Issue 31, 2014

X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Abstract

A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.

Graphical abstract: X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Supplementary files

Article information

Article type
Communication
Submitted
19 Nov 2013
Accepted
17 Jan 2014
First published
20 Jan 2014

Chem. Commun., 2014,50, 4050-4052

Author version available

X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Y. Sekine, M. Nihei, R. Kumai, H. Nakao, Y. Murakami and H. Oshio, Chem. Commun., 2014, 50, 4050 DOI: 10.1039/C3CC48820A

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