TAKAKI Ken 高木謙

… Alternative Names

Researcher Number	80116615
Other IDs
External Links
Affiliation (based on the past Project Information) *help	2012 – 2014: 広島大学, 工学(系)研究科(研究院), 教授 2009: Hiroshima University, 大学院・工学研究科, 教授 2008: Hiroshima University, 工学研究科, 教授 2005: 広島大学, 大学院工学研究科, 助教授 2004: 広島大学, 大学院・工学研究科, 助教授 … More
Review Section/Research Field	Principal Investigator Synthetic chemistry / 有機工業化学 / Synthetic chemistry / 有機工業化学 / Environmental technology/Environmental materials / Element strategy Except Principal Investigator Synthetic chemistry / 有機工業化学
Keywords	Principal Investigator ヒドロシリル化反応 / ヒドロホスフィン化反応 / 希土類金属 / アルキン / Dehydrogenative Silylation / 希土類錯体 / Hydrosilylation / 環化反応 / オキシメタラサイクル / Acylphosphonate … More Except Principal Investigator 希土類金属反応剤 / パラジウム触媒 / 極性変換 / メタンの活性化 / 酢酸パラジウム / 希土類反応剤 / Pd(OAc)_2 / Carbon Monoxide / phen / 一酸化炭素 / イッテルビウム / C-H Bond Activation / CーH結合活性化 / Lanthanoid Reagent / ニトロ化合物の脱酸素2量化 / 硫酸銅 / Copper Sulfate / アゾキシ化合物 / Deoxygenation by Sm / アルカン / One-step Phenol Synthesis / エポキシド / 非対称1、2-ジオ-ル / 非対称1,2-ジオ-ルの合成 / 銅塩 / シクロヘキサンカルボン酸 / Alkane C-H Bond Activation / イッテルビウム(III)トリフラート / イッテルビウム金属による非対称ピナコールの合成 / シレンーニッケル錯体 / 二酸化炭素(CO_2) / メタンのCO_2改質 / フェナントロリン配位子 / ベンゼンの酸素酸化 / イミンとCO_2よりαーアミノ酸合成 / Yb-mediated Syntheses / 希土類金属を用いる有機合成 / O_2混合ガス / チオケトンの二量化反応 / Ybによるイミンの二量化 / Ybによるケトンの求核付加 / 塩化イッテルビウム / アルドール〓合 / 格子酸素 / 酢配パラジウム / Phenanthroline / チオケトンの脱硫反応 / サマリウム金属によるニトロ基の脱酸素 / ケトンの極性変換 / 1,3-ジオ-ルの合成 / C-H結合活性化 / ベンゼンの酸化 / YbBr_2 / α,βー不飽和ケトン / 有機ケイ素ポリマ- / πーシラプロペニルニッケル錯体 / メタン部分酸化 / Azoxy Compound / CO系によるベンゼンの酸化 / アミノ酸合成 / メタン、エタン、プロパン / ニッケル触媒反応 / 親電子置換反応 / 触媒反応 / 三塩化ランタノイド / アルカンCーH結合活性化 / アダマンタンのカルボニル化 / サマリウム金属によるアゾキシ化合物の合成 / ハロゲン置換アゾキシ化合物の合成 / 1,2-ジアミノエタン / フェナントロリン / イツテルビウム金属による反応 / Cyclohexanecarboxylic Acid / 1,3-Diols / 均一系有機金属触媒反応 / Phenol from Benzene / ジアステレオ選択性 / Pd^<II>のアルカンへの親電子反応 / Organosilicon Polymer / チオケトン / 均一系触媒 / 固体電解質 / ペロブスカイト / 脂肪酸 / アゾキシ化合物の合成 / シクロヘキサンのカルボキシル化 / 酢配銅 / Activation of Methane / サマリウム(II)メントキシド / Yb-アセチリド / チオケトンの還元 / ランタノイド金属反応剤 / エタンよりプ個ピオン配合成 / シクロアルカンのカルボキシル化 / Electrophilic Substitution / Unsymmetrical Diols / サマロセン / ケテンシリルアセタール / 三塩化イッテルビウム / ベンゼンよりフェノール合成 / Homogeneous Catalyst / CO Catalysts / ベンゾシンノリンの合成 / モンサント酢酸プロセス / シリルアセチレン / イミンの極性変換 / メチル置換シクロヘキサン / メタンより酢配合成 / CO / Palladium Catalysts / Umpolung of Ketones / メタンより酢酸合成 / アルカンのカルボキシル化 / Yb-umpoled Ketones / Y_6-ジアニオン錯体 / イミンの還元 / 不活性小分子 / 固体晶析法 / シクロペンタノ-ル / ジエン / キラル1,3-ジオ-ル / π-アリルSm錯体 / CO触媒 / アルカンC-H結合活性化 / 希土類ルイス酸 / イッテレビウム金属による有機合成 / 1、3-ジオ-ル / イッテルビウムによる有機合成 / メタンから酢酸合成 / 合成ガス / イミン / 銅触媒 / Ybによるケトンの極性変換 / カルコンの環化二量化 / イッテルビウム反応剤 / 電気化学反応器 / イッテルビウムによる環元 / transー1,4ージメチルシクロヘキサン / Oxidation of Benzene / ダブルシリル化 / ジアリールケトン / α-ヒドロキシケトン / サマリウムによる有機合成 / エタンよりプロピオン酸合成 / プロパンより酪酸合成 / O_2 / Acetic Acid from Methane / 希土類による合成 / ジアリールチオケトン / エンイン / プロパンより酪配合成 / フェノールの一段階合成 Less

Activation of simple carbon molecules by NHC catalysts and their application in organic synthesisPrincipal Investigator
- Principal Investigator
  
  TAKAKI Ken
- Project Period (FY)
  2012 – 2014
- Research Category
  
  Grant-in-Aid for Challenging Exploratory Research
- Research Field
  
  Synthetic chemistry
- Research Institution
  Hiroshima University
New synthetic methodology of heterocycles based on ubiquitous metal catalystsPrincipal Investigator
- Principal Investigator
  
  TAKAKI Ken
- Project Period (FY)
  2008 – 2009
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Element strategy
- Research Institution
  Hiroshima University
太陽光を利用する新規な環境浄化用光触媒の開発Principal Investigator
- Principal Investigator
  
  高木謙
- Project Period (FY)
  2004 – 2005
- Research Category
  
  Grant-in-Aid for Exploratory Research
- Research Field
  
  Environmental technology/Environmental materials
- Research Institution
  Hiroshima University
Introduction of Heteroatoms Based on New Catalyst Activities of Lanthanide ComplexesPrincipal Investigator
- Principal Investigator
  
  TAKAKI Ken
- Project Period (FY)
  2001 – 2002
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Synthetic chemistry
- Research Institution
  HIROSHIMA UNIVERSITY
希土類錯体による新規な触媒反応の開発Principal Investigator
- Principal Investigator
  
  高木謙
- Project Period (FY)
  1999
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas (A)
- Research Institution
  Hiroshima University
Generation of New Active Lanthanide Species and Their Use in Organic SynthesisPrincipal Investigator
- Principal Investigator
  
  TAKAKI Ken
- Project Period (FY)
  1999 – 2000
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Hiroshima University
格子酸素を利用する炭素-酸素結合生成反応
- Principal Investigator
  
  竹平勝臣
- Project Period (FY)
  1998
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas (A)
- Research Institution
  Hiroshima University
希土類金属分子を用いる新分子変換反応
- Principal Investigator
  
  藤原裕三
- Project Period (FY)
  1994
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Hiroshima University
希土類π-アリル錯体の新規合成及びその合成化学的利用Principal Investigator
- Principal Investigator
  
  高木謙
- Project Period (FY)
  1994
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  有機工業化学
- Research Institution
  Hiroshima University
希土類金属分子を用いる新分子変換反応
- Principal Investigator
  
  藤原祐三
- Project Period (FY)
  1993 – 1994
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Hiroshima University
ヘテロ元素化合物と希土類等の澪移金属を用いる新分子変換反応
- Principal Investigator
  
  藤原祐三
- Project Period (FY)
  1992
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Hiroshima University
アルカンC-H結合の遷移金属錯体による活性化を経る合成反応
- Principal Investigator
  
  藤原祐三
- Project Period (FY)
  1992
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Hiroshima University
遷移金属錯体によるC-H結合活性化を経る新規合成反応
- Principal Investigator
  
  藤原祐三
- Project Period (FY)
  1992
- Research Category
  
  Grant-in-Aid for General Scientific Research (B)
- Research Field
  
  有機工業化学
- Research Institution
  Hiroshima University
Development of One-Step Synthetic Process of Phenol form Benzene
- Principal Investigator
  
  FUJIWARA Yuzo
- Project Period (FY)
  1992 – 1993
- Research Category
  
  Grant-in-Aid for Developmental Scientific Research (B)
- Research Field
  
  Synthetic chemistry
- Research Institution
  HIROSHIMA UNIVERSITY
希土類等の遷移金属を用いる新分子変換反応
- Principal Investigator
  
  藤原祐三
- Project Period (FY)
  1991
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Hiroshima University
希土類等の遷移金属を用いる新分子変換反応
- Principal Investigator
  
  藤原祐三
- Project Period (FY)
  1990
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Hiroshima University
希土類金属の特性を利用した新有機合成反応の開発Principal Investigator
- Principal Investigator
  
  高木謙
- Project Period (FY)
  1990
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  有機工業化学
- Research Institution
  Hiroshima University
Exploitation of New Synthetic Reactions via Thermal Activation of Alkane C-H Bonds by Transition Metals
- Principal Investigator
  
  FUJIWARA Yuzo
- Project Period (FY)
  1990 – 1991
- Research Category
  
  Grant-in-Aid for General Scientific Research (B)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Hiroshima University
希土類等の遷移金属を用いる新分子変換反応
- Principal Investigator
  
  FUJIWARA Yuzo
- Project Period (FY)
  1989
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Hiroshima University
Interaction Between Ethynylsilanes and Transition-Metal-Complex
- Principal Investigator
  
  ISHIKAWA Mitsuo
- Project Period (FY)
  1989 – 1990
- Research Category
  
  Grant-in-Aid for General Scientific Research (B)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Hiroshima University
ケイ素ー炭素二重結合化学種と遷移金属錯体との相互作用
- Principal Investigator
  
  ISHIKAWA Mitsuo
- Project Period (FY)
  1988
- Research Category
  
  Grant-in-Aid for Developmental Scientific Research
- Research Field
  
  有機工業化学
- Research Institution
  Hiroshima University
Development of New Synthetic Reactions by Rare Earth Metals
- Principal Investigator
  
  FUJIWARA Yuzo
- Project Period (FY)
  1988 – 1989
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  Synthetic chemistry
- Research Institution
  HIROSHIMA UNIVERSITY
  Kyushu University

All 2014 2013 2012 2010 2009 2008 2004 Other

All Journal Article Presentation

[Journal Article] N-Hetrocyclic carbene-catalyzed double acylation of enones with benzils.2014
- Author(s)
  Ken Takaki, Akira Ohno, Makoto Hino, Takashi Shitaoka, Kimihiro Komeyama, Hiroto, YoshidaHiroto Yoshida
- Journal Title
  
  Chem. Commun.
  
  Volume: 50 Pages: 12285-12288
- DOI
  10.1039/c4cc05436a
- Open Access / Acknowledgement Compliant / Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24655084
[Journal Article] Scope and Limitation for FeSO4-Mediated Direct Arylation of Heteroarenes with Arylboronic Acids and Its Synthetic Applications2014
- Author(s)
  K. Komeyama, Y. Nagao, M. Abe, K. Takaki
- Journal Title
  
  Bull. Chem. Soc. Jpn.
  
  Volume: 87 Pages: 301-303
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24655084
[Journal Article] Borderline metal-catalyzed organic synthesis2012
- Author(s)
  K. Komeyama, K. Takaki
- Journal Title
  
  Shokubai
  
  Volume: 54 Pages: 251-256
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-24655084
[Journal Article] Cationic Iron-Catalyzed Intramolecular Alkyne-hydroarylation with Electron-deficient Arenes.2010
- Author(s)
  K. Komeyama, R. Igawa, K. Takaki
- Journal Title
  
  Chem. Commun 46
  
  Pages: 1748-1750
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Cationic iron-catalyzed intramolecular alkyne-hydroarylation with electron-deficient arenes2010
- Author(s)
  Kimihiro Komeyama, Ryoichi Igawa, Ken Takaki
- Journal Title
  
  Chemical Communications 46
  
  Pages: 1748-1750
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Direct approach to multi-substituted pyrroles from propargyl amine and 1, 3-diketone or β-keto ester using Bi(0Tf)3.2009
- Author(s)
  Kimihiro. Komevama. Motovoshi Miyagi. Ken Takaki
- Journal Title
  
  Chemistry Letters 38
  
  Pages: 224-225
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Intramolecular Alkynylcyclopropanation of olefins catalyzed by Bi(OTf)3 : Stereoselective Synthesis of 1-alkynyl-3-azabicyclo [3. 1. 0] hexanes2009
- Author(s)
  Kimihiro Komeyama, Natsuko Saigo, Motoyoshi Miyagi, Ken Takaki
- Journal Title
  
  Angewandte Chemie International Edition 48
  
  Pages: 9875-9878
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Catalytic cyclization of alkenyl N, O-acetals by Fe(OTf)32009
- Author(s)
  Kimihiro Komeyama, Ryoichi Igawa, Takayuki Morimoto, Ken Takaki
- Journal Title
  
  Chemistry Letters 38
  
  Pages: 724-725
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Intramolecular Alkynylcyclopropanation of Olefins Catalyzed by Bi(OTf)3: Stereoselective Synthesis of 1-Alkyny1-3-azabicyclo[3, 1, 0]hexanes.2009
- Author(s)
  K. Komeyama, N. Saigo, M. Miyagi K. Takaki
- Journal Title
  
  Angew. Chem Int. Ed. 48
  
  Pages: 9875-9878
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Direct Approach to Multi-substituted Pyrroles from 2-Propynylamine and 1, 3-Diketones or β-Keto Esters Using Bi(OTf)3 Catalyst.2009
- Author(s)
  K. Komeyama, M. Miyagi, K. Takaki
- Journal Title
  
  Chemistry Letters 38(3)
  
  Pages: 224-225
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Catalytic Cyclization of Alkenyl N, O-Acetals by Fe(OAc)3.2009
- Author(s)
  K. Komeyama, R. Igawa, T. Morimoto, K. Takaki
- Journal Title
  
  Chemistry Letters 38(7)
  
  Pages: 724-725
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Bismuth-catalyzed intramolecuar hydro-oxycarbonylation of alkynes2008
- Author(s)
  Kimihiro Komeyama, Keita Takahashi., Ken Takaki
- Journal Title
  
  Chemistry Letters 37
  
  Pages: 602-603
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Bismuth-catalyzed intramolecular carbo-oxycarbonylation of 3-alkynyl esters.2008
- Author(s)
  Kimihiro Komeyama, Keita Takahashi, Ken Takaki
- Journal Title
  
  Organic Letters 10
  
  Pages: 5119-5122
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Bismuth-catalyzed Intramolecular Carbo-oxycarbonylaton of 3-Alkynyl Esters.2008
- Author(s)
  K. Komeyama, K. Takahashi, K. Takaki
- Journal Title
  
  Organic Letters 10(22)
  
  Pages: 5119-5122
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Bismuth-catalyzed Intramolecular Hydro-oxycarbonylation of Alkynes.2008
- Author(s)
  K. Komeya-ma, K. Takahashi, K. Takaki
- Journal Title
  
  Chemistry Letters 37(6)
  
  Pages: 602-603
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Bismuth-catalyzed cyclization of amino-1.6-enynes.2008
- Author(s)
  Kimihiro Komeyama, Motoyoshi Miyagi, Ken Takaki
- Journal Title
  
  Heteroatom Chemistry 19
  
  Pages: 644-648
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Bismuth-catalyzed Cyclization of Amino-1, 6-enynes.2008
- Author(s)
  K. Komeyama, M. Miyagi, K. Takaki
- Journal Title
  
  Hetaroatom Chemistry 19(6)
  
  Pages: 644-648
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20613010
[Journal Article] Photocatalytic oxidation of alkanes with dioxygen by visible light and copper(II) and iron(III) chloride : preference oxidation of alkan2004
- Author(s)
  K.Takaki, J.Yamamoto, K.Komeyama, T.Kawabata, K.Takehira
- Journal Title
  
  Bulletin of the Chemical Society of Japan 77・12
  
  Pages: 2251-2255
- Data Source
  KAKENHI-PROJECT-16651039
[Presentation] NHC触媒とベンジルによるα,β-不飽和ケトンのダブルアシル化反応2014
- Author(s)
  大野　晃、日野真人、下岡隆士、米山公啓、吉田拡人、高木　謙
- Organizer
  日本化学会
- Place of Presentation
  名古屋大学
- Data Source
  KAKENHI-PROJECT-24655084
[Presentation] NHC触媒とベンジルを用いるα,β-不飽和カルボニル化合物のダブルアシル化反応2013
- Author(s)
  大野　晃、日野真人、下岡隆士、米山公啓、吉田拡人、高木　謙
- Organizer
  日本化学会中国四国支部
- Place of Presentation
  広島大学
- Data Source
  KAKENHI-PROJECT-24655084
[Presentation] ビスマス触媒を用いたタンデム型エン/ヒドロアミノ化反応2010
- Author(s)
  高木謙
- Organizer
  日本化学会第90回春季年会
- Place of Presentation
  近畿大学・東大阪
- Year and Date
  2010-03-26
- Data Source
  KAKENHI-PROJECT-20613010
[Presentation] ビスマス触媒を用いたエンイノール類のアルキニルシクロプロパン化反応2009
- Author(s)
  米山公啓, 宮城元嘉, 高木謙
- Organizer
  日本化学会第89回春季年会
- Place of Presentation
  日本大学
- Year and Date
  2009-03-29
- Data Source
  KAKENHI-PROJECT-20613010
[Presentation] Intramolecular Hydroarylation of Alkynes with Electron-deficient Arenes by Iron Catalyst2009
- Author(s)
  高木謙
- Organizer
  IKOCK-11
- Place of Presentation
  京都
- Year and Date
  2009-09-11
- Data Source
  KAKENHI-PROJECT-20613010
[Presentation] カチオン性鉄錯体を触媒とする芳香族置換アルキンの分子内ヒドロアリール化反応2009
- Author(s)
  井川亮一, 米山公啓, 高木謙
- Organizer
  日本化学会第89回春季年会
- Place of Presentation
  日本大学
- Year and Date
  2009-03-29
- Data Source
  KAKENHI-PROJECT-20613010
[Presentation] カチオン性鉄触媒を用いた電子不足芳香環のアルキンへの分子内ヒドロアリール化反応2009
- Author(s)
  井川亮一, 米山公啓, 高木謙
- Organizer
  第56回有機金属討論会
- Place of Presentation
  同志社大学
- Year and Date
  2009-09-10
- Data Source
  KAKENHI-PROJECT-20613010
[Presentation] Borderline Metal-Catalyzed Heterofunctionalization of Alkyne2008
- Author(s)
  米山公啓, 高橋慶多, 高木謙
- Organizer
  第55回有機金属化学討論会
- Place of Presentation
  大阪府立大学
- Year and Date
  2008-10-28
- Data Source
  KAKENHI-PROJECT-20613010
[Presentation] NHC触媒とベンジルまたは芳香族アルデヒドによるイノンのダブルアシル化反応
- Author(s)
  日野真人、大野　晃、沖永紘輔、米山公啓、吉田拡人、高木　謙
- Organizer
  日本化学会第95春季年会
- Place of Presentation
  日本大学理工学部船橋キャンパス
- Year and Date
  2015-03-26 – 2015-03-29
- Data Source
  KAKENHI-PROJECT-24655084

1. FUJIWARA Yuzo (10029481)

# of Collaborated Projects: 13 results

# of Collaborated Products: 0 results
2. TANIGUCHI Yuki (50217139)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
3. ISHIKAWA Mitsuo (20025985)

# of Collaborated Projects: 2 results

# of Collaborated Products: 0 results
4. OHSIHITA Joji (90201376)

# of Collaborated Projects: 2 results

# of Collaborated Products: 0 results
5. ISOMURA Kazuaki (80037887)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
6. 竹平勝臣 (70294535)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
7. 宍戸哲也 (80294536)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
8. 川端智則 (70363025)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
9. JINTOKU Tetsuro

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
10. 浜川聡

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results

TAKAKI Ken 高木 謙

高木 謙 タカキ ケン

Research Projects

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Activation of simple carbon molecules by NHC catalysts and their application in organic synthesisPrincipal Investigator

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New synthetic methodology of heterocycles based on ubiquitous metal catalystsPrincipal Investigator

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太陽光を利用する新規な環境浄化用光触媒の開発Principal Investigator

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Introduction of Heteroatoms Based on New Catalyst Activities of Lanthanide ComplexesPrincipal Investigator

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希土類錯体による新規な触媒反応の開発Principal Investigator

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Generation of New Active Lanthanide Species and Their Use in Organic SynthesisPrincipal Investigator

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希土類π-アリル錯体の新規合成及びその合成化学的利用Principal Investigator

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TAKAKI Ken 高木謙

高木謙タカキケン