Kawamura Shintaro 河村伸太郎

Researcher Number	60732956
Other IDs	https://orcid.org/0000-0002-7422-837X
Affiliation (Current)	2025: 国立研究開発法人理化学研究所, 環境資源科学研究センター, 上級研究員
Affiliation (based on the past Project Information) *help	2021 – 2024: 国立研究開発法人理化学研究所, 環境資源科学研究センター, 上級研究員 2016 – 2017: 国立研究開発法人理化学研究所, 環境資源科学研究センター, 研究員 2015: 国立研究開発法人理化学研究所, 環境資源科学研究センター, 特別研究員
Review Section/Research Field	Principal Investigator Basic Section 47010:Pharmaceutical chemistry and drug development sciences-related / Synthetic chemistry Except Principal Investigator Basic Section 37030:Chemical biology-related
Keywords	Principal Investigator ラジカル反応 / トリフルオロメチル化 / ラジカルフィリシティ / 計算化学 / キラルアミン / フルオロアルキル化反応 / 不斉合成 / アジリジン / ラジカル / 触媒 … More / フルオロアルキル化 / DFT計算 / 銅触媒 / アミン / フルオロアルキル分子 / 超原子価ヨウ素 / 過酸化トリフルオロアセチル … More Except Principal Investigator ラマン分光法 / 同位体標識 / ラマンタグ / ラマンイメージング Less

Development and application of built-in Raman tag using isotope labeling
- Principal Investigator
  
  どど孝介
- Project Period (FY)
  2024 – 2026
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Review Section
  
  Basic Section 37030:Chemical biology-related
- Research Institution
  Institute of Physical and Chemical Research
ラジカル反応の化学選択性を予測・制御可能にする実践的パラメータの創出Principal Investigator
- Principal Investigator
  
  河村伸太郎
- Project Period (FY)
  2024 – 2026
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Review Section
  
  Basic Section 47010:Pharmaceutical chemistry and drug development sciences-related
- Research Institution
  Institute of Physical and Chemical Research
Development of an efficient asymmetric synthetic method for chiral amines bearing a fluoroalkyl groupPrincipal Investigator
- Principal Investigator
  
  Kawamura Shintaro
- Project Period (FY)
  2021 – 2023
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Review Section
  
  Basic Section 47010:Pharmaceutical chemistry and drug development sciences-related
- Research Institution
  Institute of Physical and Chemical Research
Development of trifluoromethylation reaction by using a novel chiral hypervalent iodine catalystPrincipal Investigator
- Principal Investigator
  
  Kawamura Shintaro
- Project Period (FY)
  2015 – 2017
- Research Category
  
  Grant-in-Aid for Young Scientists (B)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Institute of Physical and Chemical Research

All 2024 2023 2022 2021 2018 2017 2016 2015

All Journal Article Presentation Patent

[Journal Article] Aerobic Photoredox Catalyzed Oxamate Ester Synthesis from Bromodifluoroacetate Esters2024
- Author(s)
  Tagami Takuma、Kawamura Shintaro、Sodeoka Mikiko
- Journal Title
  
  European Journal of Organic Chemistry
  
  Volume: 2024 Issue: 23
- DOI
  10.1002/ejoc.202400265
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-21K06489
[Journal Article] Evolution and Future of Hetero‐ and Hydro‐Trifluoromethylations of Unsaturated C-C Bonds2023
- Author(s)
  Kawamura Shintaro、Barrio Pablo、Fustero Santos、Escorihuela Jorge、Han Jianlin、A. Soloshonok Vadim、Sodeoka Mikiko
- Journal Title
  
  Advanced Synthesis & Catalysis
  
  Volume: 365 Issue: 4 Pages: 398-462
- DOI
  10.1002/adsc.202201268
- Peer Reviewed / Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-21K06489
[Journal Article] Catalytic Difluoromethylation of Alkenes with Difluoroacetic Anhydride: Reactivity of Fluorinated Diacyl Peroxides and Radicals2023
- Author(s)
  Tagami Takuma、Mitani Yusuke、Kawamura Shintaro、Sodeoka Mikiko
- Journal Title
  
  Advanced Synthesis & Catalysis
  
  Volume: 365 Issue: 21 Pages: 3637-3647
- DOI
  10.1002/adsc.202300337
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-21K06489
[Journal Article] Understanding and Controlling Fluorinated Diacyl Peroxides and Fluoroalkyl Radicals in Alkene Fluoroalkylations2023
- Author(s)
  Kawamura Shintaro、Sodeoka Mikiko
- Journal Title
  
  The Chemical Record
  
  Volume: 23 Issue: 9
- DOI
  10.1002/tcr.202300202
- Peer Reviewed / Open Access
- Data Source
  KAKENHI-PROJECT-21K06489
[Journal Article] Cu-catalyzed Allylic Perfluoroalkylation of Alkenes Using Perfluoro Acid Anhydrides: Preparation of N-(5,5,5-Trifluoro-2-penten-1-yl)phthalimide2021
- Author(s)
  Yuma Aoki, Shintaro Kawamura, Mikiko Sodeoka
- Journal Title
  
  Organic Syntheses
  
  Volume: 98 Pages: 84-96
- DOI
  10.15227/orgsyn.098.0084
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-21K06489
[Journal Article] 1,2-Bis-perfluoroalkylations of alkenes and alkynes with perfluorocarboxylic anhydrides via the formation of perfluoroalkylcopper intermediates2021
- Author(s)
  Takuma Tagami, Yuma Aoki, Shintaro Kawamura, Mikiko Sodeoka
- Journal Title
  
  Organic & Biomolecular Chemistry
  
  Volume: 19 Issue: 42 Pages: 9148-9153
- DOI
  10.1039/d1ob01529j
- Peer Reviewed / Open Access
- Data Source
  KAKENHI-PROJECT-21K06489
[Journal Article] Synthesis of CF3-containing oxazolines via trifluoromethylation of allylamides with Togni reagent in the presence of alkali metal iodides2017
- Author(s)
  Kawamura Shintaro、Sekine Daisuke、Sodeoka Mikiko
- Journal Title
  
  Journal of Fluorine Chemistry
  
  Volume: 203 Pages: 115-121
- DOI
  10.1016/j.jfluchem.2017.07.012
- Peer Reviewed / Open Access
- Data Source
  KAKENHI-PROJECT-15K17860
[Journal Article] N-Heterocycle-forming amino- and carbo-perfluoroalkylations of aminoalkenes by using perfluoro acid anhydrides: mechanistic studies and applications directed toward perfluoroalkylated compound libraries2017
- Author(s)
  Shintaro Kawamura, Kento Dosei, Elena Valverde, Kiminori Ushida, Mikiko Sodeoka
- Journal Title
  
  J. Org. Chem.
  
  Volume: 82 Issue: 23 Pages: 12539-12553
- DOI
  10.1021/acs.joc.7b02307
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-15F15340, KAKENHI-PROJECT-15K17860
[Journal Article] Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source2016
- Author(s)
  Shintaro Kawamura, Mikiko Sodeoka
- Journal Title
  
  Angew. Chem. Int. Ed.
  
  Volume: 55 Issue: 30 Pages: 8740-8743
- DOI
  10.1002/anie.201604127
- Peer Reviewed / Acknowledgement Compliant
- Data Source
  KAKENHI-PROJECT-15K17860
[Patent] パーフルオロアルキル化化合物の製造方法2016
- Inventor(s)
  袖岡幹子、河村伸太郎
- Industrial Property Rights Holder
  理化学研究所
- Industrial Property Rights Type
  特許
- Filing Date
  2016-12-12
- Overseas
- Data Source
  KAKENHI-PROJECT-15K17860
[Patent] パーフルオロアルキル化化合物の製造方法2015
- Inventor(s)
  袖岡幹子、河村伸太郎
- Industrial Property Rights Holder
  理化学研究所
- Industrial Property Rights Type
  特許
- Filing Date
  2015-12-05
- Data Source
  KAKENHI-PROJECT-15K17860
[Presentation] Copper-Ligand-to-Metal Charge Transfer Photocatalysis Involving Halogen-Atom-Transfer in Alkene Difunctionalization2024
- Author(s)
  Subrata Mukherjee, Shintaro Kawamura, Mikiko Sodeoka
- Organizer
  第104回日本化学会春季年会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] Copper-Mediated 1,2-Bis-perfluoroalkylations of Alkenes and Alkynes with Perfluorocarboxylic Anhydrides2023
- Author(s)
  Takuma Tagami, Yuma Aoki, Shintaro Kawamura, Mikiko Sodeoka
- Organizer
  7th Fluorine Days
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] Cu-Catalyzed Difluoromethylation of Alkenes Using Difluoroacetic Anhydride Mediated by Diacyl Peroxide2023
- Author(s)
  Shintaro Kawamura, Takuma Tagami, Yusuke Mitani, Mikiko Sodeoka
- Organizer
  第69回有機金属化学討論会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] Synthesis of Polyhalogenated Molecules by a General Cu-Catalyzed Halo-Halofluoroalkylation of Alkenes/Alkynes with Fluorinated Carboxylic Anhydrides2023
- Author(s)
  Subrata Mukherjee, Yuma Aoki, Shintaro Kawamura, Mikiko Sodeoka
- Organizer
  第103回日本化学会春季年会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] フルオロカルボン酸無水物を用いたフルオロアルキル化反応の開発2023
- Author(s)
  河村伸太郎
- Organizer
  第19回フッ素相模セミナー
- Invited
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] Z-Enamide Synthesis by Stereoselective Radical Fluoroalkylation Reaction2023
- Author(s)
  田上拓磨、青木雄真、関根大介、河村伸太郎、袖岡幹子
- Organizer
  第103回日本化学会春季年会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] Difluoromethylation of Alkenes with Difluoroacetic Anhydride: Structure and Reactivity of Fluorinated Diacyl Peroxides and Radicals2023
- Author(s)
  Shintaro Kawamura, Takuma Tagami, Yusuke Mitani, Mikiko Sodeoka
- Organizer
  7th Fluorine Days
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] 新規有機フッ素分子の実用的合成法の開発2023
- Author(s)
  河村伸太郎
- Organizer
  日本化学会第103春季年会（2023）若い世代の特別講演会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] アリルアミドの立体選択的ラジカルフルオロアルキル化反応によるZ-エナミド合成2022
- Author(s)
  田上拓磨、青木雄真、関根大介、河村伸太郎、袖岡幹子
- Organizer
  第38回有機合成化学セミナー
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] 第38回有機合成化学セミナー2022
- Author(s)
  河村伸太郎、田上拓磨、三谷優輔、袖岡幹子
- Organizer
  ジフルオロ酢酸無水物を用いたジフルオロメチル化反応の開発：含フッ素ジアシルペルオキシドとフルオロアルキルラジカルの構造と反応性
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] フルオロアルキル分子の実用的な合成法の開発2022
- Author(s)
  河村伸太郎
- Organizer
  第30回ケムステVシンポ
- Invited
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] アリルアミドのラジカルフルオロアルキル化反応による立体選択的なZ-エナミド合成2022
- Author(s)
  田上拓磨、青木雄真、関根大介、河村伸太郎、袖岡幹子
- Organizer
  第45回フッ素化学討論会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] ジフルオロ酢酸無水物を用いたジフルオロメチル化反応の開発：含フッ素ジアシルペルオキシドとフルオロアルキルラジカルの構造と反応性2022
- Author(s)
  河村伸太郎、田上拓磨、三谷優輔、袖岡幹子
- Organizer
  第45回フッ素化学討論会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] 1,2-Bis-perfluoroalkylations of Alkenes and Alkynes with Perfluorocarboxylic Anhydride2022
- Author(s)
  田上拓磨、青木雄真、河村伸太郎、袖岡幹子
- Organizer
  日本化学会第102春季年会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] ラジカルフルオロアルキル化反応による Z-エナミドの立体選択的合成法の開発2022
- Author(s)
  田上拓磨、青木雄真、関根大介、河村伸太郎、袖岡幹子
- Organizer
  第121回有機合成シンポジウム
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] ペルフルオロアルキル銅中間体の形成を鍵とするペルフルオロ酸無水物を用いた1,2-ビスペルフルオロアルキル化反応の開発2021
- Author(s)
  田上拓磨、青木雄真、河村伸太郎、袖岡幹子
- Organizer
  第37回有機合成化学セミナー
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] ペルフルオロ酸無水物を用いたアルケンおよびアルキンのビスペルフルオロアルキル化反応の開発2021
- Author(s)
  田上拓磨、青木雄真、河村伸太郎、袖岡幹子
- Organizer
  第79回有機合成化学協会関東支部シンポジウム
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] ペルフルオロアルキル銅中間体の形成を鍵とするペルフルオロ酸無水物を用いたアルケンおよびアルキンの1,2-ビスペルフルオロアルキル化反応2021
- Author(s)
  河村伸太郎、田上拓磨、青木雄真、袖岡幹子
- Organizer
  第44回フッ素化学討論会
- Data Source
  KAKENHI-PROJECT-21K06489
[Presentation] Development of a synthetic method for perfluoroalkylated N-heterocycles directed toward construction of compound libraries2018
- Author(s)
  Shintaro Kawamura, Kento Dosei, Elena Valverde, Kiminori Ushida, Mikiko Sodeoka
- Organizer
  日本化学会第98春季年会
- Data Source
  KAKENHI-PROJECT-15K17860
[Presentation] Development of perfluoroalkylation of unactivated alkenes by using perfluoro acid anhydrides2017
- Author(s)
  Shintaro Kawamura, Mikiko Sodeoka
- Organizer
  第97日本化学会春季年会
- Place of Presentation
  慶應大学 (横浜)
- Year and Date
  2017-03-16
- Data Source
  KAKENHI-PROJECT-15K17860
[Presentation] Practical Electrophilic Perfluoroalkylation of Alkenes2016
- Author(s)
  河村伸太郎、袖岡幹子
- Organizer
  French-Japanese Symposium on Medicinal and Fine Chemistry
- Place of Presentation
  京王プラザホテル（東京・多摩）
- Year and Date
  2016-05-15
- Int'l Joint Research
- Data Source
  KAKENHI-PROJECT-15K17860
[Presentation] 実用的なペルフルオロアルキル化反応の開発2016
- Author(s)
  河村伸太郎
- Organizer
  平成28年度若手研究者のためのセミナー
- Place of Presentation
  東京大学 (東京)
- Invited
- Data Source
  KAKENHI-PROJECT-15K17860

1. どど孝介 (20415243)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
2. 江越脩祐 (60755932)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
3. 袖岡幹子

# of Collaborated Projects: 0 results

# of Collaborated Products: 1 results

Kawamura Shintaro 河村 伸太郎

Research Projects

Research Products

Co-Researchers

Development and application of built-in Raman tag using isotope labeling

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

ラジカル反応の化学選択性を予測・制御可能にする実践的パラメータの創出Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Development of an efficient asymmetric synthetic method for chiral amines bearing a fluoroalkyl groupPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Development of trifluoromethylation reaction by using a novel chiral hypervalent iodine catalystPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Journal Article] Aerobic Photoredox Catalyzed Oxamate Ester Synthesis from Bromodifluoroacetate Esters2024

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Evolution and Future of Hetero‐ and Hydro‐Trifluoromethylations of Unsaturated C-C Bonds2023

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Catalytic Difluoromethylation of Alkenes with Difluoroacetic Anhydride: Reactivity of Fluorinated Diacyl Peroxides and Radicals2023

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Understanding and Controlling Fluorinated Diacyl Peroxides and Fluoroalkyl Radicals in Alkene Fluoroalkylations2023

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Cu-catalyzed Allylic Perfluoroalkylation of Alkenes Using Perfluoro Acid Anhydrides: Preparation of N-(5,5,5-Trifluoro-2-penten-1-yl)phthalimide2021

Author(s)

Journal Title

DOI

Data Source

[Journal Article] 1,2-Bis-perfluoroalkylations of alkenes and alkynes with perfluorocarboxylic anhydrides via the formation of perfluoroalkylcopper intermediates2021

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Synthesis of CF3-containing oxazolines via trifluoromethylation of allylamides with Togni reagent in the presence of alkali metal iodides2017

Author(s)

Journal Title

DOI

Data Source

[Journal Article] N-Heterocycle-forming amino- and carbo-perfluoroalkylations of aminoalkenes by using perfluoro acid anhydrides: mechanistic studies and applications directed toward perfluoroalkylated compound libraries2017

Author(s)

Journal Title

DOI

Data Source

[Journal Article] Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source2016

Author(s)

Journal Title

DOI

Data Source

[Patent] パーフルオロアルキル化化合物の製造方法2016

Inventor(s)

Industrial Property Rights Holder

Industrial Property Rights Type

Filing Date

Data Source

[Patent] パーフルオロアルキル化化合物の製造方法2015

Kawamura Shintaro 河村伸太郎