OKUYAMA Tadashi 奥山格

Researcher Number	40029484
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Affiliation (based on the past Project Information) *help	2005: 兵庫県立大学, 大学院物質理学研究科, 教授 2004: University of Hyogo, Graduate School of Material Science, Professor, 大学院・物質理学研究科, 教授 2002 – 2003: 姫路工業大学, 大学院・理学研究科, 教授 2000 – 2001: 姫路工業大学, 理学部, 教授 1997 – 1998: 大阪大学, 大学院・基礎工学研究科, 助教授 … More 1995 – 1996: 大阪大学, 基礎工学部, 助教授 1986 – 1993: 大阪大学, 基礎工学部, 助教授 1986: Faculty of Engineering Science, Osaka University, 基礎工学部, 助教授 Less
Review Section/Research Field	Principal Investigator Science and Engineering / 有機化学一般 / Organic chemistry / Synthetic chemistry Except Principal Investigator 物理化学一般 / 有機化学一般 / Organic chemistry
Keywords	Principal Investigator ヨードニウム塩 / カルボカチオン / 閃光光分解 / ビニルヨードニウム塩 / シクロアルキン / ビニルカチオン / 超原子価中間体 / ベンゼニウムイオン / Carbocation / Flash photolysis … More / レーザー光分解 / 不安定中間体 / 超原子価化合物 / ヨーダン / カルベン / 隣接基関与 / ヨードニウムイオン / 加溶媒分解 / 開環反応 / スルフラン / 標識化合物 / 加水分解 / Photochemical ionization / Ortho ester / Ketene dithioacetal / 二価硫黄 / 光イオン化 / オルトエステル / ケテンジチオアセタール / 炭素陽イオン / laser photolysis / singlet oxygen / neighboring group participation / cycloalkyne / naphthalene / cation radical / vinyl cation / iodonium salt / 光加溶媒分解 / 光誘起付加 / 一電子移動 / 面区別反応 / ビニルカオチン / カルボン酸会合 / 水素結合 / エナンチオN選択性 / 不斉酸素化 / 1,3-ジオキソレニウムイオン / 一重項酸素 / ナフタレン / カチオンラジカル / Sulfonium Salt / Iodane / Benzenium Ion / VinylicS_N2 Reaction / Hypervalent Interaction / Iodonium Salt / Main Group Element / Onium Salt / スルホニウム塩 / ビニルSN_2反応 / ビニルSN2反応 / 典型元素 / オニウム塩 / Unstable intermediate / Electron transfer / Radical cation / Photoreaction / Laser photolysis / 置換基効果 / 電子移動反応 / ラジカルカチオン / 光反応 / 光水和反応 / 光加水分解 / チオオルトエステル / 光化学的イオン化 / 1,2水素移動 / イリド / マイケル付加 / リガンドカップリング / 反応速度 / 脱離能 / 超原子価錯体 / Michael付加 / 脱離-付加機構 / ミクロヘキシン / イオン性基質 / 光学活性化合物 / 転位反応 / 脱離反応 / 求核置換反応 / 溶媒効果 / 超原子価相互作用 / 液相反応 / イオン対 / 環歪み / 閉環反応 / 酸素同位体交換 / スルフィン酸エステル / 環化反応 / 同位体交換速度 / 酸素同位体元素 / スルフィン酸 / 環状スルフィン酸エステル / フリ-イオン / 光化学開裂反応 / イオン対再結合 / レ-ザ-光分解 / 還元反応 / 同位体元素 / スルフェン酸エステル / 硫黄超原子価中間体 … More Except Principal Investigator Reaction paths / Intramolecular insertion / 1,3-Hydrogen migration / 1,2-Hydrogen migration / Ethylnitrene / Imino radicals NH(^1delta,^3sigma^-) / Diradicals / 水素原子移動 / 水素原子脱離 / エチレンオキシドジラジカルC【H_2】C【H_2】O / ラジカル会合 / 量子収率 / 亜酸化窒素【N_2】O / イミノラジカルNH(【^1△】) / 1,2ー水素移動反応 / H原子引抜き反応 / 挿入反応 / 1,3ージラジカル / イミノラジカルNH(^1△) / エネルギー障壁 / ヒドロペルオキシニトレン / HNOOジラジカル / 1,3ー水素移動反応 / イミノラジカルNH(^3Σ^-) / 遷移状態 / 反応経路 / 分子内挿入 / 1,3ーH移動 / 1,2ーH移動 / エチルニトレン / イミノラジラカルNH(^1Δ、^3Σ^-) / ジラジカル / Reaction intermediate / Electron transfer / Photochemical reaction / Kinetics / Asymmetric Synthesis / Stereochemistry / Heteroatom Compounds / Substituent effect / 反応中間体 / 電子移動 / 光化学反応 / 反応速度 / 不斉合成 / 立体化学 / ヘテロ元素化合物 / 置換基効果 / 溶媒効果理論 / 溶液反応過程 / ミクロ溶媒効果 / 有機素反応 Less

高配位ビニルヨウ素錯体と反応性中間体の時空間制御Principal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  2004 – 2005
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Review Section
  
  Science and Engineering
- Research Institution
  University of Hyogo
高配位ヨウ素錯体と炭素不安定中間体の時空間制御Principal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  2003 – 2005
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Review Section
  
  Science and Engineering
- Research Institution
  Himeji Institute of Technology
Study on reactive intermediates and solvent participation by means of interplay of photochemical and thermochemical reactionsPrincipal Investigator
- Principal Investigator
  
  OKUYAMA Tadashi
- Project Period (FY)
  2002 – 2004
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Organic chemistry
- Research Institution
  University of Hyogo
  Himeji Institute of Technology
イオン性基質を利用する溶液反応解析と反応設計への応用Principal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  2000 – 2001
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas (A)
- Review Section
  
  Science and Engineering
- Research Institution
  Himeji Institute of Technology
Hypervalent Interactionsin the Reactions Onium Salts of Main Group ElementsPrincipal Investigator
- Principal Investigator
  
  OKUYAMA Tadashi
- Project Period (FY)
  1997 – 1998
- Research Category
  
  Grant-in-Aid for Scientific Research (C)
- Research Field
  
  Organic chemistry
- Research Institution
  Osaka University
有機素反応理論の成立
- Principal Investigator
  
  大野惇吉
- Project Period (FY)
  1996
- Research Category
  
  Grant-in-Aid for Scientific Research (B)
- Research Field
  
  Organic chemistry
- Research Institution
  Kyoto University
液相におけるイオン-分子対の反応Principal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  1995
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Osaka University
有機硫黄における超原子価中間体Principal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  1992
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Osaka University
Multi-dimentional Analysis of Highly Specific Organic Reactions Governed by the Combinal Influence of Functional Groups
- Principal Investigator
  
  SUZUKI Hitomi
- Project Period (FY)
  1992 – 1993
- Research Category
  
  Grant-in-Aid for Co-operative Research (A)
- Research Field
  
  有機化学一般
- Research Institution
  KYOTO UNIVERSITY
Sudies on Ionic Intermediates by Flash PhotolysisPrincipal Investigator
- Principal Investigator
  
  OKUYAMA Tadashi
- Project Period (FY)
  1992 – 1993
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  有機化学一般
- Research Institution
  Osaka University
超原子評中間体への反応機構論的アプロ-チPrincipal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  1991
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Osaka University
レ-ザ-光分解によるカルボカチオンのイオン対および自由イオンの反応性に関する研究Principal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  1990
- Research Category
  
  Grant-in-Aid for Scientific Research on Priority Areas
- Research Institution
  Osaka University
有機硫黄化学反応における超原子価中間体への速度論的アプロ-チPrincipal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  1989
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  有機化学一般
- Research Institution
  Osaka University
光化学的イオン化を用いる不安定中間体の高速反応過程に関する研究Principal Investigator
- Principal Investigator
  
  奥山格
- Project Period (FY)
  1988
- Research Category
  
  Grant-in-Aid for General Scientific Research (C)
- Research Field
  
  有機化学一般
- Research Institution
  Osaka University
Chemical Behavior of Quasi-Stable Diradicals and Diradicaloids
- Principal Investigator
  
  FUENO Takayuki
- Project Period (FY)
  1986 – 1988
- Research Category
  
  Grant-in-Aid for General Scientific Research (B)
- Research Field
  
  物理化学一般
- Research Institution
  Osaka university
Reactivity of the Carbocations Stabilized by Divalent Sulfur and Application to Organic SynthesisPrincipal Investigator
- Principal Investigator
  
  OKUYAMA Tadashi
- Project Period (FY)
  1985 – 1986
- Research Category
  
  Grant-in-Aid for General Scientific Research (B)
- Research Field
  
  Synthetic chemistry
- Research Institution
  Osaka University

All 2006 2005 2002

All Journal Article Book

[Book] 電子の動きでみる有機反応のしくみ2005
- Author(s)
  奥山格, 杉村高志
- Total Pages
  301
- Publisher
  東京化学同人
- Data Source
  KAKENHI-PROJECT-16033255
[Book] 有機反応論2005
- Author(s)
  奥山格, 山高博
- Total Pages
  301
- Publisher
  朝倉書店
- Data Source
  KAKENHI-PROJECT-16033255
[Journal Article] Photochemical generation of six- and five-membered cyclic vinyl cations2006
- Author(s)
  奥山格
- Journal Title
  
  Journal of Organic Chemistry 71
  
  Pages: 2227-2235
- Data Source
  KAKENHI-PROJECT-16033255
[Journal Article] Regioselectivity in nucleophilic addition of siloxyalkenes to alkylideneallyl cation2006
- Author(s)
  奥山格, 藤田守文
- Journal Title
  
  Chemistry Letters 35
  
  Pages: 382-383
- NAID
  10018125377
- Data Source
  KAKENHI-PROJECT-16033255
[Journal Article] Reaction of cyclohexenyl iodonium tetrafluoroborate with bromide ion : Retardation due to formation of λ^3-bromoiodane2006
- Author(s)
  奥山格, 藤田守文
- Journal Title
  
  Journal of Organic Chemistry 71
  
  Pages: 1609-1613
- Data Source
  KAKENHI-PROJECT-16033255
[Journal Article] Generation of cycloalkynes by hydro-iodonio-elimination of vinyl iodonium salts2005
- Author(s)
  奥山格, 藤田守文
- Journal Title
  
  Accounts of Chemical Research 38
  
  Pages: 679-686
- Data Source
  KAKENHI-PROJECT-16033255
[Journal Article] Reactions of cyclohexenyliodonium salts2005
- Author(s)
  奥山格, 藤田守文
- Journal Title
  
  Russian Journal of Organic Chemistry 41
  
  Pages: 1245-1253
- Data Source
  KAKENHI-PROJECT-16033255
[Journal Article] Chirality probe approach to reactive intermediates. Primary vinyl cation and cycloalkyne2002
- Author(s)
  Tadashi Okuyama
- Journal Title
  
  Proceeding of Japan Academy 78(B)
  
  Pages: 157-172
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-14340202
[Journal Article] Solvolysis of vinyl iodonium salts. New insight into vinyl cation intermediates2002
- Author(s)
  奥山格
- Journal Title
  
  Accounts of Chemical Research 35
  
  Pages: 12-18
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-14340202
[Journal Article] Solvolysis of vinyl iodonium salts. New insight into vinyl cation intermediates2002
- Author(s)
  Tadashi Okuyama
- Journal Title
  
  Accounts of Chemical Research 35
  
  Pages: 12-18
- Description
  「研究成果報告書概要(欧文)」より
- Data Source
  KAKENHI-PROJECT-14340202
[Journal Article] Chirality probe approach to reactive intermediates. Primary vinyl cation and cycloalkyne2002
- Author(s)
  奥山格
- Journal Title
  
  Proceeding of Japan Academy 78(B)
  
  Pages: 167-172
- Description
  「研究成果報告書概要(和文)」より
- Data Source
  KAKENHI-PROJECT-14340202

1. FUJITA Morifumi (00275314)

# of Collaborated Projects: 3 results

# of Collaborated Products: 4 results
2. TAKEUCHI Kenichi (50026358)

# of Collaborated Projects: 2 results

# of Collaborated Products: 0 results
3. SUZUKI Hitomi (50025342)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
4. KIRA Mitsuo (40004452)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
5. OKU Akira (50027885)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
6. TOMIOKA Hideo (20024599)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
7. FUENO Takayuki (60029387)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
8. YAMAGUCHI Kizashi (80029537)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
9. 森島洋太郎 (70028249)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
10. 落合正仁 (50127065)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
11. 大野惇吉 (70027077)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
12. 辻孝 (20029482)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
13. 山高博 (60029907)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
14. 浅野努 (40094057)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
15. 西田進也 (40029400)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
16. 香月つとむ (40037271)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
17. 稲津孝彦 (60037207)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
18. 広田穣 (00017881)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results
19. 安藤亘 (30008429)

# of Collaborated Projects: 1 results

# of Collaborated Products: 0 results

OKUYAMA Tadashi 奥山 格

Research Projects

Research Products

Co-Researchers

高配位ビニルヨウ素錯体と反応性中間体の時空間制御Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

高配位ヨウ素錯体と炭素不安定中間体の時空間制御Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Study on reactive intermediates and solvent participation by means of interplay of photochemical and thermochemical reactionsPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

イオン性基質を利用する溶液反応解析と反応設計への応用Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Review Section

Research Institution

Hypervalent Interactionsin the Reactions Onium Salts of Main Group ElementsPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

有機素反応理論の成立

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

液相におけるイオン-分子対の反応Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

有機硫黄における超原子価中間体Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

Multi-dimentional Analysis of Highly Specific Organic Reactions Governed by the Combinal Influence of Functional Groups

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

Sudies on Ionic Intermediates by Flash PhotolysisPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

超原子評中間体への反応機構論的アプロ-チPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

レ-ザ-光分解によるカルボカチオンのイオン対および自由イオンの反応性に関する研究Principal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Institution

有機硫黄化学反応における超原子価中間体への速度論的アプロ-チPrincipal Investigator

Principal Investigator

Project Period (FY)

Research Category

Research Field

Research Institution

光化学的イオン化を用いる不安定中間体の高速反応過程に関する研究Principal Investigator

Principal Investigator

OKUYAMA Tadashi 奥山格