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OKAWA Hisashi  大川 尚士

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… Alternative Names

大川 尚  オオカワ ヒサシ

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Researcher Number 00037219
Other IDs
Affiliation (based on the past Project Information) *help 2007: kyushu University, Faculty of Sciences, Prof. Doc.
2007: 京都大学, 九州大学・理学研究院, 名誉教授
2005 – 2006: 九州大学, 理学研究科, 教授
2004: 九州大学, 大学院・理学研究科, 教授
2004: Kyushu University, Faculty of Science, Professor, 理学研究院, 名誉教授 … More
2000 – 2003: 九州大学, 大学院・理学研究院, 教授
1997 – 1999: 九州大学, 大学院・理学研究科, 教授
1991 – 1998: 九州大学, 理学部, 教授
1996: Kyushu Univ..Fac.Sci., Prof., 理学部, 助教授
1992: 九州大, 理学部, 教授
1987 – 1990: 九州大学, 理学部, 助教授 Less
Review Section/Research Field
Principal Investigator
Inorganic chemistry / 無機・錯塩・放射化学 / Science and Engineering
Except Principal Investigator
Inorganic chemistry / Science and Engineering
Keywords
Principal Investigator
X線結晶構造 / コンパートメント配位子 / フェロ磁性体 / 強磁性体 / 異常原子価 / 鋳型反応 / 反強磁性的相互作用 / ヘテロ二核錯体 / 酸素錯体 / 金属酵素モデル … More / 磁気的相互作用 / 大環状配位子 / 二次元シート構造 / メタ磁性体 / 自発磁化 / Schiff Base Ligands / Tetrahedral Complexes / Enantioselectivity / Circular dichroism / X-Ray Crystal Structure / Non-covalent Interraction / Stereoselectivity / CDスペクトル / 1,3ージケトン / 分子内相互作用 / 錯体の立体選択性 / ルイス酸触媒 / ランタノイド錯体 / 不斉還元 / レジオナル則 / コンホーメーション解析 / 円二色性スペクトル / 亜鉛(11)錯体 / シッフ塩基配位子 / 四面体錯体 / 円偏光二色性 / Xー線結晶構造解析 / 非共有相互作用 / 立体選択性 / spin exchange / metal-metal bond / single-molecule magnet / compartmental ligand / metal cluster / coordination polymer / molecular magnet / heteronuclear complex / 金属多重結合 / 電子スプレー質量分析 / 配位高分子 / 金属ー金属結合 / 構造解析 / 多孔性固体 / 一次元錯体 / 酸化物クラスター / 多孔性個体 / 合成ゼオライト / フェリ磁性体 / 金属結合 / 単分子磁石 / クラスター / 高分子錯体 / 人工ゼオライト / 分子磁性体 / ヘテロ金属錯体 / Peroxo complex / Catalase-like function / Heterodinuclear complex / Oxygenation / Unusual oxidation state / Mixed-valence complex / Dinuclear complex / Macrocyclic ligand / コンバートメント配位子 / スーパーオキソ錯体 / ベルオキソ錯体 / 酵素錯体 / 配位位置異性 / ペルオキソ錯体 / ヘテロニ核錯体 / Spontaneous magnetization / Bridging ligand / Network compound / Magnetic ordering / Diazine ligands / Bimetallic compound / Metamegnet / Ferrimagnet / 架橋配位子 / 双性配位子 / 磁気交換 / 伸展型錯体 / ヘテロ多核鎖体 / 双性架橋配位子 / X線結晶構造解析 / ハイゼンベルグモデル / 一次元鎖構造 / ヘテロ多核錯体 / electrochemistry / electron spin resonance / dioxygen-adducts / magnetic interaction / unusual oxidation-state / X-ray crystallography / macrocycle / heterodinuclear / 電子スピン共鳴(ESR) / 二核錯体 / 可逆的酸素付加物 / 電気化学 / 電子スピン共鳴 / 酸素付加物 / 異常原子価錯体 / マクロサイクル / Ascorbate oxidase / Functional model / Electrontransfer / Multicopper enzyme / Manganese complex / Hydrogenperoxide / Manganese catalase / Metalloenzyme model / マンガン(IV)オキソ錯体 / 二電子伝達 / 不均化反応 / 過酸化水素 / アスコルビン酸酸化酵素 / 機能モデル / 分子内電子移動反応 / マルチ銅酵素 / 二核マンガン錯体 / 過酸化水素分解 / マンガンカタラーゼ / Supramolecule / Carcogenide / Prototropy / Chromotropism / Metal Porpyrine / CO_2 Reduction / Ferromagnet / O_2 Adduct / 複合系錯体 / カルコゲニド錯体 / ヘムエリトリン / スイッチング機能 / 伝導性錯体 / 抗腫瘍性白金錯体 / タングステン酸化環元酵素 / 水素結合 / 多電子移動 / 超電導ガラス / 白金クラスター / 構造精密制御 / クラスター錯体 / 分子活性化 / 酸素運搬 / 導電性 / 分子強磁性体 / 構造制御 / 金属錯体 / フェロ磁性 / 磁気交換相互作用 / 混合金属錯体 / 混合スピン錯体 / 混合金属四核錯体 / 不完全ダブルキュバン構造 / 強磁性的相互作用 / 三次元ネットワーク / ハイブリッド錯体 / ヘテロ金属集合体 / 分子設計法 … More
Except Principal Investigator
多核金属錯体 / 混合原子価錯体 / 金属クラスター錯体 / 集積型金属錯体 / 金属クラスター / マンガンカタラーゼ / 亜鉛錯体 / チトクロム酸化酵素 / Fuel Cell / Energy Device / nitric oxide reductase / ferritin / nanometerial / surface properties / Metal Complexes / Coordination Space / 新聞報道 / 研究交流 / 成果報告 / 情報交換 / 共同研究 / 国際会議 / 研究成果 / 全体会議 / プロトン伝導 / エネルギー操作 / 一酸化窒素還元酵素 / フェリチン / ナノ材料 / 表面・界面物性 / 金属錯体 / 配位空間 / Function model / Dinuclear complex / Hydrolysis / Phosphodiesterase / Phosphotriesterase / μ-ペルオキソ錯体 / 配位位置異性 / 異常原子価二核錯体 / 大環状二核化配位子 / 尿素の化学変換 / ヘテロ二核錯体 / ウレアーゼモデル / ESI質量分析 / 非対称型二核化配位子 / コンパートメント配位子 / 機能モデル / 二核錯体 / 加水分解反応 / リン酸ジエステラーゼ / リン酸トリエステラーゼ / metal complex assemblage / molecular conductor / supramolecular complex / porous solid / molecular magnet / mixed valence / cluster complexes / polynuclear complexes / 多重機能 / 協同効果 / 分子集合体 / 錯体集合体 / 超分子 / multi-nuclear metal complex / molecular recogition unit / synthetic bilayer unit / molecular orientation / nitrogen-containing cage molecule / organic zeolite / molecular magnetic complex / high spin molecule / 分子認識素子 / 合成二分子膜 / 分子配列 / 含窒素多架橋カゴ型化合物 / 有機ゼオライト / 錯体分子磁性体 / 高スピン分子 / グリーンケミストリー / 錯体化学 / 緑の地球科学 / 酸素類似機能 / 多核錯体 / 分子変換 / 錯体触媒 / 水素発生 / エネルギー変換 / dブロック元素 / 化学的構築 / 高次構造 / 反応制御 / 環境と医療 / 超機能システム / 生命金属元素 / 生物無機化学 / 多元金属錯体 / 時間分解ラマン / ミオグロビン / 共鳴ラマン散乱 / フェロ磁性体 / 強磁性的相互作用 / 有機金属錯体 / ポリラジカル / ニトロキシド / フェリ磁性体 / 強磁性体 / 三架橋D_3対称性 / 遷移金属錯体 / ポリマー / アニオンラジカル / ラジカル結晶 / 電荷移動錯体 / 高キュリー温度 / 金属錯体強磁性体 / 高分子強磁性体 / 有機磁性金属 / 有機フェリ磁性体 / 有機強磁性体 / 設計と構築 / 新しい分子磁性系 / キノールオキシダーゼ / 光合成反応中心タンパク複合体 / 金属酵素 / マンガンクラスター / 共鳴ラマン / 酸素の活性化 / ニトクロム酸化酵素 / 水の酸化 / 酸素の活性化機構 / マンガンクラスタ- / 共鳴ラマン分光 Less
  • Research Projects

    (22 results)
  • Research Products

    (17 results)
  • Co-Researchers

    (55 People)
  •  Chemistry of Coordination Space

    • Principal Investigator
      KITAGAWA Susumu
    • Project Period (FY)
      2004 – 2007
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Review Section
      Science and Engineering
    • Research Institution
      Kyoto University
  •  Design and creation of reaction active multinuclear metal complexPrincipal Investigator

    • Principal Investigator
      OHBA Masaaki, 大川 尚士
    • Project Period (FY)
      2002 – 2004
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Inorganic chemistry
    • Research Institution
      Kyoto University
      Kyushu University
  •  コンパートメント配位子を用いる四核金属錯体の合理的合成と化学特性の研究Principal Investigator

    • Principal Investigator
      大川 尚士
    • Project Period (FY)
      2001 – 2002
    • Research Category
      Grant-in-Aid for Exploratory Research
    • Research Field
      Inorganic chemistry
    • Research Institution
      Kyushu University
  •  錯体化学を基盤とする緑の地球科学への新接近法

    • Principal Investigator
      矢野 重信
    • Project Period (FY)
      1998
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Inorganic chemistry
    • Research Institution
      Nara Women's University
  •  Metal-assembled Complexes -Chemisty Based on Inorganic-Organic Hybrid Electronic Structures-

    • Principal Investigator
      ITO Tasuku
    • Project Period (FY)
      1998 – 2002
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Review Section
      Science and Engineering
    • Research Institution
      Tohoku University
  •  Synthesis of Discrete Polynuclear Complexes and Units for Metal-Assembled CompoundsPrincipal Investigator

    • Principal Investigator
      OKAWA Hisashi
    • Project Period (FY)
      1998 – 2001
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas (A)
    • Review Section
      Science and Engineering
    • Research Institution
      Kyushu University
  •  三次元ハイブリッド金属錯体:自発磁化の発現Principal Investigator

    • Principal Investigator
      大川 尚士
    • Project Period (FY)
      1997
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyushu University
  •  無機有機複合体による生物機能の高次制御

    • Principal Investigator
      矢野 重信
    • Project Period (FY)
      1997
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Inorganic chemistry
    • Research Institution
      Nara Women's University
  •  無機有機複合電子系化合物の集積

    • Principal Investigator
      ITO Tasuku
    • Project Period (FY)
      1997
    • Research Category
      Grant-in-Aid for Scientific Research (C)
    • Research Field
      Inorganic chemistry
    • Research Institution
      Tohoku University
  •  Metal Complexes in Extended Systems : Design and MagnetismPrincipal Investigator

    • Principal Investigator
      OKAWA Hisashi
    • Project Period (FY)
      1997 – 1999
    • Research Category
      Grant-in-Aid for Scientific Research (B).
    • Research Field
      Inorganic chemistry
    • Research Institution
      KYUSHU UNIVERSITY
  •  Characteristics and Functions of Dinuclear Complexes in Unusual Oxidation StatesPrincipal Investigator

    • Principal Investigator
      OKAWA Hisashi
    • Project Period (FY)
      1997 – 1999
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Inorganic chemistry
    • Research Institution
      KYUSHU UNIVERSITY
  •  Design and Control of Advanced Molecular Assembly Systems

    • Principal Investigator
      SHINKAI Seiji, 岩村 秀
    • Project Period (FY)
      1996 – 2002
    • Research Category
      Grant-in-Aid for COE Research
    • Research Institution
      Kyushu-University
  •  Studies on Heterodinuclear Metal ComplexesPrincipal Investigator

    • Principal Investigator
      OKAWA Hisashi
    • Project Period (FY)
      1995 – 1996
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Inorganic chemistry
    • Research Institution
      KYUSHU UNIVERSITY
  •  新しい分子磁性系の設計と構築

    • Principal Investigator
      杉本 豊成
    • Project Period (FY)
      1994
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyoto University
  •  多核金属酵素活性中心への生物無機化学的アプローチPrincipal Investigator

    • Principal Investigator
      OKAWA Hisashi
    • Project Period (FY)
      1994 – 1995
    • Research Category
      Grant-in-Aid for international Scientific Research
    • Research Institution
      KYUSHU UNIVERSITY
  •  生物機能が求める多元金属錯体反応系の研究

    • Principal Investigator
      山内 脩
    • Project Period (FY)
      1993
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Field
      Inorganic chemistry
    • Research Institution
      Nagoya University
  •  Stereochemical Controle for Functonal Metal ComplexesPrincipal Investigator

    • Principal Investigator
      OKAWA Hisashi
    • Project Period (FY)
      1992 – 1993
    • Research Category
      Grant-in-Aid for Co-operative Research (A)
    • Research Field
      無機・錯塩・放射化学
    • Research Institution
      KYUSYU UNIVERSITY
  •  金属酵素活性部位の精密モデル化

    • Principal Investigator
      KITAGWA Teizo
    • Project Period (FY)
      1991
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Okazaki National Research Institutes
  •  架橋性D_3対称錯体を構築素子とする錯体分子強磁性体の設計Principal Investigator

    • Principal Investigator
      大川 尚士
    • Project Period (FY)
      1991
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Field
      無機・錯塩・放射化学
    • Research Institution
      Kyushu University
  •  金属酵素活性部位の精密モデル化

    • Principal Investigator
      北川 禎三
    • Project Period (FY)
      1991 – 1993
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Okazaki National Research Institutes
  •  金属酵素活性部位の精密モデル化

    • Principal Investigator
      北川 禎三
    • Project Period (FY)
      1991 – 1993
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Okazaki National Research Institutes
  •  Intramolecular Non-covalent Interactions in Metal Complexes : Geometrical Controles and Stereoselective ReactionsPrincipal Investigator

    • Principal Investigator
      OKAWA Hisashi
    • Project Period (FY)
      1987 – 1990
    • Research Category
      Grant-in-Aid for General Scientific Research (A)
    • Research Field
      無機・錯塩・放射化学
    • Research Institution
      Kyushu University

All 2005 2004

All Journal Article

  • [Journal Article] μ-Hydroxo-μ-phenolato Dinuclear Zn(II) and Ni(II) Complexes Derived from Di-nucleating Compartmental Ligands of ‘End-off' Type : Synthesis, Structures and Properties2005

    • Author(s)
      K.Matsufuji, H.Shiraishi, T.Shiga, M.Ohba, Y.Yokoyama, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan in press

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] Dinuclear Mn(II), Ni(II) and Zn(II) Complexes Bridged by Di(p-nitrophenyl) Phosphate Ion : Relevance to Bimetallic Phosphodiesterase2005

    • Author(s)
      H.Shiraishi, R.Jikido, K.Matsufuji, T.Shiga, M.Ohba, H.Kitagawa, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan (発表予定)

    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] Dinuclear Mn(II), Ni(II) ando Zn(II) Complexes Bridged by Di(p-nitrophenyl) Phosphate Ion : Relevance to Bimetallic Phosphodiesterase2005

    • Author(s)
      H.Shiraishi, R.Jikido, K.Matsufuji, T.Shiga, M.Ohba, H.Kitagawa, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] Dinuclear Mn(II),Ni(II) and Zn(II) Complexes Bridged by Di(p-nitrophenyl) Phosphate Ion : Relevance to Bimetallic Phosphodiesterase2005

    • Author(s)
      H.Shiraishi, R.Jikido, K.Matsufuji, T.Shiga, M.Ohba, H.Kitagawa, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] μ-Hydroxo-μ-phenolato Dinuclear Zn(II) and Ni(II) Complexes Derived from Dinucleating Compartmental Ligands of 'End-off' Type : Synthesis, Structures and Properties2005

    • Author(s)
      K.Matsufuji, H.Shiraishi, T.Shiga, M.Ohba, Y.Yokoyama, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] μ-Hydroxo-μ-phenolato Dinuclear Zn(II) and Ni(II) Complexes Derived from Dinucleating Compartmental Ligands of 'End-off' Type : Synthesis, Structures and Properties2005

    • Author(s)
      K.Matsufuji, H.Shiraishi, T.Shiga, M.Ohba, Y.Yokoyama, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan (発表予定)

    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] Tetranuclear Ni^<II> and Dinuclear Mn^<III> Complexes Derived from A New Macrocyclic Ligands with Four Endogenous Phenolic Groups2004

    • Author(s)
      K.Ikeda, K.Matsufuji, M.Ohba, M.Kodera, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan 77

      Pages: 733-739

    • NAID

      10012849068

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] A Series of Trinuclear Cu(II)Ln(III)Cu(II)Complexes Derived from 2,6-di(acetoacetyl)pyridine : Synthesis, Structure, and Magnetism2004

    • Author(s)
      T.Shiga, M.Ohba, H.Okawa
    • Journal Title

      Inorganic Chemistry 43・14

      Pages: 4435-4446

    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] μ-Acetato-di-μ-phenolato-metal(II)cobalt(II) (Metal = Fe, Co, Ni, Cu, Zn) Complexes with Low-spin Co(II) : Synthesis, Structures and Magnetism2004

    • Author(s)
      K.Matsumoto, N.Sekine, K.Arimura, M.Ohba, H.Sakiyama, H.Okawa
    • Journal Title

      Bulletin and Chemical Society of Japan 77・7

      Pages: 1343-1351

    • NAID

      10013278870

    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] A Series of Trinuclear Cu(II)Ln(III)Cu(II) Complexes Derived from 2,6-di(acetoacetyl) pyridine : Synthesis, Structure, and Magnetism2004

    • Author(s)
      T.Shiga, M.Ohba, H.Okawa
    • Journal Title

      Inorganic Chemistry 43

      Pages: 4435-4446

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] Tetranuclear Ni^<II> and Dinuclear Mn^<III> Complexes Derived from A New Macrocyclic Ligands with Four Endogenous Phenolic Groups2004

    • Author(s)
      K.Ikeda, K.Matsufuji, M.Ohba, M.Kodera, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan 77・3

      Pages: 733-739

    • NAID

      10012849068

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] The Structure and Magnetism of Trinuclear Ni(II), Co(II) and Mn(II) Complexes Derived from Unsymmetrical Compartmental Ligand2004

    • Author(s)
      H.Adams, D.E.Fenton, L.R.Cummings, P.E.McHugh, M.Ohba, H.Okawa
    • Journal Title

      Inorganic Chimica Acta 357

      Pages: 3648-3656

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] The Structure and Magnetism of Trinuclear Ni(II), Co(II), and Mn(II) Complexes Derived from Unsymmetrical Compartmental Ligand2004

    • Author(s)
      H.Adams, D.E.Fenton, L.R.Cumming, P.E.McHugh, M.Ohba, H.Okawa
    • Journal Title

      Inorganic Chimica Acta 357・12

      Pages: 3648-3656

    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] A Series of Trinuclear Cu(II)Ln(III)Cu(II) Complexes Derived from 2,6-di(acetoacety1)pyridine : Synthesis, Structure, and Magnetism2004

    • Author(s)
      T.Shiga, M.Ohba, H.Okawa
    • Journal Title

      Inorganic Chemistry 43・14

      Pages: 4435-4446

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] The Structure and Magnetism of Trinuclear Ni(II), Co(II) and Mn(II) Complexes Derived from Unsymmetrical Compartmental Ligand2004

    • Author(s)
      H.Adams, D.E.Fenton, L.R.Cummings, P.E.McHugh, M.Ohba, H.Okawa
    • Journal Title

      Inorganic Chimica Acta 357・12

      Pages: 3648-3656

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] μ-Acetato-di-μ-phenolato-metal(II)cobalt(II) (Metal=Fe,Co,Ni,Cu,Zn) Complexes with Low-spin Co(II) : Synthesis, Structures and Magnetism2004

    • Author(s)
      K.Matsumoto, N.Sekine, K.Arimura, M.Ohba, H.Sakiyama, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan 77

      Pages: 1343-1351

    • NAID

      10013278870

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • [Journal Article] μ-Acetato-di-μ-phenolato-metal(II)cobalt(II) (Metal = Fe, Co, Ni, Cu, Zn) Complexes with Low-spin Co(II) : Synthesis, Structures and Magnetism2004

    • Author(s)
      H.Matsumoto, N.Sekine, K.Arimura, M.Ohba, H.Sakiyama, H.Okawa
    • Journal Title

      Bulletin of the Chemical Society of Japan 77・7

      Pages: 1343-1351

    • NAID

      10013278870

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-14340208
  • 1.  OHBA Masaaki (00284480)
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  • 2.  TAKAHASHI Kazuhiro (00216706)
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