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IMAMOTO Tsuneo  今本 恒雄

… Alternative Names

今本 恒雄  イマモト ツネオ

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Researcher Number 10134347
Other IDs
  • ORCIDhttps://orcid.org/0000-0003-3197-197X
External Links
Affiliation (based on the past Project Information) *help 2008 – 2009: Chiba University, 名誉教授
2007: Chiba University, Graduate School of Science, Chemistry, Professor
2001 – 2006: 千葉大学, 理学部, 教授
1993 – 1996: 千葉大学, 理学部, 教授
1990 – 1992: 千葉大学, 理学部, 助教授 … More
1988: 千葉大学, 理学部, 助教授
1988: 千葉大学, 理学部, 教授
1987: 千葉大学, 理学部, 助手 Less
Review Section/Research Field
Principal Investigator
Science and Engineering / Organic chemistry / 有機化学一般 / Organic chemistry / 物質変換
Except Principal Investigator
Synthetic chemistry
Keywords
Principal Investigator
ホスフィンボラン / 不斉合成 / 触媒的不斉合成 / 光学活性化合物 / 不斉触媒 / ロジウム錯体 / 不斉水素化 / ホスフィン / Asymmetric Hydrogenation / パラジウム錯体 … More / 触媒 / 光学活性配位子 / 親電子置換反応 / ホウ素アニオン / 求核置換反応 / P-Chiral Phosphine / P-キラルホスフィン / Optically Active Phosphine / 光学活性ホスフィン / 不斉複核錯体 / 不斉錯体触媒 / 協奏機能触媒 / 光学活性アミン / ホスフィン-ボラン / 不斉キレート錯体 / ハイブリッド配位子 / Chiral Palladium Complex / Chiral Rodium Complex / Phosphine-borane / Optically Active Compound / Catalytic Asymmetric Synthesis / Optically Active Phosphine Ligand / 光学活性パラジウム錯体 / エナンチオ選択性 / 遷移金属錯体 / 光学活性ボスフィン配位子 / P-キラルポスフィン / 不斉パラジウム錯体 / 不斉ロジウム錯体 / ホスフィンボラ / 光学活性ホスフィン配位子 / Asymmetric Catalysis / Chiral Ligands / Phosphine / Rhodium Complex / Iridium Complex / イリジウム錯体 / 光学活性ホスフ / Reaction Mechanism / Catalyst / Rhodium Complexes / Asymmetric Synthesis / 反応機構 / Electrophilic Substitution / Organophosphorus Compound / Nucleophilic Substitution / Amino-Borane / Borane / Phosphine-Borane / Organoboron Compound / Boron Anion / 親電子試剤 / 電子環状反応 / カルボアニオン / 求核反応 / ホウ素ジアニオン / アミン・ボラン / 有機リン化合物 / アミンボラン / ボラン / ホスフィン・ボラン / 有機ホウ素化合物 / 不斉ホスフィン / ヨードヒドリン / シクロプロパノール / サマリウム / ヨウ化サマリウム(II) / 協奏機能機能触媒 / エナンチオ選択性発現機構 / キラルボスフィン / ロジウム触媒 / 不斉配位子 / 不斉1,4付加 / イリジウム錯体触媒 / ロジウム錯体触媒 / 不斉ホスフィン配位子 / 光学活性アミノ酸 / ボスフィン-ボラン / エナンチオマー / 光学活性 / 新電子置換反応 / ホウ素化合物 / 不斉ホウ素原子 / ホスフイン・ボラン / ホスフイン / 不斉還元 / 4配位ホウ素化合物 / ホスフィンオキシド / 光学活性ホスフィンオキシド / ランタニド錯体 / 希土類 / 化学振動 … More
Except Principal Investigator
異常原子価化合物 / 低配位リン化合物 / 高歪ケイ素化合物 / 遷移状態モデル / 光学活性ホスフィンボラン / 2ーヘテロシクロプロペン / アルキルセリウム化合物の付加反応 / カルボニル基へのジアステレオ選択的付加 / シクロプロビル亜鉛 / 立体選択的クライゼン転移 / 不斉マイケル付加反応 / ハロボレーション反応 / アルケニルセリウム錯体 / 脱酸素的炭素-炭素結合生成反応 / アリルサマリウム / ランタノイド(II)トリフラート / スカンジウムパ-フラート / 希土類超強酸塩 / 希土類アルコキシド / イミン希土類(II)ジアニオン錯体 / ケトン-希土類(II)ジアニオン錯体 / 立体選択的ラジカル反応 / サマリウムケチル / 触媒的不斉エポキシ化 / 触媒的脱水素シリル化反応 / 希土類のルイス酸性の評価 / 不斉ヘテロDiels-Alder反応 / 高分子希土類触媒 / 希土類イソプロポキシド / イミン-Yb錯体 / 光学活性希土類錯体触媒 / テトラアザチアペンタレン / 3配位ホウ素アニオン / 2-ヘテロシクロプロペン / シレン / 分子間相互作用 / 分子内相互作用 / 超高スピン有機分子 Less
  • Research Projects

    (25 results)
  • Research Products

    (80 results)
  • Co-Researchers

    (22 People)
  •  P-キラルホスフィンの特性を活かした不斉協奏機能触媒の開発Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      2008 – 2009
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Review Section
      Science and Engineering
    • Research Institution
      Chiba University
  •  高性能不斉触媒の開発を基盤とする不飽和有機化合物の高度分子変換Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      2007 – 2008
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Review Section
      Science and Engineering
    • Research Institution
      Chiba University
  •  P-キラルホスフィンの特性を活かした不斉協奏機能触媒の開発Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      2007
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Review Section
      Science and Engineering
    • Research Institution
      Chiba University
  •  高性能不斉触媒の開発を基盤とする不飽和有機化合物の高度分子変換Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      2006
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Review Section
      Science and Engineering
    • Research Institution
      Chiba University
  •  Development of Highly Stereoselective Asymmetric Reactions Using P-Chiral Phosphine LigandsPrincipal Investigator

    • Principal Investigator
      IMAMOTO Tsuneo
    • Project Period (FY)
      2006 – 2007
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Organic chemistry
    • Research Institution
      Chiba University
  •  ホウ素原子上に不斉中心を有する光学活性4配位ホウ素化合物の合成と反応Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      2004 – 2005
    • Research Category
      Grant-in-Aid for Exploratory Research
    • Research Field
      Organic chemistry
    • Research Institution
      Chiba University
  •  Development of New Catalytic Asymmetric Reactions Based on the Synthesis of Optically Active Phosphine LigandsPrincipal Investigator

    • Principal Investigator
      IMAMOTO Tsuneo
    • Project Period (FY)
      2004 – 2005
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Organic chemistry
    • Research Institution
      Chiba University
  •  光学活性多元素環状金属錯体の合成と反応性に関する研究Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      2002 – 2003
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Review Section
      Science and Engineering
    • Research Institution
      Chiba University
  •  光学活性多元素環状金属錯体の合成と反応性に関する研究Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      2001 – 2002
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas (A)
    • Review Section
      Science and Engineering
    • Research Institution
      Chiba University
  •  Elucidation of the Enantioselection Mechanism of Transition Metal-Catalyzed Asymmetric ReactionsPrincipal Investigator

    • Principal Investigator
      IMAMOTO Tsuneo
    • Project Period (FY)
      2001 – 2002
    • Research Category
      Grant-in-Aid for Scientific Research (B)
    • Research Field
      Organic chemistry
    • Research Institution
      CHIBA UNIVERSITY
  •  新規光学活性ホスフィン配位子の合成と不斉触媒反応への利用Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      1995
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Chiba University
  •  新規光学活性ホスフィン配位子の合成と不斉触媒反応への利用Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      1994
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Chiba University
  •  希土類錯体の反応特性の解明と合成化学への新展開

    • Principal Investigator
      稲永 純二
    • Project Period (FY)
      1994 – 1996
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Kyushu University
  •  発見準拠型革新的有機反応 創出研究の支援体制に関するフィージビリティスタディ

    • Principal Investigator
      村井 真二
    • Project Period (FY)
      1994
    • Research Category
      Grant-in-Aid for Co-operative Research (B)
    • Research Field
      Synthetic chemistry
    • Research Institution
      Osaka University
  •  Generation of Tricooordinate Boron Anions and Synthetic Use of Novel Boron CompoundsPrincipal Investigator

    • Principal Investigator
      IMAMOTO Tsuneo
    • Project Period (FY)
      1994 – 1996
    • Research Category
      Grant-in-Aid for Scientific Research (A)
    • Research Field
      物質変換
    • Research Institution
      Chiba University
  •  新規光学活性ホスフィン配位子の合成と不斉触媒反応への利用Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      1993
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Chiba University
  •  低配位および高歪有機典型元素化合物の特徴と異常性

    • Principal Investigator
      石川 満夫
    • Project Period (FY)
      1992
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  4配位ホウ素化合物のホウ素原子上での置換反応に関する研究Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      1992
    • Research Category
      Grant-in-Aid for General Scientific Research (B)
    • Research Field
      有機化学一般
    • Research Institution
      Chiba University
  •  低配位および高歪有機典型元素化合物の特徴と異常性

    • Principal Investigator
      石川 満夫
    • Project Period (FY)
      1991
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  光学活性有機ランタニド錯体の合成と反応Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      1991
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Institution
      Chiba University
  •  低配位および高歪有機典型元素化合物の特徴と異常性

    • Principal Investigator
      石川 満夫
    • Project Period (FY)
      1990
    • Research Category
      Grant-in-Aid for Scientific Research on Priority Areas
    • Research Institution
      Hiroshima University
  •  化学振動現象を示す有機化学反応の開発Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      1990
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Field
      有機化学一般
    • Research Institution
      Chiba University
  •  物質変換機能を有する有機金属化合物

    • Principal Investigator
      鈴木 章
    • Project Period (FY)
      1988
    • Research Category
      Grant-in-Aid for Special Project Research
    • Research Institution
      Hokkaido University
  •  ホスフィンボラン錯体の特性を生かした光学活性ホスフィン配位子の合成Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      1988 – 1989
    • Research Category
      Grant-in-Aid for General Scientific Research (C)
    • Research Field
      有機化学一般
    • Research Institution
      Chiba University
  •  有機サマリウム(II)錯体の合成と反応性に関する研究Principal Investigator

    • Principal Investigator
      今本 恒雄
    • Project Period (FY)
      1987
    • Research Category
      Grant-in-Aid for Special Project Research
    • Research Institution
      Chiba University

All 2010 2009 2008 2007 2006 2005 2004 Other

All Journal Article Presentation Patent

  • [Journal Article] Improved synthetic routes to methylene-bridged P-chiral diphosphine ligands via secondary phosphine-boranes2010

    • Author(s)
      T.Imamoto, T.Tamura, T.Ogura, Y.Ikematsu, D.Mayama, M.Sugiya
    • Journal Title

      Tetrahedron : Asymmetry 21(印刷中)

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20037009
  • [Journal Article] Optically Active Dinuclear Palladium Complexes Containing a Pd-Pd Bond : Preparation and Enantioinduction Ability in Asymmetric Ring Opening Reactions2009

    • Author(s)
      T.Ogura, K.Yoshida, Y.Yanagisawa, T.Imamoto
    • Journal Title

      Organic Letters 11

      Pages: 2245-2248

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20037009
  • [Journal Article] Mechanism of enantioselection in Rh-catalyzed asymmetric hydrogenation.The origin of utmost catalytic performance2009

    • Author(s)
      I.D.Gridnev, T.Imamoto
    • Journal Title

      Chemical Communications

      Pages: 7447-7464

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20037009
  • [Journal Article] Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (R)-(tert)-Butylmethylphosphino)(di-tert-butylphosphino)methane2008

    • Author(s)
      I. D. Gridnev, T, Imamoto, G. Hoge, M. Kouchi, H. Takahashi
    • Journal Title

      Joumal of the American Chemical Society 130

      Pages: 25602572-25602572

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] Construction of Optically Active Multimetallic System of Rhodium(I), Palladiuma(II), and Ruthenium(II)2008

    • Author(s)
      K. Yashio, M. Kawabata, H. Danjo, K. Yamaguchi, T. Imamoto
    • Journal Title

      Journal of Organometallic Chemistry 694

      Pages: 97-102

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20037009
  • [Journal Article] P-キラルポスフィン配位子の合成と触媒的不斉合成への利用2008

    • Author(s)
      今本恒雄
    • Journal Title

      月刊ファインケミカル 37

      Pages: 41-54

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19020015
  • [Journal Article] Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (R)-(tert-Butylmethylphosphino) (di-tert-butylphosphino) methane2008

    • Author(s)
      I. D. Gridnev, T. Imamoto, G. Hoge, M. Kouchi, H. Takahashi
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 2560-2572

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19028009
  • [Journal Article] Formation of 1, 4-Diphosphinobenzenes via tele-Substitution on Fluorobenzenechromium Complexes2008

    • Author(s)
      Y. Yamamoto, H. Danjo, K. Yamaguchi, T. Imamoto
    • Journal Title

      Journal of Organometallic Chemistry 693

      Pages: 3546-3552

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-20037009
  • [Journal Article] Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (R)-(tert)-Butylmethylphosphino)(di-tert-butylphosphino)-methane2008

    • Author(s)
      I. D. Gridnev, T. Imamoto, G. Hoge, M. Kouchi, H. Takahashi
    • Journal Title

      Journal of the Ametrican Chemical Society 130

      Pages: 2560-2572

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] Marked Deuterium Isotope Effects on the Enantioselectivity in Rhodium-Catalyzed Asymmetric Hydrozenation of Enamides2008

    • Author(s)
      T. Imamoto, T. Itoh, K. Yoshida, I. D. Gridnev
    • Journal Title

      Chemistry : An Asian Journal 3

      Pages: 1636-1641

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19020015
  • [Journal Article] Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (R)-(tert)-Butylmethylphosphino) (di-tert-butylphosphino) methane2008

    • Author(s)
      I.D. Gridnev, T. Imamoto, G. Hode, M. Kouchi, H. Takahashi
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 2560-2572

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] Air-stable P-Chiral Bidentate Phosphne Ligand with (1-Adamantyl)methylphosphino Group2007

    • Author(s)
      T. Imamoto, A. Kumada, K. Yoshida
    • Journal Title

      Chemistry Letters 36

      Pages: 500-501

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] Synthesis and Enantioselectivity of P-Chiral Phosphine Ligands Possessing Alkynyl Groups2007

    • Author(s)
      Imamoto, Y. Saito, A. Koide, T. Ogura, K. Yoshida
    • Journal Title

      Angewandte Chemie International Edition 46

      Pages: 8636-8639

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19020015
  • [Journal Article] Air-stable P-Chiral Bidentate Phosphine Ligand with (1-Adamanty1) methylphosphino Group2007

    • Author(s)
      T. Imamoto, A. Kumada, K. Yoshida
    • Journal Title

      Chemistry Letters 36

      Pages: 500-501

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] P-Chiral Phosphine Ligands for Transition-Metal-Catalyzed Asymmetric Reactions2007

    • Author(s)
      T. Imamoto
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan, 65

      Pages: 1060-1069

    • NAID

      10019787835

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] Air-stable P-chiral Bidentate Phosphine Ligand with (1-Adamantyl) methylphosphino Group2007

    • Author(s)
      T. Imamoto, A. Kumada, K. Yoshida
    • Journal Title

      Chemistry Letters 36

      Pages: 500-501

    • NAID

      10018880788

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19020015
  • [Journal Article] t-Bu-QuinoxP* Ligand: Applications in Asymmetric Pd-Catalyzed allylic Substitution and Ru-Catalyzed Hydrogenation2007

    • Author(s)
      T. Imamoto, M. Nishimura, A. Koide, K. Yoshida
    • Journal Title

      Journal of Organic Chemistry 72

      Pages: 7413-7416

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-19020015
  • [Journal Article] P-Chiral Phosphine Ligands for Transition-Metal-Catalyzed Asymmetric Reactions2007

    • Author(s)
      T. Imamoto
    • Journal Title

      有機合成化学協会誌 65

      Pages: 1060-1069

    • NAID

      10019787835

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] P-Chiral Phosphine Ligands for Transition-Metal-catalyzed asymmetric Reactions2007

    • Author(s)
      T. Imamoto
    • Journal Title

      有機合成化学協会誌 65

      Pages: 10601069-10601069

    • NAID

      10019787835

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] Air-stable P-Chiral Bidentate Phosphine Ligand with(1-Adamantyl)methylphosphjno Group2007

    • Author(s)
      T. Imamoto, A. Kumada, K. Yoshida.
    • Journal Title

      Chemistry Letters 36

      Pages: 500-501

    • Peer Reviewed
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] Air-stable P-Chira1 Bidentate Phosphine Ligand with (1-Adamanty1)-Methylphosphino Group2007

    • Author(s)
      T.Imamoto, A.kumada, K.Yoshida
    • Journal Title

      Chemistry Letters 2007

      Pages: 500-501

    • Data Source
      KAKENHI-PROJECT-18350017
  • [Journal Article] P-Chiral Tetraphosphine Dirhodium Complex as a Catalyst for Asymmetric Hydrogenation : Synthesis, Structure, Enantioselectivity, and Mechanism. Stereoselective Formation of a Dirhodium Tetrahydride Complex and Its Reaction with Methyl (Z)-α-Acetamidocinnamate2006

    • Author(s)
      T.Imamoto, K.Yashio, K.V.L.Crepy, H.Takahashi, M.Kouichi, I.D.Gridnev
    • Journal Title

      Organometallics 25

      Pages: 908-914

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Enantioselective Hydrogenation of Acyclic Aromatic N-Aryl Iminess Catalyzed by an Iridium Complex of(S,S)-1,2-Bis(tert-butylmethylphosphino)ethane2006

    • Author(s)
      T.Imamoto, N.Iwadate, K.Yoshida
    • Journal Title

      Organic Letters 8

      Pages: 2289-2292

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] P-Chiral Tetraphosphine Dirhodium Complex as a Catalyst for Asymmetric Hydrogenation : Synthesis, Structure, Enantioselectivity, and Mechanism. Stereoselective Formation of a Dirhodium Tetrahydride Complex and Its Reaction with Methyl (Z)-α-Acetamidocinnamate,2006

    • Author(s)
      Imamoto, T., Yashio, K., Crepy, K.V.L., Katagiri, K., Takahashi, H., Kouchi, M., Gridnev, I.D.
    • Journal Title

      Organometallics 25

      Pages: 908-914

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Enantioselective Hydrogenation of Acyclic Aromatic N-Aiyl Imines Catalyzed by an Iridium Complex of (S,S)-1,2-Bis(tert-butylmethylphosphino)ethane,2006

    • Author(s)
      Imamoto, T., Iwadate, N., Yoshida, K.
    • Journal Title

      Org.Lett. 8

      Pages: 2289-2292

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Enantioselective Hydrogenation of Acyclic Aromatic N-Aryl Imines Catalyzed by an Iridium Complexes of (S, S)-1, 2-Bis(tert-butylmethylphosphino)ethan2006

    • Author(s)
      T.Imamoto, N.Iwadate, K.Yoshida
    • Journal Title

      Organic Letters 8

      Pages: 2289-2292

    • Data Source
      KAKENHI-PROJECT-18037011
  • [Journal Article] Highly Enantioselective Hydrosilylation of Simple Ketones Catalyzed by Rhodium Complexes of P-Chiral Diphosphine Ligands Bearing tert-Butylmethylphosphino Group2006

    • Author(s)
      T.Imamoto, T.Ito, Y.Yamanoi, R.Narui, K.Yoshida
    • Journal Title

      Tetrahedron : Asymmetry (印刷中)(in press)

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Highly Enantioselective Hydrosilylation of Simple Ketones Catalyzed by Rhodium Complexes of P-Chiral Diphosphine Ligands Bearing tert-Butylmethyrphosphino Groups,2006

    • Author(s)
      Imamoto, T., Itoh, T., Yamanoi, Y., Narui, R., Yoshida, K.
    • Journal Title

      Tetrahedron : Asymmetry 17

      Pages: 560-565

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Highly Enantioselective Hydrosilylation of Simple Ketones Catalyzed by Rhodium Complexes of P-Chiral Diphosphine Ligands Bearing tert-Butylmethylphosphino Group.2006

    • Author(s)
      T.Imamoto, T.Ito, Y.Yamanoi, R.Narui, K.Yoshida
    • Journal Title

      Tetrahedron : Asymmetry 17

      Pages: 560-565

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] P-Chiral Tetraphosphine Dirhodium Complex as a Catalyst for Asymmetric Hydrogenation : Synthesis, Structure,Enantioselectivity,and Mechanism. Stereoselective Formation of a Derhodium Tetrahybride Complex and Its Reaction with Methyl(Z)-α-Acetamidocinnamate2006

    • Author(s)
      T.Imamoto, K.Yashio, K.V.L.Crepy, H.Takahashi, M.Mouichi, I.D.Gridnev
    • Journal Title

      Organometalllcs 25

      Pages: 908-914

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Nucleophilic Aromatic Substitution Reactions of Fluorobenzenechromium Complexes with P-Chiral Secondary Phosphine-Boranes : Synthesis of Optically Pure P-Chiral (Dialkyl)arylphosphine-Boranes,2005

    • Author(s)
      Katagiri, K., Danjo, D., Yamaguchi, K., Imamoto, T.
    • Journal Title

      Tetrahedron 61

      Pages: 4701-4704

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Evidence for the importance of conformational equilibria in Rh-diphosphine complexes for the enantioselection in Rh-catalyzed asymmetric hydrogenation2005

    • Author(s)
      H.Tsuruta, T.Imamoto, K.Yamaguchi, I.D.Gridnev
    • Journal Title

      Tetrahedron Letters 46

      Pages: 2879-2882

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] P-Chiral o-Phosphinophenol as a P/O Hybrid Ligand : Preparation and Use in Cu-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Acyclic Enones2005

    • Author(s)
      Y.Takahashi, Y.Yamamoto, K.Katagiri, H.Danjo, K.Yamaguchi, T.Imamoto
    • Journal Title

      Journal of Organic Chemistry 70

      Pages: 9009-9012

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Evidence for the importance of conformational equilibria in Rh-diphosphine complexes for the enantioselection in Rh-catalyzed asymmetric hydrogenation2005

    • Author(s)
      H.Tsuruta.T.Imamoto, K.Yamaguchi, I.D.Gridnev
    • Journal Title

      Tetrahedron Letters 46

      Pages: 2879-2882

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Evidence for the Importance of Conformational Equilibria in Rh-Diphosphine Complexes for the Enantioselection in Rh-Catalyzed Asymmetric Hydrogenation,2005

    • Author(s)
      Tsuruta, H., Imamoto, T., Yamaguchi, K., Gridnev, I.D.
    • Journal Title

      Tetrahedron Lett. 46

      Pages: 2879-2882

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Preparation of (S,S)-Bis(tert-butylmethylphosphino)ethane ((S,S)-t-Bu-BisP^*) as a Rhodium Complex,.2005

    • Author(s)
      Crepy, K.V.L., Imamoto, T., Seidel, G., Furstner, A.
    • Journal Title

      Organic Syntheses 82

      Pages: 22-29

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] P-Chiral o-Phosphinophenol as a P/O Hybrid Ligand : Preparation and Use in Cu-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Acyclic Enones,2005

    • Author(s)
      Takahashi, Y., Yamamoto, Y., Katagiri, K., Danjo, K., Yamaguchi, K., Imamoto, T.
    • Journal Title

      J.Org.Chem. 70

      Pages: 9009-9012

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] P-Chiral o-Phosphinophenol as a P/O Hybrid Ligand : Preparation and Use in Cu-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Acyclic Enones2005

    • Author(s)
      Y.Takahashi, Y.Yamamoto, K.Katagiri, H.Danjo, K.Yamaguchi, T.Imamoto
    • Journal Title

      Journal or Organic Chemistry 70

      Pages: 9009-9012

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] An Air-Stable P-Chiral Phosphine Ligands for Highly Enantioselective Transition-Metal-Catalyzed Reactions,2005

    • Author(s)
      Imamoto, T., Sugita, K., Yoshida, K.
    • Journal Title

      J.Am.Chem.Soc. 127

      Pages: 11934-11935

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] An Air-stable P-Chiral Phosphine Ligand for Highly Enantioselective Transition-Metal-Catalyzed Reactions2005

    • Author(s)
      T.Imamoto, K.Sugita, K.Yoshida
    • Journal Title

      Journal of the American Chemical Society 127

      Pages: 11934-11935

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Preparation of (S,S)-1,2-Bis(tert-butylmethylphosphino)ethane as a Rhodium Complex2005

    • Author(s)
      K.V.L.Crepy, T.Imamoto, G.Seidel.A.Furstner
    • Journal Title

      Organic Syntheses 82

      Pages: 22-29

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Nucleophilic Aromatic Substitution Reactions of Fluorobenzenechromium Complexes with P-Chiral Secondary Phosphine-Boranes : Synthesis of Optically Pure P-Chiral (Dialkyl)arylphosphine-Boranes2005

    • Author(s)
      K.Katagiri, H.Danjo, K.Yamaguchi, T.Imamoto
    • Journal Title

      Tetrahedron 61

      Pages: 4701-4704

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Nucleophilic Aromatic Substitution Reactions of Fluorobenzenechromium Complexes with P-Chiral Secondary Phosphine-Boranes : Synthesis of Optically Pure P-Chiral (Dialkyl) arylphosphine-Boranes2005

    • Author(s)
      K.Katagiri, H.Danjo, K.Yamaguchi, T.Imamoto
    • Journal Title

      Tetrahedron 61

      Pages: 4701-4704

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] An Air-stable P-chiral Phosphine Ligand for Higyly Enantioselective Transition-Metal-Catalyzed Reactions2005

    • Author(s)
      T.Imamoto, K.Sugita, K.Yoshida
    • Journal Title

      Journal of the American Chemical Society 127

      Pages: 11934-11935

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] P-Stereogenic P/N Hybrid Ligands : A Remarkable Switch in Enantioselectivity in Palladoum-Catalyzed asymmetric Allylation.2004

    • Author(s)
      H.Danjo, M.Higuchi, M.Yada, T.Imamoto
    • Journal Title

      Tetrahedron Letters 45

      Pages: 603-606

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Optically Active Di-tert-butyl-2,2'-diphosphetanyl and Its Application in Rhodium-Catalyzed Asymmetric Hydrogenations,2004

    • Author(s)
      Imamoto, T., Oohara, N., Takahashi, H.
    • Journal Title

      Synthesis (Special Issue)

      Pages: 1353-1358

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Optically Active 1,1'-tert-Butyl-2,2'-diphosphetanyl and Its application in Rhodium-Catalyzed Asymmetric Hydrogenations2004

    • Author(s)
      T.Imamoto, N.Oohara, H.Takahashi
    • Journal Title

      Synthesis 2004,9

      Pages: 1353-1358

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Optically Active 1,1'-Di-tert-butyl-2,2'-dibenzophosphetanyl : A Highly Strained P-Stereogenic Diphosphine Ligand2004

    • Author(s)
      T.Imamoto, K.V.L.Crepy, K.Katagiri
    • Journal Title

      Tetrahedron : Asymmetry 15

      Pages: 2213-2218

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Asymmetric Hydrogenation of α.,β-Unsaturated Phosphonates with Rh-BisP^* and Rh-MiniPHOS Catalysts : Scope and Mechanism of the Reaction.2004

    • Author(s)
      I.D.Gridnev, M.Yasutake, T.Imamoto, I.P.Beletskaya
    • Journal Title

      Proceedings of the National Academy of Sciences, USA 101

      Pages: 5385-5390

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] On the Mechanism of Stereoselection in Rh-Catalyzed Asymmetric Hydroge-Nation. A General Approach for Predicting the Sense of Enantioselectivity2004

    • Author(s)
      I.D.Gridnev, T.Imamoto
    • Journal Title

      Accounts of Chemical research 37,9

      Pages: 633-644

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Optically Pure 1,2-[Bis(o-alkylphenyl)phenylphosphino]ethanes and Their Use in Rhodium-Catalyzed Asymmetric Hydrogenations of α-(Acylamino)acrylic Derivatives,2004

    • Author(s)
      Wada, Y., Imamoto, T., Tsuruta, H., Yamaguchi, K., Gridnev, I.D.
    • Journal Title

      Adv.Syn.Catal. 346

      Pages: 777-788

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] 1,1'-Di-tert-2,2'-dibenzo-phosphetanyl : A Highly Straned P-Stereogenic Diphosphine Ligands.2004

    • Author(s)
      T.Imamoto, K.V.L.Crepy, K.Katagiri
    • Journal Title

      Tetrahedron : Asymmetry 15

      Pages: 2213-2218

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] P-Stereogenic P/N Hybrid Ligands : A Remarkable Switch in Enantioselectivity in Palladium-Catalyzed asymmetric Allylation2004

    • Author(s)
      H.Danjo, M.Higuchi, M.Yada, T.Imamoto
    • Journal Title

      Tetrahedron Letters 45

      Pages: 603-606

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Diliydroboronium Derivatives of (S,S)-1,2-Bis(t-butylmethylphosphino) ethane as Convenient Chiral Ligand Precursors.2004

    • Author(s)
      T.Miyazaki, M.Sugawara, H.Danjo, T.Imamoto
    • Journal Title

      Tetrahedron Letters 45

      Pages: 9341-9344

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] P-Stereogenic P/N Hybrid Ligands : A Remaxkable Switch in Enantioselectivity in Palladium-Catalyzed Asymmetric Allylation,2004

    • Author(s)
      Danjo, H., Higuchi, M., Yada, M., Imamoto, T.
    • Journal Title

      Tetrahedron Lett. 45

      Pages: 603-606

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Dihydroboronium Derivative of (S,S)-1,2-Bis(t-butylmethylphosphino)ethane as Convenient Chiral Ligand Precursors,2004

    • Author(s)
      Miyazaki, T., Sugawara, M., Danjo, H., Imamoto, T.
    • Journal Title

      Tetrahedron Lett. 45

      Pages: 9341-9344

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Optically Active Di-tert-buty-1-2,2'-diphosphetanyland Its Application in Rhodium-Catalyzed asymmetric Hydrogenations.2004

    • Author(s)
      T.Imamoto, N.Oohara, H.Takahashi
    • Journal Title

      Synthesis 2004

      Pages: 1353-1358

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Optically Pure 1,2-Bis[(o-alkylphenyl)phenylphosphino]ethanes and Their Use in Rhodium-Catalyzed Asymmetric Hydrogenation of α-(Acylamino)acrylic2004

    • Author(s)
      Y.Wada, T.Imamoto, H.Tsuruta, K.Yamaguchi, I.D.Gridnev
    • Journal Title

      Advanced Synthesis and Catalysis 346

      Pages: 777-788

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Asymmetric Hydrogenation of α,β-Unsatirated Phosphonates with Rh-BisP^* and Rh-MiniPHOS Catalysts : Scope and Mechanism of the Reaction2004

    • Author(s)
      Gridnev, I.D., Yasutake, M., Imamoto, T., Beletskaya, I.P.
    • Journal Title

      Proc.Natl.Acad.Sci.USA 101

      Pages: 5385-5390

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] On the Mechanism of Stereoselection in Rh-Catalyzed asymmetric Hydrogenation : A General Approach for Predicting the Sense of Enantioselectivity.2004

    • Author(s)
      I.D.Gridnev, T.Imamoto
    • Journal Title

      Accounts of Chemical Researches 37

      Pages: 633-644

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Asymmetric Hydrogenation of, α,β-Unsaturated Phosphonates with Rh-BisP* And Rh-MiniPHOS Catalysts : Scope and Mechanism of the Reaction2004

    • Author(s)
      I.D.Gridnev, M.Yasutake, T.Imamoto, I.P.Beletskaya
    • Journal Title

      Proceedings of the National Academy of Sciences, USA 101,15

      Pages: 5385-5390

    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Optically Active 1.1'-Di-tert-2,2'-dibenzo-phosphetanyl : A Highly Strained P-Stereogenic Diphosphine Ligands2004

    • Author(s)
      Imamoto, T., Crepy, K.V.L., Katagiri, K.
    • Journal Title

      Tetrahedron : Asymmetry 15(Special Issue)

      Pages: 2213-2218

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] On the Mechanism of Stereoselection in Rh-Catalyzed Asymmetric hydrogenation : A General Approach for Predicting the Sense of Enantioselectivity,2004

    • Author(s)
      Gridnev, I.D., Imamoto, T.
    • Journal Title

      Acc.Chem.Res. 37

      Pages: 633-644

    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] Optically Pure 1,2-[Bis(o-alkylphenyl) phenylphosphino]ethanes and Their Use in Rhodium-Catalyzed Asymmetric Hydrogenations of a-(Acylanilno) acrylic Derivatives.2004

    • Author(s)
      Y.Wada1, T.Imamoto, H.Tsuruta, K.Yamaguchi, I.D.Gridnev
    • Journal Title

      Advanced Synthesis & Catalysis 346

      Pages: 777-788

    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Journal Article] (R, R)-2, 3-Bis(tert-butylmethylphosphino)-quinoxaline (QuinoxP)

    • Author(s)
      T.Imamoto, K.Koide
    • Journal Title

      Catalysts for the Fine Chemical Industry (印刷中)

    • Data Source
      KAKENHI-PROJECT-18037011
  • [Patent] 光学活性ビスホスフィノメタンの製造方法2009

    • Inventor(s)
      今本恒雄小倉友和吉田和弘
    • Industrial Property Rights Holder
      千葉大学日本化学工業
    • Industrial Property Number
      2009-057665
    • Filing Date
      2009-03-11
    • Data Source
      KAKENHI-PROJECT-19020015
  • [Patent] 光学活性アリル化合物類の製造方法2007

    • Inventor(s)
      今本 恒雄 吉田 和弘 西村 三和子 小出 綾
    • Industrial Property Rights Holder
      千葉大学日本化学工業株式会社
    • Industrial Property Number
      2007-195234
    • Filing Date
      2007-07-26
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Patent] 光学活性アリル化合物類の製造方法2007

    • Inventor(s)
      今本恒雄吉田和弘西村三和子小出綾
    • Industrial Property Rights Holder
      千葉大学日本化学工業株式会社
    • Industrial Property Number
      2007-195234
    • Filing Date
      2007-07-26
    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Patent] 2,3(BIS(DIALKYLPHOSPHI-NO)PYRAZINE DERIVATIVE2007

    • Inventor(s)
      T. Imamoto, K. Yoshida, K. Sugita
    • Industrial Property Rights Holder
      千葉大学日本化学工業
    • Filing Date
      2007-01-25
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Patent] 光学活性ビス(アルキニルホスフィノ)エタンーボラン誘導体2007

    • Inventor(s)
      今本恒雄, 吉田和弘, 齋藤陽一, 小出綾
    • Industrial Property Rights Holder
      千葉大学, 日本化学工業
    • Industrial Property Number
      2007-060784
    • Filing Date
      2007-03-07
    • Data Source
      KAKENHI-PROJECT-18037011
  • [Patent] 光学活性α, β-ヒドロキシカルボン酸誘導体の製造方法2007

    • Inventor(s)
      今本恒雄 吉田和弘 西村三和子 小出綾
    • Industrial Property Rights Holder
      千葉大学日本化学工業株式会社
    • Industrial Property Number
      2007-195233
    • Filing Date
      2007-07-26
    • Data Source
      KAKENHI-PROJECT-19020015
  • [Patent] 2,3-ビス(ジアルキルホスフィノ)ピラジン誘導体及びその製造方法2005

    • Inventor(s)
      今本恒雄, 吉田和弘, 杉田敬太郎
    • Industrial Property Rights Holder
      千葉大学, 日本化学工業(株)
    • Industrial Property Number
      2005-215003
    • Filing Date
      2005-07-25
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Patent] 2,3- ビス(ジアノレキノレホスフィノ)ピラジン誘導体及びその製造方法2005

    • Inventor(s)
      今本恒雄, 吉田和弘, 杉田敬太郎
    • Industrial Property Rights Holder
      千葉大学日本科学工業((株))
    • Industrial Property Number
      2005-215003
    • Filing Date
      2005-07-25
    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-16350020
  • [Presentation] Air-Stable P-Chiral Phosphine Ligands for Asymmetric Catalyses2009

    • Author(s)
      T.Imamoto
    • Organizer
      International Symposium on Chiral Compounds and Special Polymers
    • Place of Presentation
      中華人民共和国, ハルビン
    • Year and Date
      2009-07-13
    • Data Source
      KAKENHI-PROJECT-20037009
  • [Presentation] アミノ基を有するC2対称P-キラルジホスフィン配位子の合成及び不斉誘起能2008

    • Author(s)
      今本恒雄, 柳澤悠子, 吉田和弘
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス,東京
    • Data Source
      KAKENHI-PROJECT-19028009
  • [Presentation] Preparation and Enantioselectivity of P-Chiral Phosphine Ligands, QuinoxP^* and AlkynylP^*2008

    • Author(s)
      T. Imamoto
    • Organizer
      第23回有機金属化学国際会議
    • Place of Presentation
      フランス, レンヌ
    • Data Source
      KAKENHI-PROJECT-19020015
  • [Presentation] The Role of P-Chiral Phosphine Ligands in Catalytic Asymmetric Reactions2008

    • Author(s)
      T. Imamoto
    • Organizer
      The 88th Annual Meeting of Chemical Society of Japan
    • Place of Presentation
      Rikkyo University, Tokyo
    • Year and Date
      2008-03-28
    • Description
      「研究成果報告書概要(欧文)」より
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Presentation] 触媒的不斉合成におけるP-キラルポスフィン配位子の役割2008

    • Author(s)
      今本 恒雄
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス,東京
    • Year and Date
      2008-03-28
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Presentation] 触媒的不斉合成におけるP-キラルホスフィン配位子の役割2008

    • Author(s)
      今本恒雄
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス,東京
    • Year and Date
      2008-03-28
    • Description
      「研究成果報告書概要(和文)」より
    • Data Source
      KAKENHI-PROJECT-18350017
  • [Presentation] P-キラルホスフィン配位子の合成と不斉触媒反応への適用2007

    • Author(s)
      熊田淳、小出綾, 齋藤陽一, 吉田和弘, 今本恒雄
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      広島大学東広島キャンパス東広島
    • Data Source
      KAKENHI-PROJECT-19020015
  • 1.  DANJO Hiroshi (70332567)
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  • 2.  YOSHIDA Kazuhiro (60375607)
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