New Aspects of Catalytic Trans form ation of Alcohols Using Metal Alkoxides Having Protic Ligands
Project/Area Number |
21350052
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Synthetic chemistry
|
Research Institution | Nagoya University |
Principal Investigator |
SAITO Susumu 名古屋大学, 大学院・理学研究科, 准教授 (90273268)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2011: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2009: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
|
Keywords | アルコール / 求電子剤 / 分子表面触媒 / 環境負荷低減 / 遷移金属 / 主要元素 / 分子触媒反応 / アルコール変換 / プロトン性配位子 / 金属アルコキシド / 炭素-炭素結合形成反応 / 炭素-酸素結合形成反応 / 炭素-窒素結合形成反応 / N-アルキル化 |
Research Abstract |
The research project was focused on how we could control and alter the reactivity of alcohols as electrophile(R^+-^OH) nucleophile(R^+-^OH) using new molecular catalyses in organic synthesis. Importance of a new concept“molecular surface"in those catalyses was newly introduced and validated during the project. Overall, we demonstrated that molecular surface consisting of special element and bond alignment as represented by RO(δ-)-M(δ+)-X(δ-)-H(δ+) is important to achieve otherwise difficult catalysis under near neutral pH conditions.
|
Report
(4 results)
Research Products
(131 results)