KAWANO Yasuro 河野泰朗

Researcher Number	10262099
Affiliation (based on the past Project Information) *help	2009 – 2011: The University of Tokyo, 大学院・総合文化研究科, 助教 2003 – 2005: 東京大学, 大学院・総合文化研究科, 助手 1998 – 2001: 東京大学, 大学院・総合文化研究科, 助手 1997: 東京大学, 大学院・総合文化研究所, 助手 1996: The University of Tokyo, Graduate School of Arts and Sciences, Researc Associate, 大学院・総合文化研究科, 助手 1995: The University of Tokyo, College of Arts and Sciences, Assistant, 教養学部, 助手
Review Section/Research Field	Principal Investigator Inorganic chemistry / Science and Engineering / Inorganic chemistry Except Principal Investigator Inorganic chemistry / Science education
Keywords	Principal Investigator ボラン / ホウ素 / シグマ錯体 / 触媒 / 錯体 / 金属錯体 / Transition metals / Heterolytic cleavage / Borane complexes / Sigma complexes … More / Metal complexes / Boranes / Boron / プロトン化 / モリブデン / イリジウム / 陽イオン / ルテニウム / タングステン / マンガン / 遷移金属 / 不均等解裂 / ポラン錯体 / 密度汎関数法 / 脱水素カップリング / 金属錯体化学 / 脱水素反応 / 光化学反応 / 遷移金属錯体 / 動的挙動 / ボリル錯体 / 光反応 / スタニルボラン / シリルボラン / シラン … More Except Principal Investigator ボリル錯体 / ボリレン錯体 / ボリレン / arene ligand / phosphines / ruthenium / clusters / ruthenaboranes / metallaboranes / ルテナボチン / アレーンルテナボラン / クラスター化合物 / アレーン配位子 / ホスフィン / ルテニウム / クラスター / ルテナボラン / メタラボラン / Visualization / Chemical education, / Junior course in university, / Molecular modeling, / Computer, / コンピュータ化学 / 大学前記課程 / 視覚化 / 化学教育 / 大学前期課程 / 分子モデリング / コンピュータ / metal clusters / metal complex / boryl / borane / borylene / ボラン錯体 / 金属クラスター錯体 / 金属錯体 / ボリル / ボラン / ルテニウム錯体 / 鉄錯体 / H-D交換反応 / B_2H_5錯体 / シグマ錯体 / テトラボラテトラヘドラン / ジメタラペンタボラン / ボリド錯体 Less

Dehydrocoupling Reactions of Boron Compounds via a Transition Metal. BoraneσComplexPrincipal Investigator
- Principal Investigator
  
  KAWANO Yasuro
- Project Period (FY)
  2009 – 2011
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Inorganic chemistry
- Research Institution
  The University of Tokyo
高度にフラクショナルなボランシグマ錯体の動的挙動と反応性に関する研究Principal Investigator
- Principal Investigator
  
  河野泰朗
- Project Period (FY)
  2003
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Review Section
  
  Science and Engineering
- Research Institution
  The University of Tokyo
Study on Syntheses of Cationic Borane a Complexes and Heterolytic Cleavage of a Boron-Hydrogen BondPrincipal Investigator
- Principal Investigator
  
  KAWANO Yasuro
- Project Period (FY)
  2003 – 2005
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Inorganic chemistry
- Research Institution
  The University of Tokyo
遷移金属―ホウ素二重結合を有するボリレン錯体の合成
- Principal Investigator
  
  下井守
- Project Period (FY)
  1999
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas (A)
- Research Institution
  The University of Tokyo
新規なシリルボランおよびスタニルボラン配位子の開発とその金属錯体合成への展開Principal Investigator
- Principal Investigator
  
  河野泰朗
- Project Period (FY)
  1999 – 2000
- Research Category
  
  Grant-in-Aid for Encouragement of Young Scientists (A)
- Research Field
  
  Inorganic chemistry
- Research Institution
  The University of Tokyo
Establishment of syntheses of metal-rich metallaborane clusters using borane-Lewis base adducts
- Principal Investigator
  
  SHIMOI Mamoru
- Project Period (FY)
  1999 – 2001
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Inorganic chemistry
- Research Institution
  The University of Tokyo
遷移金属-ホウ素二重結合を有するボリレン錯体の合成
- Principal Investigator
  
  下井守
- Project Period (FY)
  1998
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas (A)
- Research Institution
  The University of Tokyo
遷移金属-ホウ素二重結合を有するボリレン錯体の合成
- Principal Investigator
  
  SHIMOI Mamoru
- Project Period (FY)
  1997
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  The University of Tokyo
Development And Trial of Computer Chemistry Education System in The Junior Course of University
- Principal Investigator
  
  OGAWA Keiichiro
- Project Period (FY)
  1995 – 1996
- Research Category
  
  Grant-in-Aid for Scientific Research (A)
- Research Field
  
  Science education
- Research Institution
  The University of Tokyo
Syntheses and Reactivity of Metal Cluster Complexes with Borylene as a Bridging Ligand
- Principal Investigator
  
  SHIMOI Mamoru
- Project Period (FY)
  1994 – 1995
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  Inorganic chemistry
- Research Institution
  The University of Tokyo

All 2011 2010 2009 2007 2006 2004 2003 Other

All Journal Article Presentation Book

[Book] 錯体化学選書(6)「有機金属化学」第9章, 9-1「M. BR2錯体」2010
- Author(s)
  中沢浩,小坂田耕太郎,上野圭司,岡崎雅明,河野泰朗,松坂裕之,水田勉
- Publisher
  三共出版
- Data Source
  KAKENHI-PROJECT-21550056
[Book] 錯体化学会選書「有機金属錯体」第9章第1部「M-BR_2錯体」2010
- Author(s)
  河野泰朗
- Publisher
  三共出版(印刷中)
- Data Source
  KAKENHI-PROJECT-21550056
[Book] 錯体化学選書(6)有機金属化学2010
- Author(s)
  中沢浩, 小坂田耕太郎, 上野圭司, 岡崎雅明, 河野泰朗, 松坂裕之
- Total Pages
  299
- Publisher
  三共出版
- Data Source
  KAKENHI-PROJECT-21550056
[Journal Article] Dehydrocoupling Reactions of Secondary and Primary Amine-Borane Adducts Catalyzed by Half-sandwich Carbonyl Complexes2011
- Author(s)
  Taeko Kakizawa, Yasuro Kawano, Kohsuke Naganeyama, Mamoru Shimoi
- Journal Title
  
  [CpMn(CO)_3],[(η^6-C_6H_6) Cr(CO)_3], and[ CpV(CO)_4], Chem. Lett.
  
  Volume: 40 Pages: 171-173
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-21550056
[Journal Article] Dehydrocoupling Reactions of Secondary and Primary Amine-Borane Adducts Catalyzed by Half-sandwich Carbonyl Complexes, [CpMn(CO)3], [(η6-C6H6)Cr(CO)3], and [CpV(CO)412011
- Author(s)
  Taeko Kakizawa, Yasuro Kawano, Kohsuke Naganeyama, Mamoru Shimoi
- Journal Title
  
  Chemistry Letters
  
  Volume: 40 Pages: 171-173
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-21550056
[Journal Article] Dehydrocoupling Reactions of Borane. Secondary and Primary Amine Adducts Catalyzed by Group-6 Carbonyl Complexes2009
- Author(s)
  Yasuro Kawano, Mikio Uruichi, Mamoru Shimoi, Seitaro Taki, Takayuki Kawaguchi, Taeko Kakizawa, Hiroshi Ogino
- Journal Title
  
  Formation of Aminoboranes and Borazines, J. Am. Chem. Soc.
  
  Volume: 131 Pages: 14946-14957
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-21550056
[Journal Article] Dehydrocoupling Reactions of Borane-Secondary and Primary Amine Adducts Catalyzed by Group-6 Carbonyl Complexes : Formation of Aminoboranes and Borazines2009
- Author(s)
  Kawano, Yasuro
- Journal Title
  
  Journal of the American Chemical Society 131
  
  Pages: 14946-14957
- Peer Reviewed
- Data Source
  KAKENHI-PROJECT-21550056
[Journal Article] Syntheses and Structures of Molybdenum, Tungsten, and Manganese Complexes of a Cyclic Thiourea, [M(CO)_5(SC_3N_2Me_4)] (M = Mo, W) and [{CpMn(CO)_2}_2(μ-SC_3N_2Me_4)]2007
- Author(s)
  Kazuya Saito, Yasuro Kawano, Mamoru Shimoi
- Journal Title
  
  Eur.J.Inorg.Chem. (in Press)
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Syntheses and Structures of Molybdenum, Tungsten, and Manganese Complexes of a Cyclic Thiourea, [M(CO)_5(SC_3N_2Me_4)] (M = Mo, W) and [{CpMn(CO)_2}_2(η-SC_3N_2Me_4)]2007
- Author(s)
  Kazuya Saito, Yasuro Kawano, Mamoru Shimoi
- Journal Title
  
  Eur. J. Inorg. Chem. (印刷中)
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Investigation of the Stability of the M-H-B Bond in Borane σ Complexes [M(CO)_5(η^1-BH_2R・L)] and [CpMn(CO)_2(η^1-BH_2R・L)] (M = Cr, W; L = Tertiary Amine or Phosphine) : Substituent Effect and Lewis Base Effect2007
- Author(s)
  Yasuro Kawano, Kazunori Yamaguchi, Shun-ya Miyake, Taeko Kakizawa, Mamoru Shimoi
- Journal Title
  
  Chem. Eur. J. 13(印刷中)
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Syntheses and Reactivity of Cationic Borane-Ruthenium Complexes [η^5-C_5R_5)Ru(PMe_3)_2(η^1-BH_3・EMe_3)][BAr^1_4] (R = H, Me; E=N, P; BAr^1_4=[B{3,5-C_6H_3(CF_3)_2}_4])2006
- Author(s)
  Yasuro Kawano, Masahiro Hashiva, Mamoru Shimoi
- Journal Title
  
  Organometallics 25
  
  Pages: 4420-4426
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] A Computational Study on Fluxional Behavior of Group 6 and 7 Transition Metal Complexes of Borane-Lewis Base Adducts2006
- Author(s)
  Yasuro Kawano, Taeko Kakizawa, Kazunori Yamaguchi, Mamoru Shimoi
- Journal Title
  
  Chemistry Letters 35(印刷中)
- NAID
  10019162265
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Syntheses and Reactivity of Cationic "Borane-Ruthenium Complexes [(η^5-C_5R_5)Ru(PMe_3)_2- (η^1-BH_3・EMe_3)][BAr^f_4] (R = H, Me ; E = N, P ; BAr^f_4 = [B{3,5-C_6H_3(CF_3}_2}_4])"2006
- Author(s)
  Yasuro Kawano, Masahiro Hashiva, Mamoru Shimoi
- Journal Title
  
  Organometallics 25
  
  Pages: 4420-4426
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] A Computational Study on Fluxional Behavior of Group 6 and 7 Transition Metal Complexes of Borane-Lewis Base Adducts2006
- Author(s)
  Yasuro Kawano, Taeko Kakizawa, Kazunori Yamaguchi, Mamoru Shimoi
- Journal Title
  
  Chem.Lett. 35
  
  Pages: 568-569
- NAID
  10019162265
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] A Computational Study on Fluxional Behavior of Group 6 and 7 Transition Metal Complexes of Borane-Lewis Base Adducts2006
- Author(s)
  Yasuro Kawano, Taeko Kakizawa, Kazunori Yamaguchi, Mamoru Shimoi
- Journal Title
  
  Chem. Lett. 35
  
  Pages: 568-569
- NAID
  10019162265
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Reactivity of the Cluster Core of Ruthenaboranes toward Phosphorus Compounds2004
- Author(s)
  Lourdes N.Pangan, Mamoru Shimoi, Hiroyuki Kawakami, Yasuro Kawano
- Journal Title
  
  Boron Chemistry at the Beginning of the 21th Century
  
  Pages: 266-270
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Boryl Complexes and Cationic Borane σ Complexes of Manganese : Heterolytic Cleavage of the Metal-coordinated BH σ Bond2004
- Author(s)
  Yasuro Kawano, Takahiro Yasue, Mamoru Shimoi
- Journal Title
  
  Boron Chemistry at the Beginning of the 21th Century
  
  Pages: 234-238
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Reactivity of the Cluster Core of Ruthenaboranes toward Phosphorus Compounds2004
- Author(s)
  Lourdes N.Pangan, Mamoru Shimoi, Hiroyuki Kawakami, Yasuro Kawano
- Journal Title
  
  Boron Chemistry at the Beginning of the 21th Century, Scientific Publishers URSS
  
  Pages: 234-238
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Boryl Complexes and Cationic Borane a Complexes of Manganese : Heterolytic Cleavage of the Metal- coordinated BH a Bond2004
- Author(s)
  Yasuro Kawano, Takahiro Yasue, Mamoru Shimoi
- Journal Title
  
  Boron Chemistry at the Beginning of the 21th Century, Scientific Publishers URSS
  
  Pages: 234-238
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Reactivity of the Cluster Core of Ruthenaboranes toward Phosphorus Compounds2003
- Author(s)
  L.N.Pangan, M.Shimoi, H.Kawakami, Y.Kawano
- Journal Title
  
  Boron Chemistry at the Beginning of the 21th Century
  
  Pages: 266-270
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Proton-induced Mode Change of Boron Group Coordination : Boryl Complexes [Mn(CO)_4(PR_3)(BH_2,・PMe_3)] and Cationic Borane σ Complexes [Mn(CO)_4(PR_3)(η^1-BH_3・PMe_3)] (PR_3= PMe_3Ph, PEt_3)2003
- Author(s)
  Takahiro Yasue, Yasuro Kawano, Mamoru Shimoi
- Journal Title
  
  Angew. Chem., Int. Ed. Engl 42
  
  Pages: 1727-1730
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Boryl Complexes and Cationic Borane σ Complexes of Manganese : Heterolytic Cleavage of the Metal-coordinated BH σ Bond2003
- Author(s)
  Y.Kawano, T.Yasue, M.Shimoi
- Journal Title
  
  Boron Chemistry at the Beginning of the 21th Century
  
  Pages: 234-238
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Proton-induced Mode Change of Boron Group Coordination : Boryl Complexes [Mn(CO)_4(PR_3)(BH_2・PMe_3)] and Cationic Borane σ Complexes [Mn(CO)_4(PR_3)(η^1-BH_3・PMe_3]^+ (PR3=PMe, Ph, PEt_3)2003
- Author(s)
  T.Yasue, Y.Kawano, M.Shimoi
- Journal Title
  
  Angewandte Chemie, International Edition in English 42
  
  Pages: 1727-1730
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Proton-induced Mode Change of Boron Group Coordination : Boryl Complexes [Mn(CO)_4(PR_3)(BH_2・PMe_3)] and Cationic Borane a Complexes [Mn(CO)_4(PR_3)(η^1-BH_3・PMe_3)]+ (PR_3 = PMe_2Ph, PEt_3)2003
- Author(s)
  Takahiro Yasue, Yasuro Kawano, Mamoru Shimoi
- Journal Title
  
  Angew.Chem., Int.Ed.Engl. 42
  
  Pages: 1727-1730
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Journal Article] Investigation of the Stability of the M-H-B Bond in Borane a Complexes [M(CO)_5(η^1-BH_2R・L)] and [CpMn(CO)_2(η^1-BH_2R・L)] (M = Cr, W ; L= Tertiary Amine or Phosphine) : Substituent Effect and Lewis Base Effect
- Author(s)
  Yasuro Kawano, Kazunori Yamaguchi, Shun-ya Miyake, Taeko Kakizawa, Mamoru Shimoi
- Journal Title
  
  Chem.Eur.J. 13(in Press)
  
  Pages: 2007-2007
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-15350031
[Presentation] 新規二座配位型陽イオン性ボランシグマ錯体の合成と性質2009
- Author(s)
  浅香俊貴,河野泰朗,下井守
- Organizer
  第59回錯体化学討論会
- Place of Presentation
  長崎
- Data Source
  KAKENHI-PROJECT-21550056

1. SHIMOI Mamoru (30092240)

# of Collaborated Projects: 8 results

# of Collaborated Products: 22 results
2. OGAWA Keiichiro (50114426)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
3. IMAMURA Yasutada (40201339)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
4. KIKUCHI Kazuo (60012423)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
5. NISHIKIORI Shin-ichi (70134400)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results

KAWANO Yasuro 河野 泰朗

Research Projects

Research Products

Co-Researchers

Dehydrocoupling Reactions of Boron Compounds via a Transition Metal. BoraneσComplexPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

高度にフラクショナルなボランシグマ錯体の動的挙動と反応性に関する研究Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Study on Syntheses of Cationic Borane a Complexes and Heterolytic Cleavage of a Boron-Hydrogen BondPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

遷移金属―ホウ素二重結合を有するボリレン錯体の合成

Principal Investigator

Project Period (FY)

Research Category

Research Institution

新規なシリルボランおよびスタニルボラン配位子の開発とその金属錯体合成への展開Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Establishment of syntheses of metal-rich metallaborane clusters using borane-Lewis base adducts

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

遷移金属-ホウ素二重結合を有するボリレン錯体の合成

Principal Investigator

Project Period (FY)

Research Category

Research Institution

遷移金属-ホウ素二重結合を有するボリレン錯体の合成

Principal Investigator

Project Period (FY)

Research Category

Research Institution

Development And Trial of Computer Chemistry Education System in The Junior Course of University

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Syntheses and Reactivity of Metal Cluster Complexes with Borylene as a Bridging Ligand

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

[Book] 錯体化学選書(6)「有機金属化学」第9章, 9-1「M. BR2錯体」2010

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Data Source

[Book] 錯体化学会選書「有機金属錯体」第9章第1部「M-BR_2錯体」2010

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Data Source

[Book] 錯体化学選書(6)有機金属化学2010

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[Journal Article] Dehydrocoupling Reactions of Secondary and Primary Amine-Borane Adducts Catalyzed by Half-sandwich Carbonyl Complexes2011

Author(s)

Journal Title

Data Source

[Journal Article] Dehydrocoupling Reactions of Secondary and Primary Amine-Borane Adducts Catalyzed by Half-sandwich Carbonyl Complexes, [CpMn(CO)3], [(η6-C6H6)Cr(CO)3], and [CpV(CO)412011

Author(s)

KAWANO Yasuro 河野泰朗