KAKUSAWA Naoki 角澤直紀

… Alternative Names

角沢直紀カクサワナオキ

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Researcher Number	20185721
Other IDs
Affiliation (based on the past Project Information) *help	2007: Hokuriku University, Faculty of Pharmaceutical Sciences, Research Associate 2005 – 2006: 北陸大学, 薬学部, 助手 2001 – 2003: 北陸大学, 薬学部, 助手 1989 – 1990: 北陸大学, 薬学部, 助手
Review Section/Research Field	Except Principal Investigator Chemical pharmacy / Chemical pharmacy / Science and Engineering
Keywords	Except Principal Investigator アンチモン / 超原子価結合 / MASb / BINAPSb / BINASb / 不斉触媒配位子 / Sb-キラル化合物 / クロスカップリング反応 / Transition-metal Catalyst / N-Arylation … More / Reduction / Cross-coupling / 1, 5-Azastibocine / Sb-N Trans-annular Interaction / Hypervalent Compounds / Antimony / 触媒的還元 / マイクロウェーブ / O-アリール化 / ペンタアリールアンチモン / 高配位アンチモン化合物 / 遷移金属触媒反応 / N-アリール化 / アンチモン(V)化合物 / クロスカップリング / 1,5-アザスチボシン / Sb-N渡環相互作用 / 高原子価アンチモン化合物 / Asymmetric hydrosilylation / Asymmetric alkylation / Asymmetric Reaction / Optical Resolution / Optically Active Organoantimony / dinaphtho[2,1-b;1',2'-d]heterole / 2,2'-bis(diarylbismutho)binaphtyl / 2,2'-bis(diarylstibano)binaphthyl / C_2-軸不再 / オキサゾリン / 不斉誘導反応 / 不斉配位子 / C2-軸不斉 / パラジウム触媒 / 不斉ヒドロシリル化 / 不斉アルキル化 / 不斉反応触媒配位子 / 光学分割 / 光学活性アンチモン化合物 / ring transformation / eight-membered heterocyclic ring / seven-membered heterocyclic ring / synthesis of heterocyclic ring compound / rearrangement / valence isomerization / highly strained compound / オキシアゼピン / ジアゼピン / チエピン / オキセピン / アゼピン / 高眞空瞬間熱反応 / 原子価異性化 / 環変換 / 多環縮合複素環 / 8員複素環 / 7員複素環 / 複素環化合物の合成 / 転位反応 / 原子位異性化 / 高ひずみ化合物 / 還元反応 / 超原子化結合 / 複素環 / 遷移金属触媒 / 有機合成化学 / benzo-2,1-aza-λ^4-stibolane / 還元 / 1,5-azastibocine / 渡環相互作用 Less

Synthesis of Hypervalent Organoantimony Compounds and Their Utilization for Organic Synthesis
- Principal Investigator
  
  KURITA Jyoji
- Project Period (FY)
  2005 – 2007
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Chemical pharmacy
- Research Institution
  Hokuriku University
超原子価結合を持つ新規な第15族重元素複素環の合成とその有機合成試薬としての活用
- Principal Investigator
  
  KURITA Jyoji (栗田城治)
- Project Period (FY)
  2002 – 2003
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Review Section
  
  Science and Engineering
- Research Institution
  Hokuriku University
Synthesis of Optically Active Orgnoantimony Compounds and Their Application for Asymmetric Reactions
- Principal Investigator
  
  KURITA Jyoji
- Project Period (FY)
  2001 – 2003
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Chemical pharmacy
- Research Institution
  Hokuriku University
Applications of the Isomerizations of Highly Strained Molecules to the Synthesis of Heterocycles
- Principal Investigator
  
  TSUCHIYA Takashi
- Project Period (FY)
  1989 – 1990
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  Chemical pharmacy
- Research Institution
  Hokuriku University

All 2008 2007 2006 2005 2003 2002

All Journal Article Presentation

[Journal Article] Triarylantimony dicarboxylates as pseudo-halides for palladium-catalyzed cross-coupling reaction with arylboronic acids and triarylbismuthanes without any base2008
- Author(s)
  W. Qin, S. Yasuike, N. Kakusawa, Y. Sugawara, M. Kawahata, K. Yamaguchi, J. Kurita
- Journal Title
  
  Journal of Organometallic Chemistry 693
  
  Pages: 109-116
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Carbonylative cross-coupling reaction of ethynylstibane with aryl iodides2006
- Author(s)
  N.Kakusawa, J.Kurita
- Journal Title
  
  Chem. Pharm. Bull. 54(5)
  
  Pages: 699-702
- NAID
  110004836357
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Hypervalent organoantimony compounds 12-ethynyltetrahydrodibenzo-[c,f][1,5]azastibocines : Highly efficient new transmetallating agent for organic halides2006
- Author(s)
  N.Kakusawa, Y.Tobiyasu, S.Yasuike, K.Yamaguchi, H.Seki, J.Kurita
- Journal Title
  
  J. Organomet. Chem. 691
  
  Pages: 2953-2968
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Hypervalent organoantimony compound 12-aryltetrahydrodibenzo[c,f][1,5]azastibocine : new transmetallating agent for palladiumcatalyzed arylation of organic halides2006
- Author(s)
  N.kakusawa, J.kurita
- Journal Title
  
  Heterocycles (accepted)
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Carbonylative cross-coupling reaction of ethynylstibane with aryl iodides2006
- Author(s)
  N.Kakusawa, J.Kurita
- Journal Title
  
  Chem.Pharm Bull. (in press)
- NAID
  110004836357
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Hypervalent Organoantimony compounds 12-Ethynyltetrahydrodibenzo-[c,f][1,5]azastibocines : hyly efficient new transmetallating agent for organic halides2006
- Author(s)
  N.Kakusawa, Y.Tobiyasu, S.Yasuike, K.Yamaguchi, H.Seki, J.Kurita
- Journal Title
  
  J.Organomet.Chem. (in press)
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Hypervalent organoantimony compound 12-aryltetrahydrodibenzo-[c, f][1,5]azastibocine : New transmetallating agent for palladium-catalyzed arylation of organic halides2006
- Author(s)
  N.kakusawa, J.kurita
- Journal Title
  
  Heterocycles 68(7)
  
  Pages: 1335-1348
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Palladium-catalyzed Cross-coupling Reaction of Ethynylstibanes with Organic Halides2005
- Author(s)
  N.Kakusawa, K.Yamaguchi, J.Kurita
- Journal Title
  
  J.Organomet.Chem. (in press)
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-13672242
[Journal Article] Microwave assisted cross-coupling reaction of alkynylstibanes with aryl iodides in the presence of ammonium salt2005
- Author(s)
  N.Kakusawa, J.Kurita
- Journal Title
  
  Chem.Pharm.Bull. 53
  
  Pages: 1369-1371
- NAID
  110003666282
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Palladium Catalyzed cross-coupling reaction of ethynylstibanes with organic halides2005
- Author(s)
  N.Kakusawa, K.Yamaguchi, J.Kurita
- Journal Title
  
  J.Organomet.Chem. 690
  
  Pages: 2956-2966
- Data Source
  KAKENHI-PROJECT-17590022
[Journal Article] Pallladium-catalyzed Cross-coupling Reaction of Ethynylstibanes with Organic Halides2005
- Author(s)
  N.Kakusawa, K.Yamaguchi, J.Kurita
- Journal Title
  
  J.Organomet.Chem. (in press)
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-13672242
[Journal Article] Remarkable Reactivity Enhancement with Sb---N Inter-coordination of Ethynyl-1,5-azastibocine in Pd-catalyzed Cross-coupling Reaction with Organic Halides2003
- Author(s)
  N.Kakusawa, Y.Tobiyasu, S.Yasuike, K.Yamaguchi, H.Seki, J.Kurita
- Journal Title
  
  Tetrahedron Lett. 44
  
  Pages: 8589-8589
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-13672242
[Journal Article] Synthesis of Sb-chiral organoantimony compounds having intramolecular Sb---N interaction and their separation into optically pure compounds via ortho-palladated benzylamine complexes2002
- Author(s)
  S.Okajima, S.Yasuike, N.Kakusawa, A.Osada, K.Yamaguchi, H.Seki, J.Kurita
- Journal Title
  
  J.Organomet.Chem. 656
  
  Pages: 234-234
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-13672242
[Journal Article] Synthesis of Sb-chiral organoantimony compounds having intramolecular Sb---N interaction and their separation into optically pure compounds via ortho-palladated benzylamine complexes2002
- Author(s)
  Okajima, S., Yasuike, S., Kakusawa, N., Osada, A., Yamaguchi, K., Seki, H., Kurita, J.
- Journal Title
  
  J.Organomet.Chem. 656
  
  Pages: 234-242
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-13672242
[Presentation] Rhodium catalyzed 1,4-conjugated addition of Sb-aryl-1,5-azastibocines to a,b-unsaturated carbonyl compounds2007
- Author(s)
  Naoki Kakusawa
- Organizer
  21st International congress for heterocyclic chemistry
- Place of Presentation
  オーストラリア(シドニー)
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-17590022
[Presentation] トリアリールスチバンとエノン類とのロジウム触媒による1,4-付加反応2007
- Author(s)
  角澤直紀
- Organizer
  日本薬学会北陸支部第116回例会
- Place of Presentation
  金沢
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-17590022
[Presentation] Rh-catalyzed 1, 4-conjugated addition with organoantimony compounds2007
- Author(s)
  Kakusawa Naoki
- Organizer
  The 34th Symposium on Main Group Element Chemistry
- Place of Presentation
  Osaka
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-17590022
[Presentation] ロジウム触媒による有機アンチモン化合物のエノン類への1,4-共役付加反応2007
- Author(s)
  角澤直紀
- Organizer
  第34回有機典型元素化学討論会
- Place of Presentation
  大阪
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-17590022
[Presentation] Rhodium catalyzed 1, 4-conjugated addition of Sb-aryl-1, 5-azastibocines toa, b-unsaturated carbonyl compounds2007
- Author(s)
  Naoki Kakusawa, Jyoji Kurita
- Organizer
  21st International congress for heterocyclic chemistry
- Place of Presentation
  オーストラリア(シドニー)
- Data Source
  KAKENHI-PROJECT-17590022
[Presentation] Rh-catalyzed 1, 4-conjugated addition of Triarylstibanes to α, β-unsaturated carbonyl compounds2007
- Author(s)
  Kakusawa Naoki
- Organizer
  116th Conference of Japanese Pharmaceu-tical Society, Hokuriku Branch
- Place of Presentation
  Kanazawa
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-17590022
[Presentation] Rh-catalyzed 1, 4-conjugated addition of Sb-aryl-1, 5-aza-stibocines to α, β-unsaturated carbonyl compounds2007
- Author(s)
  Kakusawa Naoki
- Organizer
  21st International Congress for Hetero-cyclic Chemistry
- Place of Presentation
  Australia(Sydney)
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-17590022
[Presentation] 1,5-アザスチボシンを用いたエノン類への触媒的1,4-付加反応2007
- Author(s)
  角澤直紀
- Organizer
  日本薬学会第127年会
- Place of Presentation
  富山
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-17590022
[Presentation] Catalytic 1, 4-conjugated addition of 1, 5-azastibocines to enones2007
- Author(s)
  Kakusawa Naokii
- Organizer
  127th Conference of Japanese Pharmaceu-tical Society
- Place of Presentation
  Toyama
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-17590022

1. KURITA Jyoji (80100494)

# of Collaborated Projects: 4 results

# of Collaborated Products: 15 results
2. TSUCHIYA Takashi (20100505)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
3. YASUIKE Shuji (10230210)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results

KAKUSAWA Naoki 角澤 直紀

角沢 直紀 カクサワ ナオキ

Research Projects

Research Products

Co-Researchers

Synthesis of Hypervalent Organoantimony Compounds and Their Utilization for Organic Synthesis

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

超原子価結合を持つ新規な第15族重元素複素環の合成とその有機合成試薬としての活用

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Synthesis of Optically Active Orgnoantimony Compounds and Their Application for Asymmetric Reactions

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Applications of the Isomerizations of Highly Strained Molecules to the Synthesis of Heterocycles

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] Triarylantimony dicarboxylates as pseudo-halides for palladium-catalyzed cross-coupling reaction with arylboronic acids and triarylbismuthanes without any base2008

Author(s)

Journal Title

Data Source

[Journal Article] Carbonylative cross-coupling reaction of ethynylstibane with aryl iodides2006

Author(s)

Journal Title

NAID

Data Source

[Journal Article] Hypervalent organoantimony compounds 12-ethynyltetrahydrodibenzo-[c,f][1,5]azastibocines : Highly efficient new transmetallating agent for organic halides2006

Author(s)

Journal Title

Data Source

[Journal Article] Hypervalent organoantimony compound 12-aryltetrahydrodibenzo[c,f][1,5]azastibocine : new transmetallating agent for palladiumcatalyzed arylation of organic halides2006

Author(s)

Journal Title

Data Source

[Journal Article] Carbonylative cross-coupling reaction of ethynylstibane with aryl iodides2006

Author(s)

Journal Title

NAID

Data Source

[Journal Article] Hypervalent Organoantimony compounds 12-Ethynyltetrahydrodibenzo-[c,f][1,5]azastibocines : hyly efficient new transmetallating agent for organic halides2006

Author(s)

Journal Title

Data Source

[Journal Article] Hypervalent organoantimony compound 12-aryltetrahydrodibenzo-[c, f][1,5]azastibocine : New transmetallating agent for palladium-catalyzed arylation of organic halides2006

Author(s)

Journal Title

Data Source

[Journal Article] Palladium-catalyzed Cross-coupling Reaction of Ethynylstibanes with Organic Halides2005

Author(s)

Journal Title

Description

Data Source

[Journal Article] Microwave assisted cross-coupling reaction of alkynylstibanes with aryl iodides in the presence of ammonium salt2005

Author(s)

Journal Title

NAID

Data Source

[Journal Article] Palladium Catalyzed cross-coupling reaction of ethynylstibanes with organic halides2005

Author(s)

Journal Title

Data Source

[Journal Article] Pallladium-catalyzed Cross-coupling Reaction of Ethynylstibanes with Organic Halides2005

Author(s)

Journal Title

Description

Data Source

[Journal Article] Remarkable Reactivity Enhancement with Sb---N Inter-coordination of Ethynyl-1,5-azastibocine in Pd-catalyzed Cross-coupling Reaction with Organic Halides2003

Author(s)

KAKUSAWA Naoki 角澤直紀

角沢直紀カクサワナオキ