Category
  
  Grant-in-Aid for General Scientific Research (B)
- Research Field
  
  有機工業化学
- Research Institution
  KINKI UNIVERSITY
The Catalytic Synthesis of Allyl Derivatives Using Copper(I) Complexies Having Enzymimic FunctionPrincipal Investigator
- Principal Investigator
  
  MATSUBARA Yoshio
- Project Period (FY)
  1992 – 1993
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  有機工業化学
- Research Institution
  Faculty of Science and Engineering, Kinki University
Acymmetric oxidation using non-enzymatically oxidantPrincipal Investigator
- Principal Investigator
  
  MATSUBARA Yoshio
- Project Period (FY)
  1988 – 1989
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  有機工業化学
- Research Institution
  Kinki University

All 2007 2006

All Journal Article Presentation

[Journal Article] Solid-state optical properties of a chiral supramolecular fluorophore consisting of chiral(1R, 2R)-1, 2-diphenylethyleneiamine and fluorescent carboxylic acid derivatives2007
- Author(s)
  Y. Imai, K. Kawaguchi, T. Harada, T. Sato, M. Ishikawa, M. Fujiki, R. Kuroda, Y. Matsubara
- Journal Title
  
  Tetrahedron Lett. 48(16)
  
  Pages: 2927-2930
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18550133
[Journal Article] New Fluorophores with Rod-Shaped Polycyano π-Conjugated Structures : Synthesis and Photophysical Properties.2006
- Author(s)
  Y.Yamaguchi, T.Ochi, T.Wakamiya, Y.Matsubara, Z.Yoshida
- Journal Title
  
  Org.Lett. 8(4)
  
  Pages: 717-720
- Data Source
  KAKENHI-PROJECT-18550133
[Journal Article] New Fluorophores with Rod-Shaped Polycyano π-Conjugated Structures : Synthesis and Photophysical Properties.2006
- Author(s)
  Y. Yamaguchi, T. Ochi, T. Wakamiya, Y. Matsubara, Z. Yoshida
- Journal Title
  
  Org. Lett. 8(4)
  
  Pages: 717-720
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18550133
[Journal Article] Rigid Molecular Architectures That Comprise a 1, 3, 5-Trisubstituted Benzene Core and Three Oligoarylene-ethynylene Arms : Light-Emitting Characteristics and π Conjugation between the Arms.2006
- Author(s)
  Y. Yamaguchi, T. Ochi, S. Miyamura, T. Tanaka, S. Kobayashi, T. Wakamiya, Y. Matsubara, Z. Yoshida
- Journal Title
  
  J. Am. Chern,Soc 128(14)
  
  Pages: 4504-4505
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18550133
[Presentation] Donor and Acceptor-Substituted Oligo(phenylenethynylene)s Having The Acceptor Groups at The Molecular Center : Synthesis and Light-Emitting Characteristics2007
- Author(s)
  T. Ochi, Y. Yamaguchi, T. Wakamiya, Y. Matsubara, Z. Yoshida
- Organizer
  The 88th Spring Meeting of CSJ
- Year and Date
  2007-03-26
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-18550133

1. YOSHIDA Zenichi (60025814)

# of Collaborated Projects: 3 results

# of Collaborated Products: 0 results
2. TAKEKUMA Shinichi (00171629)

# of Collaborated Projects: 2 results

# of Collaborated Products: 0 results
3. MAEKAWA Masahiko (70229293)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
4. 中塚巌

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results

MATSUBARA Yoshio 松原 凱男

Research Projects

Research Products

Co-Researchers

Creation of the cross type electron conjugated system strong fluorophore arranged donor- and acceptor- groupsPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Creation of Nano-Luminophores from Five-Membered Heterocyde with C_<60>Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Development of New Reactions Using Charge Transfer Complex Based on New ConceptPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

芳香族ヒドラゾンとTCNEを用いるジアザナフタレン類の革新的新合成反応Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

芳香族ヒドラゾンとTCNEを用いるジアザナフタレン類の革新的新合成反応Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

芳香族ヒドラゾンとTCNEを用いるジアザナフタレン類の革新的新合成反応Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

Development of Innovative Synthetic Method of Diazanaphthalene Rings from Hydrazine-Carbonyl Analogs and TCNEPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

CREATION OF SUPPER FUNCTIONAL DYES BASED ON NEW CONCEPTPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Development on Fixation and Transformation of Carbon Dioxide by Use of New Copper (I) Complex Catalytic SystemPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

SYNTHESIS AND FUNCTION OF CHEMICAL MODIFIED NEW AROMATIC SYSTEMS

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

The Catalytic Synthesis of Allyl Derivatives Using Copper(I) Complexies Having Enzymimic FunctionPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Acymmetric oxidation using non-enzymatically oxidantPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] Solid-state optical properties of a chiral supramolecular fluorophore consisting of chiral(1R, 2R)-1, 2-diphenylethyleneiamine and fluorescent carboxylic acid derivatives2007

Author(s)

Journal Title

Description

Data Source

[Journal Article] New Fluorophores with Rod-Shaped Polycyano π-Conjugated Structures : Synthesis and Photophysical Properties.2006

Author(s)

MATSUBARA Yoshio 松原凱男