KASAI TOSHIO 笠井俊夫

… Alternative Names

KASAI Toshio 笠井俊夫

笠井俊夫カサイトシオ

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Researcher Number	20152613
External Links
Affiliation (Current)	2025: 大阪大学, 産業科学研究所, 招へい教授
Affiliation (based on the past Project Information) *help	2010: Osaka University, 名誉教授 2008 – 2009: Osaka University, 大学院・理学研究科, 教授 2002: Osaka University, Graduate School of Science, Chemistry, Professor, 大学院・理学研究科, 教授 2000 – 2001: 岡崎国立共同研究機構, 分子科学研究所, 教授 1996: 大阪大学, 大学院・理学研究科, 教授 … More 1995: 大阪大学, 理学部, 教授 1994: 大阪大学, 理学部, 講師 1990: 大阪大学, 理学部, 講師 1987: 大阪大学, 理学部, 助手 Less
Review Section/Research Field	Principal Investigator 物理化学一般 / Physical chemistry / Physical chemistry Except Principal Investigator 物理化学一般
Keywords	Principal Investigator 配向分子線 / 立体ダイナミクス / OHラジカル / レーザー蒸発法 / 立体効果 / サンドイッチクラスター / 化学発光 / Single Ω state OH radical / Hot-hydrogen mechanism on surface reactions / Doppler-selected TOF method … More / [ClDCl] transition state / Electrostatic hexapole method for orienting molecules / Hydrogen bonded (DCl)_2 dimer / Stereodynamics / Effect of molecular orientation / 水素吸蔵金属界面 / ホット原子表面反応 / クラスター光解離 / 六極電場法 / 有機金属クラスター / 水素結合型クラスター / シリコン表面 / シリコンクラスター / 単一Ω状態OHラジカル / 単一W状態OHラジカル / ホット水素表面反応機構 / ドプラー選別飛行時間法 / [ClDCl]遷移状態 / 六極電場配向法 / 水素結合型(DCl)_2二量体 / 分子配向効果 / ビーム法 / ガス / DNO / HNO / fs状態選択 / 六極不均一磁場 / 単一量子状態 / 立体効果の直接観測 / 反応制御 / 分子のアライメント状態選別 / 分子の電子密度 / 偏光レーザー / アライメント選別 / 準安定CO分子ビーム / 衝突錯合体 / 反応分岐 / 配向OH分子ビーム / 反応遷移状態 / 分子配向 / 化学反応 / 集束曲線 / 六極電場 / 電気双極子モーメント / クラスター構造 / クラスタービーム / 立体ダイナミックス / 散乱分布測定 / 反応の異方性 / 分子軌道の広がり / 反応立体化学 / 同位体効果 / アセトニトリル … More Except Principal Investigator クラスター内反応 / Dynamic Spin Polarization / Electron Spin Relaxation / Short-Lived Reaction Intermediate / Process of Molecular Dynamics / Process of Reaction Dynamics / Para magnetic Intermediate / Pulsed FT-ESR / 光解離反応中間体 / 溶媒和電子 / ラジカルイオン対 / 光化学反応中間体 / CIDEP / 電子スピン緩和時間 / 磁場効果 / 励起三重項状態 / 短寿命中間体 / スピン分極の移動 / パルスFTーESR / ラジカル対 / 動的スピン分極 / 電子スピン緩和 / 短寿命反応中間体 / 分子動力学的過程 / 反応動力学的過程 / 常磁性中間体 / パルスFT-ESR / 立体動力学 / 構造異性体選別 / 六極不均一電場 / ホット水素原子 / 第三体効果 / 立体異方性 / 配向分子線 Less

Direct observation of the steric effect in chemical reactions by controlling the orientation at transition statePrincipal Investigator
- Principal Investigator
  
  KASAI Toshio
- Project Period (FY)
  2008 – 2010
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Physical chemistry
- Research Institution
  Osaka University
Stereo-Dynamical Processes of Chemical Reactions Observed by Orienting MoleculesPrincipal Investigator
- Principal Investigator
  
  KASAI Toshio
- Project Period (FY)
  2000 – 2002
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Physical chemistry
- Research Institution
  Osaka University
  Okazaki National Research Institutes
配向分子線法による金属クラスターの生成過程及び構造と反応における立体効果の研究Principal Investigator
- Principal Investigator
  
  笠井俊夫
- Project Period (FY)
  1996 – 1997
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Osaka University
分子内運動状態選別に基づく光誘起クラスター内反応並びに二分子反応の反応制御
- Principal Investigator
  
  大山浩
- Project Period (FY)
  1995
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Osaka University
配向分子線法によるサイドイッチクラスターの構造と反応における立体効果の研究Principal Investigator
- Principal Investigator
  
  笠井俊夫
- Project Period (FY)
  1995
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Osaka University
構造選別に基づく光誘起クラスター内反応における立体効果と第三体効果の検証
- Principal Investigator
  
  大山浩
- Project Period (FY)
  1994
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Osaka University
アセトニトリルの化学励起反応における同位体効果の配向分子線による解明Principal Investigator
- Principal Investigator
  
  笠井俊夫
- Project Period (FY)
  1990
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  物理化学一般
- Research Institution
  Osaka University
Studies on Reaction Dynamics and Molecular Dynamics of Para magnetic Intermediates by Use of Pulsed FT-ESR Method
- Principal Investigator
  
  KUWATA Keiji
- Project Period (FY)
  1990 – 1992
- Research Category
  
  Grant-in-Aid for General Scientific Research (A)
- Research Field
  
  物理化学一般
- Research Institution
  Osaka University
六極不均一磁場により状態選択したNO分子線によるH(D)+NO化学発光の研究Principal Investigator
- Principal Investigator
  
  笠井俊夫
- Project Period (FY)
  1987
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  物理化学一般
- Research Institution
  Osaka University

All 2011 2010 2009 2008

All Journal Article Presentation

[Journal Article] Orientation dependence for Br formation in the reaction of oriented OHradical with HBr molecule2011
- Author(s)
  P.-Y.Tsai, D.-C.Che, M.Nakamura, K.-C.Kin, T.Kasai
- Journal Title
  
  Phys.Chem.Chem Phys. vol.13
  
  Pages: 1419-1423
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Orientation dependence in the four-atom reaction of OH+HBr using the single-state oriented OH radical beam2010
- Author(s)
  P.-Y.Tsai, D.-C.Che, M.Nakamura, K.-C.Lin, T.Kasai
- Journal Title
  
  Phys.Chem.Chem.Phys.,(Communications) vol.12
  
  Pages: 2532-2534
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Steric effects in the scattering of oriented CH_3Cl molecular beam from a Si(111) surface2010
- Author(s)
  H.Ito, M.Okada, D.Yamazaki, T.Kasai
- Journal Title
  
  J.Phys.Chem.A vol.114
  
  Pages: 3080-3086
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] 配向分子線と化学反応2010
- Author(s)
  笠井俊夫
- Journal Title
  
  Journal of the Vacuum Society of Japan
  
  Volume: 11 Pages: 629-634
- NAID
  10027498650
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Temperature dependence of chemical and biophysical rate processes : Phenomenological approach to deviations from Arrhenius law2010
- Author(s)
  V.Aquilanti, K, C.Mundim, M.Elango, S.Kleijn, T.Kasai
- Journal Title
  
  Chem.Phys.Lett. vol.498
  
  Pages: 209-213
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Multi-Dimensional Steric Effect for the XeBr* (B, C) Formation in the Oriented Xe* (3P2,MJ=2)+Oriented CF3Br Reaction2010
- Author(s)
  H.Ohoyama, R.Oda, T.Kasai
- Journal Title
  
  J.Chem.Phys. vol.132
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Molecular Orientation Effects in Gas-Surface Dynamical Processes2010
- Author(s)
  岡田美智雄, 笠井俊夫
- Journal Title
  
  Euro.Phys.J.B vol.75
  
  Pages: 71-79
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Multi-dimensional Steric Effect for the XeI*(B) Formation in the Oriented Xe^*(3P2, MJ=2)+Oriented CH3I Reaction2010
- Author(s)
  H.Ohoyama, T.Kasai
- Journal Title
  
  Phys.Chem.Chem.Phys. vol.12
  
  Pages: 6949-6954
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] TiAl表面酸化のシンクロトロン放射光を用いた光電子分光研究2010
- Author(s)
  橋之口道宏, 角本雄一, 戸出真由美, James Harries, 岡田美智雄, 寺岡有殿, 笠井俊夫
- Journal Title
  
  電気学会誌C 130
  
  Pages: 1723-1729
- NAID
  10026693977
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] 配向分子線と化学反応2010
- Author(s)
  笠井俊夫
- Journal Title
  
  J.Vacuum Sci.Jpn No.11
- NAID
  10027498650
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Electrostatic Hexapole State-Selection of the Asymmetric-Top Molecule Propylene Oxide2010
- Author(s)
  D.-C.Che, F.Palazzetti, Y.Okuno, V.Aquilanti, T.Kasai
- Journal Title
  
  J.Phys.Chem.A. vol.114
  
  Pages: 3280-3286
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] His Arrows and His Targets : A Tribute to Vincenzo Aquilanti2009
- Author(s)
  P.Casavecchia, F.Vecchiocattivi, R.W.Anderson, T.Kasai
- Journal Title
  
  J.Phys.Chem.A Enzo Special Issue vol.113
  
  Pages: 14181-14183
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Cu3Au表面自然酸化のシンクロトロン放射光を用いた光電子分光研究2009
- Author(s)
  宗和誠, 山崎大地, 岡田美智雄, 吉越章隆, 寺岡有殿, 笠井俊夫
- Journal Title
  
  電気学会誌C 129-C
  
  Pages: 229-232
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Kinetics of Oxygen Adsorption and Initial Oxidation on Cu(110) by Hyperthermal Oxygen Molecular Beams2009
- Author(s)
  K.Moritani, M.Okada, Y.Teraoka, A.Yoshigoe, T.Kasai
- Journal Title
  
  J.Phys.Chem.A 113
  
  Pages: 15217-15220
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Steric effects in the scattering of oriented CH_3Cl molecular beam from a graphite surface : weak interaction of physisorption2009
- Author(s)
  T.Fukuyama, M.Okada, T.Kasai
- Journal Title
  
  J.Phys.Chem.A 113
  
  Pages: 14749-14755
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Collision energy dependence for the Br formation in the reaction of OD+HBr2009
- Author(s)
  D.-C.Che, A.Doi, Y.Yamamoto, Y.Okuno, T.Kasai
- Journal Title
  
  Phys.Scr. vol.80
  
  Pages: 48110-48114
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Collision Energy Dependence of the Rotational-State-Resolved Cross Section in the CH(v=0,J)+O_2→OH(A)+CO Reaction2009
- Author(s)
  H.Ohoyama, Y.Nagamachi, K.Yamakawa, T.Kasai
- Journal Title
  
  Phys.Chem.Chem.Phys. vol.11
  
  Pages: 10281-10285
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Steric Effects in Dissociative Adsorption of Low Energy CH_3Cl on Si(100): Orientation and Steering Effects2008
- Author(s)
  M.Okada, S. Goto, T.Kasai
- Journal Title
  
  J.Phys.Chem.C 112
  
  Pages: 19612-19616
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Journal Article] Negative collision energy dependence of the Br formation in the OH+HBr four-atom reaction2008
- Author(s)
  D.-C.Che, T.Matsuo, Y.Yano, L.Bonnet, T.Kasai
- Journal Title
  
  Phys.Chem.Chem.Phys. vol.10
  
  Pages: 1419-1423
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] OH orientation dependence of the OH+HBr reaction2010
- Author(s)
  M.Nakamura, D.-C.Che, P.-Y.Tsai, K.-C.Lin T.Kasai
- Organizer
  第4回化学反応討論会
- Place of Presentation
  広島
- Year and Date
  2010-06-03
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Chemical Reaction Rates Beyond Arrhenius2010
- Author(s)
  V.Aquilanti, K.C.Mundim, T.Kasai
- Organizer
  MOLEC Curia-Anadia
- Place of Presentation
  Portugal
- Year and Date
  2010-09-07
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] OHの配向制御によるOH+HBrの反応機構の解明2010
- Author(s)
  中村雅明、蔡徳七、P.-Y. Tsai, K.-C. Lin, 笠井俊夫
- Organizer
  分子科学討論会2010
- Place of Presentation
  大阪
- Year and Date
  2010-09-17
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] 立体ダイナミクス:化学反応論における意義とその位置づけ2010
- Author(s)
  笠井俊夫
- Organizer
  日本物理学会第65回年次大会
- Place of Presentation
  大阪府立大学中百舌鳥キャンパス大阪
- Year and Date
  2010-03-29
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Stereodynamics : Generic Meaning in Chemical Reactions2010
- Author(s)
  笠井俊夫
- Organizer
  III SEEDMOL, Brasilia-DF
- Place of Presentation
  Brasil
- Year and Date
  2010-10-25
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Stereodynamics : Generic Meaning in Chemical Reactions2010
- Author(s)
  Toshio Kasai
- Organizer
  III SEEDMOL
- Place of Presentation
  Brasil, Brasilia
- Year and Date
  2010-10-21
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Embedded Sign of Stereodynamics in Overall Chemical Reaction2010
- Author(s)
  笠井俊夫
- Organizer
  Stereodynamics Santa Cruz
- Place of Presentation
  米国
- Year and Date
  2010-11-05
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Stereodynamics aiming at ecological reaction control : a bridge to link micro-and macroscopic view of chemical reactions2009
- Author(s)
  笠井俊夫
- Organizer
  NTU/IAMS Joint Special Letcture
- Place of Presentation
  台北(台湾)
- Year and Date
  2009-10-02
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Collision energy dependence of Br atom formation in the OH+HBr and the OD+HBr reactions2009
- Author(s)
  蔡徳七, 奥乃康弘, 笠井俊夫
- Organizer
  第25回化学反応討論会
- Place of Presentation
  大宮
- Year and Date
  2009-06-02
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] 六極不均一電場を用いた非対称コマ分子の回転状態選別2009
- Author(s)
  蔡徳七、奥乃康弘、笠井俊夫
- Organizer
  第3回分子科学討論会
- Place of Presentation
  名古屋
- Year and Date
  2009-09-22
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Stereodynamics : Searching for a bridge to link micro-and macroscopic concepts of chemical reactions2009
- Author(s)
  笠井俊夫
- Organizer
  第25回化学反応討論会
- Place of Presentation
  大宮ソニックシティ(埼玉)
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Stereodynamics : Searching for a bridge to link micro- and macroscopic concepts of chemical reactions2009
- Author(s)
  笠井俊井
- Organizer
  第25回化学反応討論会
- Place of Presentation
  大宮ソニックシティーホール(大宮)
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Stereodynamics : Searching for a bridge to link micro- and macroscopic concepts of chemical reactions2009
- Author(s)
  笠井俊夫
- Organizer
  第25回化学反応討論会
- Place of Presentation
  大宮
- Year and Date
  2009-06-02
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Dynamics of the OH+HBr four-atom reaction by using electrostatic hexapole state-selection and VUV-LIF product detection2008
- Author(s)
  D.-C.CHE, T.Kasai
- Organizer
  XVII MOLEC European Conferece on Dynamics of Molecular Systems
- Place of Presentation
  Russia, St.Petersburg
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Dynamics of the OH+HBr four-atom reaction by using electrostatic hexapole state-selection and VUV-LIF product detection2008
- Author(s)
  蔡徳七, 笠井俊夫
- Organizer
  XVII MOLEC European Conferece on Dynamics of Molecular Systems
- Place of Presentation
  Russia, St. Petersburg
- Year and Date
  2008-08-26
- Data Source
  KAKENHI-PROJECT-20350006
[Presentation] Stereodynamics of Chemical Reactions in Heterogeneous Systems : Dissociative Adsorption of NO on Si(111)2008
- Author(s)
  M.Hashinokuchi, M.Okada, H.Ito, T.Kasai, K.Moritani, Y.Teraoka
- Organizer
  Stereodynamics
- Place of Presentation
  大連China
- Year and Date
  2008-11-03
- Data Source
  KAKENHI-PROJECT-20350006

1. 大山浩 (60192522)

# of Collaborated Projects: 4 results

# of Collaborated Products: 0 results
2. CHE DockーChil (20273732)

# of Collaborated Projects: 3 results

# of Collaborated Products: 11 results
3. KUWATA Keiji (50028099)

# of Collaborated Projects: 3 results

# of Collaborated Products: 0 results
4. OKADA Michio (30281116)

# of Collaborated Projects: 2 results

# of Collaborated Products: 0 results
5. MURAI Hisao (50142261)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
6. KAMACHI Mikiharu (40028163)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results

KASAI TOSHIO 笠井 俊夫

KASAI Toshio 笠井 俊夫

笠井 俊夫 カサイ トシオ

Research Projects

Research Products

Co-Researchers

Direct observation of the steric effect in chemical reactions by controlling the orientation at transition statePrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Stereo-Dynamical Processes of Chemical Reactions Observed by Orienting MoleculesPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

配向分子線法による金属クラスターの生成過程及び構造と反応における立体効果の研究Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

分子内運動状態選別に基づく光誘起クラスター内反応並びに二分子反応の反応制御

Principal Investigator

Project Period (FY)

Research Category

Research Institution

配向分子線法によるサイドイッチクラスターの構造と反応における立体効果の研究Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

構造選別に基づく光誘起クラスター内反応における立体効果と第三体効果の検証

Principal Investigator

Project Period (FY)

Research Category

Research Institution

アセトニトリルの化学励起反応における同位体効果の配向分子線による解明Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Studies on Reaction Dynamics and Molecular Dynamics of Para magnetic Intermediates by Use of Pulsed FT-ESR Method

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

六極不均一磁場により状態選択したNO分子線によるH(D)+NO化学発光の研究Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] Orientation dependence for Br formation in the reaction of oriented OHradical with HBr molecule2011

Author(s)

Journal Title

Data Source

[Journal Article] Orientation dependence in the four-atom reaction of OH+HBr using the single-state oriented OH radical beam2010

Author(s)

Journal Title

Data Source

[Journal Article] Steric effects in the scattering of oriented CH_3Cl molecular beam from a Si(111) surface2010

Author(s)

Journal Title

Data Source

[Journal Article] 配向分子線と化学反応2010

Author(s)

Journal Title

NAID

Data Source

[Journal Article] Temperature dependence of chemical and biophysical rate processes : Phenomenological approach to deviations from Arrhenius law2010

Author(s)

Journal Title

Data Source

[Journal Article] Multi-Dimensional Steric Effect for the XeBr* (B, C) Formation in the Oriented Xe* (3P2,MJ=2)+Oriented CF3Br Reaction2010

Author(s)

Journal Title

KASAI TOSHIO 笠井俊夫

KASAI Toshio 笠井俊夫

笠井俊夫カサイトシオ

[Journal Article] Multi-dimensional Steric Effect for the XeI(B) Formation in the Oriented Xe^(3P2, MJ=2)+Oriented CH3I Reaction2010