TSUBOUCHI Akira 坪内彰

Researcher Number	40272637
Other IDs
Affiliation (Current)	2025: 東京農工大学, 工学(系)研究科(研究院), 助教
Affiliation (based on the past Project Information) *help	2025: 東京農工大学, 工学(系)研究科(研究院), 助教 2011 – 2016: 東京農工大学, 工学(系)研究科(研究院), 助教 2007 – 2008: Tokyo University of Agriculture and Technology, 大学院・共生科学技術研究院, 助教 2004: National University Corporation Tokyo University of Agriculture and Technology, Institute of Symbiotic Science and Technology, Research Associate, 大学院・共生科学技術研究部, 助手 2002 – 2003: 東京農工大学, 工学部, 助手 1999 – 2000: 東京農工大学, 工学部, 助手
Review Section/Research Field	Principal Investigator Synthetic chemistry / Organic chemistry / Basic Section 33020:Synthetic organic chemistry-related Except Principal Investigator 物質変換 / Synthetic chemistry
Keywords	Principal Investigator エノールシリルエーテル / シリカート / クロスカップリング / 三成分連結反応 / 共役付加 / アルケニル銅 / アリール銅 / 銅エノラート / シリル転位 / Enol Silyl Ether … More / Allenes / Silicate / Vinylcopper / Peterson Elimination / Silyl Migration / Brook転移 / アリル化 / Brook転位 / アレン / ビニル銅 / Peterson脱離 / ジオール / 触媒・化学プロセス / 銅(I)アルコキシド / 環状シリカート / 有機銅化合物 / ケイ素化合物 / 有機銅 / 触媒反応 / ケイ素転位 / 炭素-炭素結合形成反応 / 炭素-炭素結合形成 … More Except Principal Investigator Polyacetylene / Reductive Alkylation / Cyclopropanation / Carbonyl Olefination / Alkyltitaniums / Carbene Complexes / Alkyl Halides / Thioacetals / β-置換スチレン / 末端オレフィン / アルキニルシクロプロ / マルチカルベン錯体 / エノールエーテル / アレン / アルキニルシクロプロパン / アシル化 / 共役ジエン / ビニルアレン / 二価チタノセン / チタン-カルベン錯体 / ポリアセチレン / 還元的アルキル化 / シクロプロパン化 / カルボニル・オレフィン化 / アルキルチタン / カルベン錯体 / ハロゲン化アルキル / チオアセタール / Hydrolysis / Imidazole / Histidine / Functional Material / Complex / Peptide / Hydroxamic Acid / 加水分解 / イミダゾール / ヒスチジン / 機能物質 / 錯体 / ペプチド / ヒドロキサム酸 Less

分子状ヨウ素とハロゲン結合の協働触媒を利用した官能基化複素環構築法Principal Investigator
- Principal Investigator
  
  坪内彰
- Project Period (FY)
  2025 – 2027
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Review Section
  
  Basic Section 33020:Synthetic organic chemistry-related
- Research Institution
  Tokyo University of Agriculture and Technology
Copper(I)-Catalized Cross-Coupling of Organosilicon Compounds Utilizing Fluoride Ion Free ActivatorsPrincipal Investigator
- Principal Investigator
  
  TSUBOUCHI Akira
- Project Period (FY)
  2014 – 2016
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Organic chemistry
- Research Institution
  Tokyo University of Agriculture and Technology
Stereoselective Preparation of Enol Silyl Ethers via Formation of Vinylcopper Species by Silyl MigrationPrincipal Investigator
- Principal Investigator
  
  TSUBOUCHI Akira
- Project Period (FY)
  2011 – 2013
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Tokyo University of Agriculture and Technology
Generation of Functionalized Organometallic Compounds by Controlling the Reactivity of Silicates Coordinated with Transition Metal EnolatesPrincipal Investigator
- Principal Investigator
  
  TSUBOUCHI Akira
- Project Period (FY)
  2007 – 2008
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Organic chemistry
- Research Institution
  Tokyo University of Agriculture and Technology
Preparation of Organocupper Species Using Silyl Migration and Their Application to Organic SynthesisPrincipal Investigator
- Principal Investigator
  
  TSUBOUCHI Akira
- Project Period (FY)
  2003 – 2004
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Synthetic chemistry
- Research Institution
  National University Corporation Tokyo University of Agriculture and Technology
Exploration of Unique Reactivity of Organotitanocene Complexes and Its Application to Organic Synthesis
- Principal Investigator
  
  TAKEDA Takeshi
- Project Period (FY)
  2002 – 2004
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  物質変換
- Research Institution
  National University Corporation Tokyo University of Agriculture and Technology
Structural Arrangement Functional Group Disposition of Artificial Peptide Hydroxamate Ligands by Complex Formation with Metal Ions
- Principal Investigator
  
  AKIYAMA Masayasu
- Project Period (FY)
  1999 – 2000
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Synthetic chemistry
- Research Institution
  TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY

All 2015 2014 2013 2012 2011 2009 2008 2004 2002 Other

All Journal Article Presentation

[Journal Article] Cross-coupling between Aryl- and Alkenyldimethylsilanes and Organic Halides Promoted by a Copper(I) Iodide/Sodium Hydride/Ethylene Glycol System2015
- Author(s)
  Takeshi Takeda, Yuichiro Takeda, Akira Tsubouchi
- Journal Title
  
  Chem. Lett.
  
  Volume: 44 Issue: 6 Pages: 809-811
- DOI
  10.1246/cl.150171
- NAID
  130005074584
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-26410037
[Journal Article] Copper(i) 2-Hydroxyethoxide-promoted Cross-coupling of Aryl- and Alkenyldimethylsilanes with Organic Halides2014
- Author(s)
  Takeshi Takeda, Ryosuke Obata, Daisuke Muramatsu, Yuichiro Takeda, Akira Tsubouchi
- Journal Title
  
  Chem. Commun.
  
  Volume: 50 Issue: 96 Pages: 15156-15158
- DOI
  10.1039/c4cc07371a
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-26410037
[Journal Article] Diversity-Oriented Stereoselective Synthesis of β,γ-Disubstituted tert -Homoallylic Alcohols2014
- Author(s)
  Takeshi Takeda, Sota Amarume, Ippei Sekioka, Akira Tsubouchi
- Journal Title
  
  Org. Lett.
  
  Volume: 17 Issue: 5 Pages: 1150-1153
- DOI
  10.1021/acs.orglett.5b00084
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-26410037
[Journal Article] Diversity Oriented Synthesis of Conjugate Dienes and AlkenylCyclopropanes Utilizing Silyl Group-substituted Titanium Carbene Complexes as Bimetallic Synthetic Reagents2014
- Author(s)
  Takeshi Takeda, Ayako Mori, Tomoya. Fujii, Akira Tsubouchi
- Journal Title
  
  Tetrahedron
  
  Volume: 70 Issue: 35 Pages: 5776-5786
- DOI
  10.1016/j.tet.2014.06.043
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-26410037
[Journal Article] Copper(I)-Promoted Alkylation of Alkenylbenzyldimethylsilanes2014
- Author(s)
  Takeshi Takeda, Ryo Matsumura, Hideki Wasa, Akira Tsubouchi
- Journal Title
  
  Asian J. Org. Chem.
  
  Volume: 3 Issue: 8 Pages: 838-841
- DOI
  10.1002/ajoc.201402060
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-26410037
[Journal Article] Regio- and stereoselective preparation of (Z)-silyl enol ethers by three-component coupling using α,β-unsaturated acylsilanes as core building blocks2013
- Author(s)
  Akira Tsubouchi
- Journal Title
  
  Tetrahedron Letters
  
  Volume: 54 Issue: 10 Pages: 1264-1267
- DOI
  10.1016/j.tetlet.2012.12.089
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-23550118
[Journal Article] Copper(I)-Catalyzed Alkylation of Aryl- and Alkenylsilanes Activated by Intramolecular Coordination of an Alkoxide2013
- Author(s)
  Akira Tsubouchi, Daisuke Muramatsu, Takeshi Takeda,
- Journal Title
  
  Angew. Chem. Int. Ed.
  
  Volume: 52 Issue: 48 Pages: 12719-12722
- DOI
  10.1002/anie.201306882
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-23550118
[Journal Article] Titanocene(II)-promoted Reaction of Thioacetals with Styrenes : Stereoselective Formation of (E)-β-Substituted Styrene Derivatives2004
- Author(s)
  Akira Tsubouchi
- Journal Title
  
  Lett.Org.Chem. 1-4
  
  Pages: 357-359
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-14340228
[Journal Article] Titanocene(II)-promoted Reaction of Thioacetals with Styrenes : Stereoselective Formation of (E)-β-Substituted Styrene Derivatives2004
- Author(s)
  Akira Tsubouchi
- Journal Title
  
  Lett.Org.Chem. 1・4
  
  Pages: 357-359
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-14340228
[Journal Article] Copper(I) tert-Butoxide-Promoted Allylation of β-Triphenylsilyl Allylic Alcophols via 1,3-C^<sp2>-to-O Silyl Migration2004
- Author(s)
  Akira Tsubouchi
- Journal Title
  
  Synthesis
  
  Pages: 1504-1508
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15550085
[Journal Article] Copper(I) tert-Butoxide-Promoted Allylation of β-Triphenylsilyl Allylic Alcophols via 1,3-C^<sp2>-to-0 Silyl Migration2004
- Author(s)
  Akira Tsubouchi
- Journal Title
  
  Synthesis
  
  Pages: 1504-1508
- Data Source
  KAKENHI-PROJECT-15550085
[Journal Article] Titanocene(II)-promoted reactions of thioacetals with ethylene : selective formation of terminal olefins with one- or two-carbon homologation2002
- Author(s)
  Akira Tsubouchi
- Journal Title
  
  Tetrahedron Lett. 43・33
  
  Pages: 5755-5758
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-14340228
[Journal Article] Titanocene(II)-promoted reactions of thioacetals with ethylene : selective formation of terminal olefms with one-or two-carbon homologation2002
- Author(s)
  Akira Tsubouchi
- Journal Title
  
  Tetrahedron Lett. 43-33
  
  Pages: 5755-5758
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-14340228
[Presentation] チタンカルベン錯体とホモプロパルギルアルコールび反応による共役ジエンの位置および立体選択的合成2014
- Author(s)
  武田　猛、森　綾子、坪内　彰
- Organizer
  日本化学会　第94　春季年会
- Place of Presentation
  名古屋大学東山キャンパス（愛知県）
- Data Source
  KAKENHI-PROJECT-23550118
[Presentation] 銅(I)塩により促進されるアリールおよびアルケニルジメチルシランのアルコキシド化を経由するクロスカップリング2014
- Author(s)
  武田猛, 村松大輔, 小幡亮介, 坪内彰
- Organizer
  日本化学会第94春季年会
- Place of Presentation
  名古屋大学東山キャンパス(愛知県)
- Year and Date
  2014-03-29
- Data Source
  KAKENHI-PROJECT-23550118
[Presentation] 銅(I)塩により促進されるアリール及びアルケニルジメチルシランのアルコキシド化を経由するクロスカップリング2014
- Author(s)
  武田　猛、村松大輔、小幡　亮介、坪内　彰
- Organizer
  日本化学会　第94　春季年会
- Place of Presentation
  名古屋大学東山キャンパス（愛知県）
- Data Source
  KAKENHI-PROJECT-23550118
[Presentation] 環状シリカートを経由するアルケニルおよびアリールシランの銅(I)塩による触媒的アルキル化2013
- Author(s)
  村松大輔, 坪内彰, 武田猛
- Organizer
  日本化学会第93春季年会
- Place of Presentation
  立命館大学びわこ・くさつキャンパス(滋賀県)
- Year and Date
  2013-03-24
- Data Source
  KAKENHI-PROJECT-23550118
[Presentation] ケイ素置換アリルチタノセンを用いた第三級ホモアリルアルコールの合成2013
- Author(s)
  松村　遼、餘目草太、和佐英樹、関岡一平、坪内　彰、武田　猛
- Organizer
  第60回　有機金属化学討論会
- Place of Presentation
  学習院大学（東京都豊島区）
- Data Source
  KAKENHI-PROJECT-23550118
[Presentation] ケイ素置換アリルチタノセンを用いた第三級ホモアリルアルコールの合成2013
- Author(s)
  松村遼, 餘目草太, 和佐英樹, 関岡一平, 坪内彰, 武田猛
- Organizer
  第60回有機金属化学討論会
- Place of Presentation
  学習院大学(東京都豊島区)
- Year and Date
  2013-09-13
- Data Source
  KAKENHI-PROJECT-23550118
[Presentation] 銅(I)アルコキシドの分子内配位により促進されるアルケニルシランとハロゲン化アルキルとのクロスカップリング2012
- Author(s)
  村松大輔, 坪内彰, 武田猛
- Organizer
  日本化学会第92春季年会
- Place of Presentation
  慶応大学日吉・矢上キャンパス(神奈川県)
- Year and Date
  2012-03-26
- Data Source
  KAKENHI-PROJECT-23550118
[Presentation] ケイ素転位を鍵とするα, β-不飽和アシルシラン, 有機金属試薬, 有機ハロゲン化物の三成分連結反応によるエノールシリルエーテルの立体選択的合成2011
- Author(s)
  佐々木なつき, 江夏晶子, 坪内彰, 武田猛
- Organizer
  第58回有機金属化学討論会
- Place of Presentation
  名古屋大学東山キャンパス(愛知県)
- Year and Date
  2011-09-08
- Data Source
  KAKENHI-PROJECT-23550118
[Presentation] ケイ素置換不飽和ケトン・有機銅試薬・有機ハロゲン化物の三成分連結反応による立体選択的エノールシリルエーテル合成2009
- Author(s)
  坪内彰
- Organizer
  日本化学会第89春季年会
- Place of Presentation
  千葉県船橋市
- Year and Date
  2009-03-30
- Data Source
  KAKENHI-PROJECT-19550032
[Presentation] ケイ素置換不飽和ケトン・有機銅試薬・有機ハロゲン化物の三成分連結反応による立体選択的ェノールシリルェーテル合成2009
- Author(s)
  坪内彰
- Organizer
  日本化学会第89春季年会
- Place of Presentation
  千葉県船橋市
- Year and Date
  2009-03-30
- Data Source
  KAKENHI-PROJECT-19550032
[Presentation] マイケル付加で生成するエノラートへのケイソ転位を利用する三成分連結反応2008
- Author(s)
  坪内彰
- Organizer
  第55回有機金属化学討論会
- Place of Presentation
  大阪府堺市
- Year and Date
  2008-09-30
- Data Source
  KAKENHI-PROJECT-19550032
[Presentation] マイケル付加で生成するエノラートへのケイ素転位を利用する三成分連結反応2008
- Author(s)
  坪内彰
- Organizer
  第55回有機金属化学討論会
- Place of Presentation
  大阪府堺市
- Year and Date
  2008-09-30
- Data Source
  KAKENHI-PROJECT-19550032
[Presentation] 不飽和チタンーカルベン錯体とビニルボラン及びビニルシランの反応
- Author(s)
  武田　猛、寺元佑蔵、井上雄太、坪内　彰、
- Organizer
  日本化学会第95春季年会
- Place of Presentation
  日本大学船橋キャンパス（千葉）
- Year and Date
  2015-03-26 – 2015-03-29
- Data Source
  KAKENHI-PROJECT-26410037
[Presentation] ヨウ化銅(I)ー水素化ナトリウムーエチレングリコール系により促進されるアリールおよびアルケニルシランのクロスカップリング
- Author(s)
  武田　猛、武田有一郎、坪内　彰
- Organizer
  日本化学会第95春季年会
- Place of Presentation
  日本大学船橋キャンパス（千葉）
- Year and Date
  2015-03-26 – 2015-03-29
- Data Source
  KAKENHI-PROJECT-26410037

1. TAKEDA Takeshi (40111455)

# of Collaborated Projects: 2 results

# of Collaborated Products: 0 results
2. AKIYAMA Masayasu (20016728)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results

TSUBOUCHI Akira 坪内 彰

Research Projects

Research Products

Co-Researchers

分子状ヨウ素とハロゲン結合の協働触媒を利用した官能基化複素環構築法Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Copper(I)-Catalized Cross-Coupling of Organosilicon Compounds Utilizing Fluoride Ion Free ActivatorsPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Stereoselective Preparation of Enol Silyl Ethers via Formation of Vinylcopper Species by Silyl MigrationPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Generation of Functionalized Organometallic Compounds by Controlling the Reactivity of Silicates Coordinated with Transition Metal EnolatesPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Preparation of Organocupper Species Using Silyl Migration and Their Application to Organic SynthesisPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Exploration of Unique Reactivity of Organotitanocene Complexes and Its Application to Organic Synthesis

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Structural Arrangement Functional Group Disposition of Artificial Peptide Hydroxamate Ligands by Complex Formation with Metal Ions

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] Cross-coupling between Aryl- and Alkenyldimethylsilanes and Organic Halides Promoted by a Copper(I) Iodide/Sodium Hydride/Ethylene Glycol System2015

Author(s)

Journal Title

DOI

NAID

Data Source

[Journal Article] Copper(i) 2-Hydroxyethoxide-promoted Cross-coupling of Aryl- and Alkenyldimethylsilanes with Organic Halides2014

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Diversity-Oriented Stereoselective Synthesis of β,γ-Disubstituted tert -Homoallylic Alcohols2014

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Diversity Oriented Synthesis of Conjugate Dienes and AlkenylCyclopropanes Utilizing Silyl Group-substituted Titanium Carbene Complexes as Bimetallic Synthetic Reagents2014

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Copper(I)-Promoted Alkylation of Alkenylbenzyldimethylsilanes2014

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Regio- and stereoselective preparation of (Z)-silyl enol ethers by three-component coupling using α,β-unsaturated acylsilanes as core building blocks2013

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Copper(I)-Catalyzed Alkylation of Aryl- and Alkenylsilanes Activated by Intramolecular Coordination of an Alkoxide2013

Author(s)

Journal Title

TSUBOUCHI Akira 坪内彰